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排序方式: 共有291条查询结果,搜索用时 343 毫秒
91.
Arkhipova Ekaterina A. Strokova Natalia E. Tambovtseva Yulia A. Ivanov Anton S. Chernyak Sergei A. Maslakov Konstantin I. Egorova Tolganay B. Savilov Serguei V. Lunin Valery V. 《Journal of Thermal Analysis and Calorimetry》2020,140(6):2641-2648
Journal of Thermal Analysis and Calorimetry - Combustion heats of graphene nanoflakes (GNFs) of different thicknesses produced by chemical vapor deposition method were measured for the first time... 相似文献
92.
93.
It is well known that a finite graph can be viewed, in many respects, as a discrete analogue of a Riemann surface. In this paper, we pursue this analogy further in the context of linear equivalence of divisors. In particular, we formulate and prove a graph-theoretic analogue of the classical Riemann-Roch theorem. We also prove several results, analogous to classical facts about Riemann surfaces, concerning the Abel-Jacobi map from a graph to its Jacobian. As an application of our results, we characterize the existence or non-existence of a winning strategy for a certain chip-firing game played on the vertices of a graph. 相似文献
94.
This paper gives a pathwise construction of Jackson-type queueing networks allowing the derivation of stability and convergence theorems under general probabilistic assumptions on the driving sequences; namely, it is only assumed that the input process, the service sequences and the routing mechanism are jointly stationary and ergodic in a sense that is made precise in the paper. The main tools for these results are the subadditive ergodic theorem, which is used to derive a strong law of large numbers, and basic theorems on monotone stochastic recursive sequences. The techniques which are proposed here apply to other and more general classes of discrete event systems, like Petri nets or GSMPs. The paper also provides new results on the Jackson-type networks with i.i.d. driving sequences which were studied in the past.The work of this author was supported in part by a grant from the European Commission DG XIII, under the BRA Qmips contract.The work of this author was supported by a sabbatical grant from INRIA Sophia Antipolis. 相似文献
95.
Aronica C Chastanet G Zueva E Borshch SA Clemente-Juan JM Luneau D 《Journal of the American Chemical Society》2008,130(7):2365-2371
A series of compounds (cat)[V6O6(OCH3)8(calix)(CH3OH)] was obtained under anaerobic conditions and solvothermal reaction of VOSO4 with p-tert-butylcalix[4]arene (calix) in methanol using different types of bases (Et4NOH, NH4OH, pyridine, Et3N). All compounds contain the same polyoxo(alkoxo)hexavanadate anion [V6O6(OCH3)8(calix)(CH3OH)]- (1) exhibiting a mixed valence {VIIIVIV5O19} core with the so-called Lindqvist structure coordinated to a calix[4]arene macrocycle and cocrystallizing with the conjugated acid of the base (cat = Et4N+, NH4(+), pyridinium, Et3NH+) involved in the synthesis process. The structures have been fully established from X-ray diffraction on single crystals and the mixed valence state has been confirmed by bond valence sum calculations. The magnetic behavior of all compounds are the same because of the polyalkoxohexavanadate anion [V6O6(OCH3)8(calix)(CH3OH)]- (1) and have been interpreted by DFT calculations. Thus the V(III)...V(IV) interactions are found to be weakly ferromagnetic (<5.5 cm(-1)) while the V(IV)...V(IV) are antiferromagnetic (-17.6; -67.6 cm(-1)). The set of the coupling exchange parameters allows a good agreement with the magnetic experimental data. 相似文献
96.
