全文获取类型
收费全文 | 34135篇 |
免费 | 978篇 |
国内免费 | 254篇 |
专业分类
化学 | 23523篇 |
晶体学 | 223篇 |
力学 | 807篇 |
数学 | 5743篇 |
物理学 | 5071篇 |
出版年
2022年 | 294篇 |
2021年 | 434篇 |
2020年 | 522篇 |
2019年 | 505篇 |
2018年 | 392篇 |
2017年 | 384篇 |
2016年 | 865篇 |
2015年 | 776篇 |
2014年 | 846篇 |
2013年 | 1820篇 |
2012年 | 1947篇 |
2011年 | 2470篇 |
2010年 | 1205篇 |
2009年 | 1065篇 |
2008年 | 2116篇 |
2007年 | 2102篇 |
2006年 | 2069篇 |
2005年 | 1932篇 |
2004年 | 1671篇 |
2003年 | 1421篇 |
2002年 | 1326篇 |
2001年 | 416篇 |
2000年 | 409篇 |
1999年 | 376篇 |
1998年 | 352篇 |
1997年 | 367篇 |
1996年 | 499篇 |
1995年 | 353篇 |
1994年 | 311篇 |
1993年 | 280篇 |
1992年 | 273篇 |
1991年 | 244篇 |
1990年 | 210篇 |
1989年 | 209篇 |
1988年 | 236篇 |
1987年 | 200篇 |
1986年 | 182篇 |
1985年 | 354篇 |
1984年 | 349篇 |
1983年 | 246篇 |
1982年 | 316篇 |
1981年 | 327篇 |
1980年 | 305篇 |
1979年 | 289篇 |
1978年 | 273篇 |
1977年 | 231篇 |
1976年 | 212篇 |
1975年 | 215篇 |
1974年 | 216篇 |
1973年 | 215篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
51.
The structures and energetics of Li(6) (+), Li(6) (-) and three isomers of Li(6) are investigated using the coupled-cluster singles, doubles and perturbative triples [CCSD(T)] method with valence and core-valence correlation consistent basis sets of double- to quadruple-zeta quality (cc-pVXZ and cc-pCVXZ, where X=D-Q). These results are compared with qualitatively different predictions by less reliable methods. Our results conclusively show that the D(4h) isomer is the global minimum structure for Li(6). It is energetically favored over the C(5v) and D(3h) structures by about 5.1 and 7.1 kcal mol(-1), respectively, after the inclusion of the zero-point vibrational energy (ZPVE) correction. Our most accurate total atomization energies are 123.2, 117.6, and 115.7 kcal mol(-1) for the D(4h), C(5v), and D(3h) isomers, respectively. Comparison of experimental optical absorption spectra with our computed electronic spectra also indicate that the D(4h) isomer is indeed the most stable structure. The cation, anion, and some higher spin states are investigated using the less expensive cc-pCVDZ basis set. Adiabatic ionization energies and electron affinities are reported and compared with experimental values. Predictions of molecular properties are found to be sensitive to the basis set used and to the treatment of electron correlation. 相似文献
52.
The alkylhalide-halide association ions, [RX2]? that are observed in the negative chemical ionization mass spectra of alkyl halides appear to be directly related to the corresponding SN2 transition states in solution. ‘Frontside’ association of halide ions with bridgehead alkyl halides does not occur in our system. The Change in heats and entropies of association for the chloromethane series is consistent with delocalization in the [RX]2? ions. 相似文献
53.
Balakumar A Lysenko AB Carcel C Malinovskii VL Gryko DT Schweikart KH Loewe RS Yasseri AA Liu Z Bocian DF Lindsey JS 《The Journal of organic chemistry》2004,69(5):1435-1443
A molecular approach to information storage employs redox-active molecules tethered to an electroactive surface. Attachment of the molecules to electroactive surfaces requires control over the nature of the tether (linker and surface attachment group). We have synthesized a collection of redox-active molecules bearing different linkers and surface anchor groups in free or protected form (hydroxy, mercapto, S-acetylthio, and Se-acetylseleno) for attachment to surfaces such as silicon, germanium, and gold. The molecules exhibit a number of cationic oxidation states, including one (ferrocene), two [zinc(II)porphyrin], three [cobalt(II)porphyrin], or four (lanthanide triple-decker sandwich compound). Electrochemical studies of monolayers of a variety of the redox-active molecules attached to Si(100) electrodes indicate that molecules exhibit a regular mode of attachment (via a Si-X bond, X = O, S, or Se), relatively homogeneous surface organization, and robust reversible electrochemical behavior. The acetyl protecting group undergoes cleavage during the surface deposition process, enabling attachment to silicon via thio or seleno groups without handling free thiols or selenols. 相似文献
54.
