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201.
Two different approaches under ambient conditions were developed for the preparation of clean, non-reconstructed, single crystalline ZnO(0001)-Zn surfaces. The surface preparation by a wet chemical etching procedure was compared with the same treatment in combination with a subsequent heat treatment in humidified oxygen atmosphere. Depending on the preparation technique, atomically flat terraces with a width of 100 nm to several micrometers were observed using an atomic force microscope (AFM). The obtained surface structures were further characterized by means of angle resolved X-ray photoelectron spectroscopy (AR-XPS), time-of-flight secondary ion mass spectroscopy (ToF-SIMS), Auger electron spectroscopy (AES) and low energy electron diffraction (LEED) measurements. Based on these results it is shown that the obtained surfaces are, in contrast to surfaces prepared under UHV conditions, stabilised by the adsorption of a monolayer of hydroxides. The important role of H(2)O during the heat treatment is pointed out by comparing the results of the same heat treatment in the absence of water. H(2)O turned out to play an important role in the reorganization process of the surface at elevated temperatures, thereby yielding extremely large atomically flat terraces. The terminating edges of these terraces were found to include 120 degrees and 60 degrees angles, thus perfectly reflecting the hexagonal surface structure. 相似文献
202.
AFM single molecule experiments at the solid-liquid interface: in situ conformation of adsorbed flexible polyelectrolyte chains 总被引:2,自引:0,他引:2
This paper reports the in situ study of conformations of flexible synthetic polymer molecules of protonated poly(2-vinylpyridine) at the solid-liquid interface at different pH of aqueous solutions. The direct conformation study of such thin ( approximately 0.4 nm) single molecules under liquid is performed for the first time. The highly protonated poly(2-vinylpyridine) chains possess a conformation of 2D equilibrated random coil, while at low degree of protonation, molecules are in the conformation of a strongly compressed 3D coil. Molecules are immobile during the few hours of the AFM experiment. 相似文献
203.
Very accurate calculations of the pure vibrational spectrum of the HeH(+) ion are reported. The method used does not assume the Born-Oppenheimer approximation, and the motion of both the electrons and the nuclei are treated on equal footing. In such an approach the vibrational motion cannot be decoupled from the motion of electrons, and thus the pure vibrational states are calculated as the states of the system with zero total angular momentum. The wave functions of the states are expanded in terms of explicitly correlated Gaussian basis functions multipled by even powers of the internuclear distance. The calculations yielded twelve bound states and corresponding eleven transition energies. Those are compared with the pure vibrational transition energies extracted from the experimental rovibrational spectrum. 相似文献
204.
An enantioselective total synthesis of the diterpenoid natural product (+)-salvileucalin B is reported. Key findings include a copper-catalyzed arene cyclopropanation reaction to provide the unusual norcaradiene core and a reversible retro-Claisen rearrangement of a highly functionalized norcaradiene intermediate. 相似文献
205.
A continuous quadratic polynomial spline of several variables is constructed. It solves the optimal recovery problem studied
by V.F. Babenko, S.V. Borodachov, and D.S. Skorokhodov for the class of functions defined on a convex polytope in R
d
, whose second derivatives in any direction are uniformly bounded, and for a periodic analogue of this class. The information
consists of the values and gradients of the function at some finite set of nodes in R
d
. 相似文献
206.
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209.
Lennart Fries Sergiy Antonyuk Stefan Heinrich Gerhard Niederreiter Stefan Palzer 《Particuology》2014,(1):13-24
Fluidized bed agglomeration is a process commonly used to construct powdered food or pharmaceuti cal products to improve their instant properties. This works analyzes the influence of a wide range of operating parameters (i.e., fluidization air flow rate, temperature, and liquid injection rate) on growth rate, process stability, and product particle structure. Different granulator configurations (i.e., top spray, Wurster coater, spouted bed) are compared using identical process parameters. The impacts of both pro cess variables and granulator geometry on the fluidization regime, the particle and collision dynamics, and the resulting product structure and corresponding properties are studied in detailed simulations using a discrete particle model (DPM) and labscale agglomeration experiments with amorphous dextrose syrup (DE21). The combination of numerical and experimental results allows to correlate the kinetics of micro scale particle interactions and the final product properties (i.e., agglomerate structure and strength). In conclusion, detailed DPM simulations are proven as a valuable tool for knowledgebased product design. 相似文献
210.
An effect of appearance of new band in the excitation spectra of 3-hydroxy-4′-(dimethylamino)flavone (FME probe) in presence
of adenosine triphosphate (ATP) is described. Considerable shift of new band up to the red and increase of fluorescence intensity
points to the formation of FME-ATP associate, in which FME molecule undergoes to a strong electrostatic stabilization by tetra-charged
ATP anion. It is shown the FME anion formation is possible under influence of ATP in the studied conditions. The dynamics
of the observed effect is studied in mitochondria. The registered phenomenon allows the quantitative evaluation of ATP concentration
in the range of 10−3–10−5 M. In contrast to ATP, other nucleoside phosphates do not give a new band in the excitation spectra of FME probe. This implies
the possibility of the in vivo determination of the ATP concentration. 相似文献