Genre C Jeanneau E Bousseksou A Luneau D Borshch SA Matouzenko GS 《Chemistry (Weinheim an der Bergstrasse, Germany)》2008,14(2):697-705
We report here on the synthesis and characterisation of a first iron(II) spin-crossover coordination polymer with the dca spacer ligand, having the formula [Fe(aqin)2(dca)]ClO4.MeOH (aqin=8-aminoquinoline, dca=dicyanamide), which displays a two-step complete spin transition. Variable-temperature magnetic susceptibility measurements and M?ssbauer spectroscopy have revealed that the two relatively gradual steps are centred at 215 and 186 K and are separated by an inflection point at about 201 K, at which 50 % of the complex molecules undergo a spin transition. The two steps are related to the existence of two crystallographically inequivalent metal sites, as confirmed by the structural and M?ssbauer studies. The crystal structure was resolved at 293 K (HS form) and 130 K (LS form). Both spin-state structures belong to the triclinic P1 space group (Z=2). The complex assumes a linear chain structure, in which the active iron(II) sites are linked to each other by anionic dicyanamide ligands acting as chemical bridges. The Fe-Fe distances through the dca ligand are 8.119(1) and 7.835(1) A in the high-spin and low-spin structures, respectively. The polymeric chains extend along a (1, 0, -1) axis and are packed in sheets, between which the perchlorate anions and methanol molecules are inserted. The complex molecules are linked together by pi-stacking interactions and H-bonding between the H-donor aqin ligands and the perchlorate ions. These structural features provide a basis for cooperative interactions in the crystal lattice. Analysis of the two-step spin-crossover character in this compound suggests that covalent interactions through the spacer ligand do not provide the main mechanism of cooperativity. 相似文献
97.
A p‐list assignment L of a graph G assigns to each vertex v of G a set of permissible colors. We say G is L‐(P, q)‐colorable if G has a (P, q)‐coloring h such that h(v) ? L(v) for each vertex v. The circular list chromatic number of a graph G is the infimum of those real numbers t for which the following holds: For any P, q, for any P‐list assignment L with , G is L‐(P, q)‐colorable. We prove that if G has an orientation D which has no odd directed cycles, and L is a P‐list assignment of G such that for each vertex v, , then G is L‐(P, q)‐colorable. This implies that if G is a bipartite graph, then , where is the maximum average degree of a subgraph of G. We further prove that if G is a connected bipartite graph which is not a tree, then . © 2008 Wiley Periodicals, Inc. J Graph Theory 59: 190–204, 2008 相似文献
98.
99.
Bossé E Den Auwer C Berthon C Guilbaud P Grigoriev MS Nikitenko S Le Naour C Cannes C Moisy P 《Inorganic chemistry》2008,47(13):5746-5755
The complexes [MeBu 3N] 2[UCl 6] and [BuMe 2Im] 2[UCl 6] were characterized in the solid state and in solution of [MeBu 3N][Tf 2N], [BuMe 2Im][Tf 2N], and [BuMeIm][Tf 2N] room-temperature ionic liquids using single-crystal XRD, EXAFS, electrochemistry, UV-visible absorption spectroscopy, and NMR. In the solid state and in solution, the existence of hydrogen bonding between the UCl 6 (2-) complex and the ionic liquid cations was revealed by these techniques. The MeBu 3N (+) cation interacts with UCl 6 (2-) via the protons on the alpha-carbon atoms of nitrogen. The protons of the imidazolium ring account for the interaction between the BuMe 2Im (+) cation and the UCl 6 (2-) anion. For the BuMeIm (+) cation the major interaction was confirmed between the most acidic proton on C(2) and the chlorides of UCl 6 (2-). The experimental results also show that the intensity of the interaction between the UCl 6 (2-) anion and the cation varies with the ionic liquid cation in the following order: MeBu 3N (+) approximately BuMe 2Im (+) < BuMeIm (+). 相似文献
100.
Guillon T Salmon L Molnár G Zein S Borshch S Bousseksou A 《The journal of physical chemistry. A》2007,111(33):8223-8228
A quantum chemical study of the Fe[5-NO2-sal-(1,4,7,10)] ((1,10-bis(5-nitrosalicylaldehyde)-1,4,7,10-tetra-ezdecane-O,O',N,N',N' ',N' ')iron(II)) molecule was performed using density functional theory (DFT). Starting from the different X-ray crystallographic structures, geometry optimizations have been performed. These calculations confirmed the conformational isomerism of this complex in each spin states of the molecule ((1)A(1g) and (5)T(2g)). Each employed DFT method (B3LYP, B3LYP*, BP86, HCTH407) reproduced correctly the structural differences between the two calculated conformers when compared to the experimental structures. Furthermore, electronic polarizabilities have been calculated in each spin state and for each conformer. These calculations revealed a higher polarizability in the singlet state in agreement with the measured higher dielectric constant in this state. 相似文献