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31.
A new method based on microcolumn packed with ionic liquid-modified silica combined with flame atomic absorption spectrometry has been developed for the determination of lead in environmental samples. Several factors influencing the preconcentration efficiency of lead and its subsequent determination, such as pH of the sample, flow rate, mass of ionic liquid, and interfering effect, have been investigated. Lead could be quantitatively retained by ionic liquid-modified silica in the pH range of 5-7, and then eluted completely with 3.0 mL 1.0 mol L−1 HCl. The detection limit of this method for lead was 0.7 μg L−1 with preconcentration factor of 185, and the relative standard deviation (RSD) was 4.2% at 0.1 μg mL−1 Pb(II). This method has been applied for the determination of trace amount of lead in NIST standard reference material 2709 (San Joaquin Soil) and river water samples with satisfactory results. 相似文献
32.
A gas chromatographic-mass spectrometric method was developed, validated and demonstrated by measuring the levels of nitrogen mustard hydrolysis products in the urine collected from dosed rats. The recovery values for trimethylsilyl derivatives of EDEA and MDEA are between 82-95% and 88-112%, respectively. In vivo studies performed by using three different doses (0.5 mg/kg, 1.0 mg/kg, and 2.0 mg/kg) of HN2 base of nitrogen mustard. MDEA concentrations were between 43.1-232.2 ng/mL. The limit of detection (S/N = 3) values are 2.5 ng/mL and 1.6 ng/mL for EDEA and MDEA, respectively, and the precision of the method in terms of RSD is between 5-8%. 相似文献
33.
Chang TY Huang M Yanik AA Tsai HY Shi P Aksu S Yanik MF Altug H 《Lab on a chip》2011,11(21):3596-3602
Microarrays allowing simultaneous analysis of thousands of parameters can significantly accelerate screening of large libraries of pharmaceutical compounds and biomolecular interactions. For large-scale studies on diverse biomedical samples, reliable, label-free, and high-content microarrays are needed. In this work, using large-area plasmonic nanohole arrays, we demonstrate for the first time a large-scale label-free microarray technology with over one million sensors on a single microscope slide. A dual-color filter imaging method is introduced to dramatically increase the accuracy, reliability, and signal-to-noise ratio of the sensors in a highly multiplexed manner. We used our technology to quantitatively measure protein-protein interactions. Our platform, which is highly compatible with the current microarray scanning systems can enable a powerful screening technology and facilitate diagnosis and treatment of diseases. 相似文献
34.
Starovoitova V Budarz TE Wyllie GR Scheidt WR Sturhahn W Alp EE Prohofsky EW Durbin SM 《The journal of physical chemistry. B》2006,110(26):13277-13282
The normal-mode spectrum for the four-coordinated heme compound Fe(II) octaethylporphyrin, Fe(OEP), has been determined by refining force constants to the experimental Fe vibrational density of states measured with nuclear resonance vibrational spectroscopy (NRVS). Convergence of the calculated spectrum to the data was achieved by first imposing D4 symmetry on the model structure as well as the force constants, progressively including different internal coordinates of motion, then allowing the true Ci (or S2) point group symmetry of the C(i)1 Fe(OEP) crystal structure. The NRVS-refined normal modes are in good agreement with Raman and IR spectra at high frequencies. Prior density functional theory predictions for a model porphyrin are similar to the core modes computed with the best-fit force field, but significant differences between D4 and Ci modes underline the sensitivity of porphyrin Fe normal modes to structural details. Some differences between the Ci best fit and the NRVS data can be attributed to intermolecular contacts not included in the normal-mode analysis. 相似文献
35.
In this paper we introduce and study the notion of a graded (strongly) nil clean ring which is group graded. We also deal with extensions of graded (strongly) nil clean rings to graded matrix rings and to graded group rings. The question of when nil cleanness of the component, which corresponds to the neutral element of a group, implies graded nil cleanness of the whole graded ring is examined. Similar question is discussed in the case of groupoid graded rings as well. 相似文献
36.
