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141.
142.
Explicit equations which take into account the effect of sphericity of the DME on the current—potential curves with EC and CE mechanisms accompanied by Nernstian behavior have been derived in a rigorous way. These equations have been obtained without using the steady-state approximation and therefore they are valid without any limitation in the magnitude of rate constants of the chemical reaction. 相似文献
143.
Bing Wang L.M. Molina M.J. Lpez A. Rubio J. A. Alonso M. J. Stott 《Annalen der Physik》1998,510(2):107-119
We have performed ab initio total-energy pseudopotential calculations on neutral and negatively charged Snn and Pbn (n = 3 ? 10) clusters. The lowest energy structures have been determined for all clusters, and the stabilities of neutral clusters were investigated by comparing their evaporation energies and stability functions. Clusters with n = 7,10 were found to be most stable while the clusters with n = 8 and Pbs were much less stable, in agreement with features of the observed mass spectra. Calculations on Sn?n and Pb?n show that both atomic and electronic structures of a neutral cluster change substantially upon charging. The densities of states of Sn?n clusters reproduce the main features of the experimental photoelectron spectra. The agreement is poorer for Pb?n clusters where the calculations underestimate the separation between energy levels which we think is due to the larger spin-orbit splitting in Pb, which was neglected in the calculations. We found that the differences between Sn and Pb clusters cannot be completely addressed without a more complete accounting of relativistic effects. The electron affinities of Snn and Pbn clusters have also been calculated and the results agree fairly well with experimental values. Finally we considered Sn2?4 and Pb2?4 clusters and related the results to the formation of Zintl anions in liquid alkali-Sn and alkali-Pb alloys. 相似文献
144.
Santos Blanco Francisco J Molina Lourdes Castro Maria L Del Moral Raquel Hernandez Ana Jimenez Alma Rus Esther Martinez-Lara Eva Siles Maria A Peinado 《BMC neuroscience》2010,11(1):78
Background
The cerebellum is the neural structure with the highest levels of nitric oxide, a neurotransmitter that has been proposed to play a key role in the brain aging, although knowledge concerning its contribution to cerebellar senescence is still unclear, due mainly to absence of integrative studies that jointly evaluate the main factors involved in its cell production and function. Consequently, in the present study, we investigate the expression, location, and activity of nitric oxide synthase isoenzymes; the protein nitration; and the production of nitric oxide in the cerebellum of adult and old rats. 相似文献145.
J. A. López Molina M. E. Puerta M. J. Rivera 《Bulletin of the Brazilian Mathematical Society》2006,37(2):191-216
Let
, be a family of compatible couples of Lp-spaces. We show that, given a countably incomplete ultrafilter
in
, the ultraproduct
of interpolation spaces defined by the real method is isomorphic to the direct sum of an interpolation space of type
, an intermediate K?the space between
and
being a purely atomic measure space, and a K?the function space K(Ω3) defined on some purely non atomic measure space (Ω3, ν3) in such a way that Ω2 ∪ Ω3 ≠∅.
The research of first and third authors is partially supported by the MEC and FEDER project MTM2004-02262 and AVCIT group
03/050. 相似文献
146.
Kretz T Bats JW Losi S Wolf B Lerner HW Lang M Zanello P Wagner M 《Dalton transactions (Cambridge, England : 2003)》2006,(41):4914-4921
Cationic dinuclear Cu(II) complexes 3 and 4 have been prepared using the novel hydroquinone-based imine chelators 2,5-((i)Pr(2)NCH(2)CH(2)N[double bond, length as m-dash]CH)(2)-1,4-(OH)(2)-C(6)H(2) (1) and 2,5-(pyCH(2)CH(2)N[double bond, length as m-dash]CH)(2)-1,4-(OH)(2)-C(6)H(2) (2), respectively (py = 2-pyridyl). X-Ray quality crystals of both complexes were grown from their DMF solutions. The sterically more encumbered compound crystallizes in the form of discrete dinuclear entities with Cu(II) centres in a distorted square-planar ligand environment (one coordination site is occupied by a DMF molecule). The pyridyl derivative 4 features dinuclear hydroquinone-bridged subunits similar to 3. However, the Cu(II) ions are now six-coordinate with two DMF molecules at an axial and an equatorial position of a Jahn-Teller-distorted octahedron. Moreover, the dinuclear subunits are no longer isolated but linked with each other via bridging hydroquinone oxygen atoms which occupy the second apical position of each octahedron. The structure suggests that the magnetic properties of the resulting coordination polymer of 4 could be described by a model valid for dimerized spin chains. As a result of this analysis the antiferromagnetic coupling constants J(1)/k(B) = 9.9 K (intradimer) and J(2)/k(B) = 0.9 K (interdimer) are obtained. Both in 3 and in 4, the hydroquinone --> semiquinone transition of the central bridging unit (E degrees ' = + 0.57 V, 3; E degrees ' = + 0.51 V, 4; DMF; vs. SCE) displays features of chemical reversibility. In the case of , reduction of Cu(II) centres requires a peak potential of E(p) = - 0.42 V. 相似文献
147.
