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81.
Setsuo Kashino Jun‐ichiro Taka Takeo Fukunaga Hiroyuki Ishida 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(5):549-552
A centrosymmetric and short O—H?O hydrogen bond was found in isomorphic crystals of potassium hydrogen trans‐glutaconate monohydrate (potassium hydrogen trans‐pent‐2‐ene‐1,5‐dioate, K+·C5H5O4?·H2O), (I), and rubidium hydrogen trans‐glutaconate monohydrate (rubidium hydrogen trans‐pent‐2‐ene‐1,5‐dioate, Rb+·C5H5O4?·H2O), (II). The O?O distance at room temperature is 2.444 (3) Å in (I), and 2.417 (4) Å in (II). The O?O distance for (I) showed no significant decrease at low temperatures. 相似文献
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Polyoxytetramethyleneglycol (PTMG) can be directly prepared from tetrahydrofuran (THF) and water in the presence of heteropolyacids (HPA), without the hydrolysis step. The reaction is carried out by mixing two liquid phases: the THF phase and a heteropolyacid catalyst phase. In this reaction the molar ratio of water to a heteropolyacid (H2O/HPA) in the catalyst phase plays an important role in the THF polymerization activity and the molecular weight of PTMG. IR spectrometric studies revealed that THF is coordinated to a heteropolyanion through either a water molecule or a proton in the catalyst phase. The latter type of coordination bings about the activation of THF capable of initiating the ring-opening polymerization even in the presence of water at a lower acid strength. The PTMG prepared by this method has a narrow molecular weight distribution (M?w/M?n = 1.5 or less) and a number average molecular weight of 500–2000 which are requisite for the production of polyurethane elastomers. A new polymerization mechanism named “Phase Transfer Polymerization” is proposed for elucidating a narrow molecular weight distribution. 相似文献
85.
Susumu Shinagawa Fumiko Kasahara Yoshikazu Wada Setsuo Harada Mitsuko Asai 《Tetrahedron》1984,40(18):3465-3470
The structure of bulgecin A, a bacterial metabolite with bulge-inducing activity, was determined chemically and spectrometrically to be 4-o-(2'-acetylamino-2'-deoxy-4'-o-hydroxysulfonyl-β-D-glucopyranosyl)-(2S, 4S, 5R -4-hydroxy-5-hydroxymethylprolyltaurine monosodium salt. Bulgecns B and C, the minor components, were found to be analogs of bulgecin A in which the taurine moiety was replaced as shown in Fig, 1. 相似文献
86.
Rayleigh light scatterings of 2-propanol-water binary mixtures at 546 nm have been measured by using a conventional fluorophotometer at 25 degrees C. Mean square concentration fluctuations and Kirkwood-Buff parameters of the mixtures in a range of 2-propanol mole fraction of 0.0=x(2pr)=0.4 (0-75% (v/v)) have been calculated from the scattering intensities. On the basis of these parameters, it has been concluded that at x(2pr)<0.05 (15% (v/v)) 2-propanol is well solvated by water molecules, and hydrates consisting of one 2-propanol molecule and 20-30 water molecules are formed in the mixtures. However, at 0.05=x(2pr)=0.3 (15-65% (v/v)) large clusters mainly composed of 2-propanol molecules are formed in the mixtures, and these clusters are further reduced into small 2-propanol aggregates at x(2pr)>/=0.4. The usage of 2-propanol as organic modifier and its effects on CE and RPLC separations are also discussed in terms of microheterogeneity in the mobile phase. 相似文献
87.
Chrysophanol and 1,8-di-O-hexylchrysophanol derivatives having nucleic acid bases at position 5 were synthesized. Furthermore, derivatives of menadione substituted at position 11 (type A naphthoquinone derivatives) or methylmenadione substituted at position 7 (type B naphthoquinone derivatives) modified with nucleic acid bases, amines and thiocyano, selenocyano or thioacetyl groups were synthesized. The cytotoxic effects of these derivatives on HCT 116 cells, which poorly express P-glycoprotein (P-gp), and Hep G2 cells, which stably express P-gp, were evaluated by performing 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay. Results were compared with those obtained using 5-fluorouracil (5-FU), which has been used clinically. Several of these derivatives exhibited markedly higher potent cytotoxic effects not only on HCT cancer cells but also Hep G2 cancer cells as compared with 5-FU. 相似文献
88.
Let M be a real hypersurface with almost contact metric structure ${(\phi, \xi, \eta, g)}$ in a complex projective space ${P_{n}\mathbb{C}}$ . A Real hypersurface M is said to be a Hopf hypersurface if ξ is principal. In this paper we investigate real hypersurfaces of ${P_{n}\mathbb{C}}$ whose Ricci tensors S satisfy ${\nabla_{\phi\nabla_{\xi}\xi}S = 0}$ . Under some further conditions we characterize Hopf hypersurfaces of ${P_{n}\mathbb{C}}$ . 相似文献