Merve??lkhan P?nar?Zengin Alp Emrah?Evren?KaraEmail author 《Mediterranean Journal of Mathematics》2018,15(3):136
An asymmetric norm is a positive sublinear functional p on a real vector space X satisfying \(x=\theta _X\) whenever \(p(x)=p(-x)=0\). Since the space of all lower semi-continuous linear functionals of an asymmetric normed space is not a linear space, the theory is different in the asymmetric case. The main purpose of this study is to define bounded and continuous linear operators acting between asymmetric cone normed spaces. After examining the differences with symmetric case, we give some results related to Baire’s characterization of completeness in asymmetric cone normed spaces. 相似文献
37.
The concept of efficiency in data envelopment analysis (DEA) is defined as weighted sum of outputs/weighted sum of inputs. In order to calculate the maximum efficiency score, each decision making unit (DMU)’s inputs and outputs are assigned to different weights. Hence, the classical DEA allows the weight flexibility. Therefore, even if they are important, the inputs or outputs of some DMUs can be assigned zero (0) weights. Thus, these inputs or outputs are neglected in the evaluation. Also, some DMUs may be defined as efficient even if they are inefficient. This situation leads to unrealistic results. Also to eliminate the problem of weight flexibility, weight restrictions are made in DEA. In our study, we proposed a new model which has not been published in the literature. We describe it as the restricted data envelopment analysis ((ARIII(COR))) model with correlation coefficients. The aim for developing this new model, is to take into account the relations between variables using correlation coefficients. Also, these relations were added as constraints to the CCR and BCC models. For this purpose, the correlation coefficients were used in the restrictions of input–output each one alone and their combination together. Inputs and outputs are related to the degree of correlation between each other in the production. Previous studies did not take into account the relationship between inputs/outputs variables. So, only with expert opinions or an objective method, weight restrictions have been made. In our study, the weights for input and output variables were determined, according to the correlations between input and output variables. The proposed new method is different from other methods in the literature, because the efficiency scores were calculated at the level of correlations between the input and/or output variables. 相似文献
38.
Lena Scherthan Sebastian F. M. Schmidt Hendrik Auerbach Tim Hochdrffer Juliusz A. Wolny Wenli Bi Jiyong Zhao Michael Y. Hu Tom Toellner E. Ercan Alp Dennis E. Brown Christopher E. Anson Annie K. Powell Volker Schünemann 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(11):3482-3487
Time‐domain synchrotron Mössbauer spectroscopy (SMS) based on the Mössbauer effect of 161Dy has been used to investigate the magnetic properties of a DyIII‐based single‐molecule magnet (SMM). The magnetic hyperfine field of [Dy(Cy3PO)2(H2O)5]Br3?2 (Cy3PO)?2 H2O?2 EtOH is with B0=582.3(5) T significantly larger than that of the free‐ion DyIII with a 6H15/2 ground state. This difference is attributed to the influence of the coordinating ligands on the Fermi contact interaction between the s and 4f electrons of the DyIII ion. This study demonstrates that 161Dy SMS is an effective local probe of the influence of the coordinating ligands on the magnetic structure of Dy‐containing compounds. 相似文献
39.
Dağlı Özge Köse Dursun Ali İçten Okan Avcı Gülçin Alp Şahin Onur 《Journal of Thermal Analysis and Calorimetry》2019,136(4):1467-1480
Journal of Thermal Analysis and Calorimetry - The coumarilate (coum?) and 1,10-phenanthroline (phen) mixed ligand complexes of Co(II) (1), Ni(II) (2) Cu(II) (3) and Zn(II) (4) were... 相似文献
40.
Liu D Chu XQ Lagi M Zhang Y Fratini E Baglioni P Alatas A Said A Alp E Chen SH 《Physical review letters》2008,101(13):135501
Molecular dynamics simulations and neutron scattering experiments have shown that many hydrated globular proteins exhibit a universal dynamic transition at TD = 220 K, below which the biological activity of a protein sharply diminishes. We studied the phononlike low-energy excitations of two structurally very different proteins, lysozyme and bovine serum albumin, using inelastic x-ray scattering above and below TD. We found that the excitation energies of the high-Q phonons show a marked softening above TD. This suggests that the large amplitude motions of wavelengths corresponding to this specific Q range are intimately correlated with the increase of biological activities of the proteins. 相似文献