Martin B. Hocking David T. Syme David E. Axelson Kirk H. Michaelian 《Journal of polymer science. Part A, Polymer chemistry》1990,28(11):2969-2982
The comonomer required, p-maleimidobenzoic acid (MBA) was first prepared in good yield by refinements of published methods. p-Carboxysuccinanilic acid (CSA), and p-succinimidobenzoic acid (SBA), were also prepared to provide models useful for IR and NMR for spectroscopic assignments of the new copolymers. Polymerization of MBA with acrylamide in glacial acetic acid at 60°C gave copolymers with estimated viscosity average molecular weights of 60,000 to 90,000. Yields and viscosity average molecular weights decreased as the MBA to acrylamide monomer feed ratio was increased. The rate of incorporation of MBA into the copolymer rose from 7 to 23% when the mole ratio in the feed was raised from 5 to 20%. Decreasing the initiator concentration increased molecular weights by less than predicted and reduced the yield of copolymer for any given feed ratio of MBA to acrylamide. In all cases about 30–40% of the MBA units in the purified copolymers were hydrolyzed. A change to dimethyl sulfoxide solvent gave good, and poor yields of copolymer at 5 and 10 mol % MBA, respectively, and no copolymer at 20 mol % MBA. Viscosity average molecular weights of the copolymer products prepared in DMSO were somewhat lower than obtained for the copolymers prepared in acetic acid. Polymerization in a DMSO-water mixture gave a negligible yield of polymeric product. Instead, only hydrolysates of MBA precipitated when the coloured polymerization solutions were added to methanol. 相似文献
55.
Fluorescence emission spectra indicate that oligomers containing both hematoporphyrin and its dehydration products (vinyl porphyrins) comprise the tumor-localizing fraction of HPD. In the relatively polar solvent methanol, the vinyl porphyrins exhibit reduced fluorescence yields while the hematoporphyrin residues are relatively resistant to fluorescence quenching by Fe+3. In the less polar solvent tetrahydrofuran, fluorescence from oligomeric vinyl porphyrins was enhanced, and Fe+3-induced quenching of oligomeric hematoporphyrin promoted. These, together with other studies in biological systems, suggest a substantial degree of interaction among the porphyrin units contained in these oligomers, as a function of the polarity of the environment. 相似文献
56.
Useful procedures for preparing a novel tetraazacyclotetradecadiene and a pentaazacyclotetradecatriene are reported. J. Heterocyclic Chem., 14, 1097 (1977) 相似文献
57.
The synthesis of alkylarylphosphines is easily carried out by hydrophosphination of unactivated alkenes under mild thermal activation; gram scale amounts of products can be prepared by this simple methodology. 相似文献
58.
The photodegradation of 1,3-dimethyl-1-(2-(3-fluorobenzylthio)-1,3,4-thiadiazol-5-yl)urea as a thin film and in solution is described. The two photoproducts from thin-film photolysis were characterized by spectral and synthetic methods. The X-ray crystal structure of one of the photoproducts is also reported. The rearrangements were shown to involve an S-to-N benzyl migration, followed by a sulfur-oxygen substitution. 相似文献
59.
An SCF perturbation method for investigating the effects of an arbitrary change in nuclear configuration on the electronic structure of a molecule is reported. Illustrative calculations for CO2 and CH3OH are presented. It is found that, when taken to second order, the error in the calculated change in energy which results from a change in nuclear configuration is typically in the range of 0.1 to 7%. 相似文献
60.
Dr. F. David Peat 《Theoretical chemistry accounts》1972,24(1):11-15
It is suggested that certain transition density matrices, N-representable in a limit, be used in a variational calculation. It is noted that such trial matrices should yield reasonable values for the ground state energies of small atoms or molecules provided a set of overlap integrals is maximised.
Zusammenfassung Es wird vorgeschlagen, bestimmte Übergangsdichtematrizen, die im Limit N-darstellbar sind, in einer Variationsrechnung zu benutzen. Es wird festgestellt, daß solche Näherungsmatrizen gute Werte für die Energie des Grundzustandes kleiner Atome oder Moleküle geben sollten, falls im Satz von Überlappungsintegralen maximiert wird.
Résumé On propose d'utiliser dans un calcul variationnel certaines matrices densité de transition, N représentables à la limite. Ces matrices d'essai devraient fournir des valeurs raissonnables pour l'énergie de l'état fondamental dans les petits atomes et les petites molécules à condition de maximiser un ensemble d'intégrales de recouvrement.相似文献