Corr SA O'Byrne A Gun'ko YK Ghosh S Brougham DF Mitchell S Volkov Y Prina-Mello A 《Chemical communications (Cambridge, England)》2006,(43):4474-4476
Fluorescent magnetite nanocomposites based on magnetic nanoparticles, a polyhedral octaaminopropylsilsesquioxane and a porphyrin derivative have been prepared. The intracellular uptake of the nanocomposites by macrophage and bone osteoblast cells, and their potential as MRI contrast agents, has been demonstrated. 相似文献
148.
Aamodt K Abelev B Quintana AA Adamová D Adare AM Aggarwal MM Rinella GA Agocs AG Salazar SA Ahammed Z Masoodi AA Ahmad N Ahn SU Akindinov A Aleksandrov D Alessandro B Molina RA Alici A Alkin A Aviña EA Alt T Altini V Altinpinar S Altsybeev I Andrei C Andronic A Anguelov V Anson C Antičić T Antinori F Antonioli P Aphecetche L Appelshäuser H Arbor N Arcelli S Arend A Armesto N Arnaldi R Aronsson T Arsene IC Asryan A Augustinus A Averbeck R Awes TC Aystö J Azmi MD Bach M Badalà A Baek YW 《Physical review letters》2010,105(25):252301
The first measurement of the charged-particle multiplicity density at midrapidity in Pb-Pb collisions at a center-of-mass energy per nucleon pair √ S NN = 2.76 TeV is presented. For an event sample corresponding to the most central 5% of the hadronic cross section, the pseudorapidity density of primary charged particles at midrapidity is 1584 ± 4(stat) ± 76(syst), which corresponds to 8.3 ± 0.4(syst) per participating nucleon pair. This represents an increase of about a factor 1.9 relative to pp collisions at similar collision energies, and about a factor 2.2 to central Au-Au collisions at √ S NN = 2.76 TeV. This measurement provides the first experimental constraint for models of nucleus-nucleus collisions at LHC energies. 相似文献
149.
Aamodt K Abelev B Quintana AA Adamová D Adare AM Aggarwal MM Rinella GA Agocs AG Salazar SA Ahammed Z Masoodi AA Ahmad N Ahn SU Akindinov A Aleksandrov D Alessandro B Molina RA Alici A Alkin A Aviña EA Alt T Altini V Altinpinar S Altsybeev I Andrei C Andronic A Anguelov V Anson C Antičić T Antinori F Antonioli P Aphecetche L Appelshäuser H Arbor N Arcelli S Arend A Armesto N Arnaldi R Aronsson T Arsene IC Asryan A Augustinus A Averbeck R Awes TC Aystö J Azmi MD Bach M Badalà A Baek YW 《Physical review letters》2010,105(25):252302
We report the first measurement of charged particle elliptic flow in Pb-Pb collisions at sqrt[S(NN)] =2.76 TeV with the ALICE detector at the CERN Large Hadron Collider. The measurement is performed in the central pseudorapidity region (|η|<0.8) and transverse momentum range 0.2
相似文献
150.
Let be a tree. We show that the null space of the adjacency matrix of has relevant information about the structure of . We introduce the Null Decomposition of trees, which is a decomposition into two different types of trees: N-trees and S-trees. N-trees are the trees that have a unique maximum (perfect) matching. S-trees are the trees with a unique maximum independent set. We obtain formulas for the independence number and the matching number of a tree using this decomposition. We also show how the number of maximum matchings and the number of maximum independent sets in a tree are related to its null decomposition. 相似文献