High-Energy Ejection of Molecules and Gas-Dust Outbursts in Coal Mines

In the current work, using the framework of the formalism found in the Bogolyubov–Born–Green–Kirkwood–Yvon (BBGKY) equations for the distribution functions of particle groups, the effective single-particle potential near the surface of the liquid was analyzed. The thermodynamic conditions under which a sudden opening of the liquid surface leads to high-energy ejection of atoms and molecules were found. The energies of the emitted particles were observed to be able to significantly exceed their thermal energy. Criteria of the ejection stability of the liquid surface and the self-acceleration of ejection were formulated. The developed theory was used to explain the phenomenon of the self-acceleration of gas-dust outbursts in coal mines during the explosive opening of methane traps. The results also explained the mechanisms of generating significant amounts of methane and the formation of coal nanoparticles in gas-dust outbursts. The developed approach was also used to explain the phenomenon of the self-ignition of hydrogen when it enters the atmosphere.     

Terpenoid Hydrazones as Biomembrane Penetration Enhancers: FT-IR Spectroscopy and Fluorescence Probe Studies

Hydrazones based on mono- and bicyclic terpenoids (verbenone, menthone and carvone) have been investigated in vitro as potential biomembrane penetration enhancers. In this regard, liposomes composed of lecithin or cardiolipin as phospholipid phase components with incorporated fluorescence probes have been prepared using the thin-film ultrasonic dispersion method. The mean particle size of the obtained liposomes, established using laser diffraction, was found to be 583 ± 0.95 nm, allowing us to categorize them as multilamellar vesicles (MLVs) according to their morphology. Pursuant to fluorescence analysis, we may assume a reduction in microviscosity and, consequently, a decrease in the packing density of lecithin and cardiolipin lipids to be the major mechanism of action for terpenoid hydrazones 1–15. In order to determine the molecular organization of the lipid matrix, lipids were isolated from rat strata cornea (SCs) and their interaction with tested compounds was studied by means of Fourier transform infrared spectroscopy. FT-IR examination suggested that these hydrazones fluidized the SC lipids via the disruption of the hydrogen-bonded network formed by polar groups of SC constituents. The relationship between the structure of terpenoid hydrazones and their ability to enhance biomembrane penetration is discussed.     

Determination of the proton and neutron densities at the nuclear periphery with antiprotonic X-rays and \overline p -nucleus reactions

The nucleon density at the nuclear periphery has been investigated with two different methods. The first one is the measurement of the energy shift and the width of antiprotonic X-ray lines. Besides various other nuclides the X-rays from the isotopes ¹⁷²Yb and ¹⁷⁶Yb have been measured very extensively. From these data the absorption widths of six antiprotonic levels and the shifts of the lowest visible transitions could be determined. The comparison of the experimental intensities of the transitions with results from calculations of the antiprotonic cascade showed a good agreement. The second method is the determination of the yield of the annihilation products from the reaction of the antiprotons with nuclei. From this the neutron-to-proton density ratio at a distance of about 3 fm outside the half-density radius can be determined. This method was extended to short-lived residual nuclei with a half-life down to 5 s. The experiment confirmed the previously found negative correlation between the size of the neutron skin and the binding energy of the last neutron. The results have been compared with calculations. For many nuclei a good agreement was found between experiment and calculation, however for some nuclei measured and calculated values are at variance. This revised version was published online in August 2006 with corrections to the Cover Date.     

On defects in aluminium single crystal thin films

Defects in Al single crystal thin films prepared by epitaxial growth on mica were investigated by transmission electron microscopy. Dislocations, subgrain boundaries, grain of different orientation and separated polycrystalline regions were observed in the single crystal matrix with density dependent on the pressure of residual gases.     

Photoswitchable Dissipative Two‐Dimensional Colloidal Crystals

Control over particle interactions and organization at fluid interfaces is of great importance both for fundamental studies and practical applications. Rendering these systems stimulus‐responsive is thus a desired challenge both for investigating dynamic phenomena and realizing reconfigurable materials. Here, we describe the first reversible photocontrol of two‐dimensional colloidal crystallization at the air/water interface, where millimeter‐sized assemblies of microparticles can be actuated through the dynamic adsorption/desorption behavior of a photosensitive surfactant added to the suspension. This allows us to dynamically switch the particle organization between a highly crystalline (under light) and a disordered (in the dark) phase with a fast response time (crystallization in ≈10 s, disassembly in ≈1 min). These results evidence a new kind of dissipative system where the crystalline state can be maintained only upon energy supply.     

Solid Phase Luminescence and Thermal Transformations of Palladium(II) Complexes with 3-(2-Pyridyl)-1,2,4-Triazoles

Theoretical and Experimental Chemistry - The thermal behavior and luminescent properties of palladium(II) Pd(LR)2 complexes with 3-(2-pyridyl)-5-R-1,2,4-triazoles (LR , where R = H, Ph, Me) in...     

On solutions of a quasilinear differential second-order system represented by Fourier series with slowly varying parameters in some critical cases

We study a quasilinear second-order differential system whose coefficients are represented in the form of absolutely and uniformly convergent Fourier series with slowly varying coefficients and the frequency. The conditions of existence of a particular solution of a similar structure are obtained in the case where the eigenvalues of the matrix of the linear part of the system are equal to zero.