Highly selective immobilization of Au nanoparticles onto isolated and dense nanopatterns of poly(2-vinyl pyridine) brushes down to single-particle resolution

Chemical patterns consisting of poly(2-vinyl pyridine) (P2VP) brushes in a background of a cross-linked polystyrene (PS) mat enabled the highly selective placement of citrate-stabilized Au nanoparticles (NPs) in arrays on surfaces. The cross-linked PS mat prevented the nonspecific binding of Au NPs, and the regions functionalized with P2VP brushes allowed the immobilization of the particles. Isolated chemical patterns of feature sizes from hundreds to tens of nanometers were prepared by standard lithographic techniques. The number of 13 nm Au NPs bound per feature increased linearly with increasing area of the patterns. This behavior is similar to previous reports using 40 nm particles or larger. Arrays of single NPs were obtained by reducing the dimensions of patterned P2VP brushes to below ~20 nm. To generate dense (center-to-center distance = 80 nm) linear chemical patterns for the placement of rows of single NPs, a block-copolymer (BCP)-assisted lithographic process was used. BCPs healed defects associated with the standard lithographic patterning of small dimensions at high densities and led to highly registered, linear, single NP arrays.     

Non-line-of-sight sound source localization using matched-field processing

Acoustic diffraction allows sound to travel around opaque objects and therefore may allow beyond-line-of-sight sensing of remote sound sources. This paper reports simulated and experimental results for localizing sound sources based on fully shadowed microphone array measurements. The generic geometry includes a point source, a solid 90° wedge, and a receiving array that lies entirely in the shadow defined by the source location and the wedge. Source localization performance is assessed via matched-field (MF) ambiguity surfaces as a function of receiving array configuration, and received signal-to-noise ratio for the Bartlett and minimum variance distortionless (MVD) MF processors. Here, the sound propagation model is developed from a Green's function integral treatment. A simple 16 element line array of microphones is tested in three mutually orthogonal orientations. The experiments were conducted using an approximate 50-to-1-scaled tabletop model of a blind city-street intersection and produced ambiguity surfaces from source frequencies between 17.5 and 19 kHz that were incoherently summed. The experimental results suggest that a sound source may be localized by the MVD processor when using fully shadowed arrays that have significant aperture parallel to the edge of the wedge. However, this performance is reduced significantly for signal-to-noise ratios below 40 dB.     

A thermodynamical consistent model for modeling of ionic electroactive polymers (EAPs) within the framework of the Theory of Porous Media

Ionic electroactive polymers are widely used in many engineering fields. These kind of materials can be stimulated to change their shape and size, see [1]. Since, the material under consideration has a complex multiphasic microstructure, such multiphasic materials are best described by a continuum mechanical approach. Thus, the presented model is based on the Theory of Porous Media (TPM), cf. [2]. In this contribution, we consider the Ionic Polymer Metal Composites (IPMCs). Stimulating by an electrical voltage, a structural deformation will be caused. Responsible for this deformation are the mobile ions. The focus of the presented model is to capture this material behavior, e.g. the distribution of the mobile cations. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Application of a Viscoelastic Material Model in Electro-Mechanics

In this contribution, the numerical modeling of electro-viscoelastic material is considered. The electro-mechanical problem formulated in terms of a symmetrized stress tensor is extended to a viscoelastic material model. For the incorporation of the viscosity model, the logarithmic strain space setting is utilized which mimics the small strain setting. Therefore a rheological model for viscosity from the geometrically linear theory can be used. Numerical examples for a typical uniaxial tensile test show the capability of the method to demonstrate typical relaxation and creep behavior. (© 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)