基于FCS的海水痕量元素的通用测定平台

为了对海水痕量营养盐与重金属进行测定,基于FCS的设计思想,采用流动注射分光光度法研制了具有自适应外界设备、快速组建多种仪器及全数字化通信等特点的软硬件一体化的通用测定平台。平台以ARM(S3C2416)处理器为核心,Linux为操作系统,LCD作为人机交互显示,触摸屏或者USB鼠标完成输入控制,构成完整的嵌入式工控机系统;采用CAN总线并制定CAN应用层协议管理设备,提高了系统的可靠性及抗干扰能力。实际测试和应用证明,该平台自动化程度高,通用性、重用性及可扩展性均较强,可组建成亚硝氮、硝氮、氨氮、活性磷、铁等多种痕量元素的实验室、船载和原位分析系统,检测限为nmol/L级别。平台对样品的测试准确度与商品专用仪器无显著性差异。     

智能弹药的实时仿真可视化系统设计

针对仿真可视化系统开发时间长、开发费用高的问题,提出了一种利用Unity3D引擎进行实时仿真可视化系统开发的模块式设计方法。首先,对武器仿真可视化系统进行了分析,提出了智能弹药实时仿真可视化系统的五大模块;然后,通过在3ds Max下建立智能弹药模型和Unity3D下的二次开发,构建了智能弹药仿真可视化系统的仿真环境,以C#为编程工具,设计了仿真驱动、串口数据通讯和仿真输出模块;最终,实现了智能弹药实时仿真可视化系统。实验证明,该系统可以有效地在监视器上实时显示出智能弹药的飞行姿态、飞行参数和飞行轨迹。     

Edge Flips in Surface Meshes

Little theoretical work has been done on edge flips in surface meshes despite their popular usage in graphics and solid modeling to improve mesh equality. We propose the class of \((\varepsilon ,\alpha )\)-meshes of a surface that satisfy several properties: the vertex set is an \(\varepsilon \)-sample of the surface, the triangle angles are no smaller than a constant \(\alpha \), some triangle has a good normal, and the mesh is homeomorphic to the surface. We believe that many surface meshes encountered in practice are \((\varepsilon ,\alpha )\)-meshes or close to being one. We prove that flipping the appropriate edges can smooth a dense \((\varepsilon ,\alpha )\)-mesh by making the triangle normals better approximations of the surface normals and the dihedral angles closer to \(\pi \). Moreover, the edge flips can be performed in time linear in the number of vertices. This helps to explain the effectiveness of edge flips as observed in practice and in our experiments. A corollary of our techniques is that, in \(\mathbb {R}^2\), every triangulation with a constant lower bound on the angles can be flipped in linear time to the Delaunay triangulation.     

A turn-on and reversible fluorescence sensor with high affinity to Zn in aqueous solution

A new simple receptor 1 based on aminosalicylimine was prepared. It exhibited an ‘off–on fluorescence type’ mode with high sensitivity in the presence of Zn²⁺. In particular, this chemosensor could clearly distinguish Zn²⁺ from Cd²⁺. Also, it could be a reusable chemosensor because the addition of EDTA quenched the fluorescence of the Zn²⁺-2·1 complex. Furthermore, receptor 1 had a sufficiently low detection limit (68 nM) in aqueous solutions, which implies that 1 could sense the nanomolar concentration of Zn²⁺. Therefore, this sensor has the ability to be a practical system for the monitoring of Zn²⁺ concentrations in aqueous samples.     

Efficient approach to allylated quinolines via palladium-catalyzed cyclization–allylation of 1-azido-2-(2-propynyl) benzenes with allyl methyl carbonate

The palladium-catalyzed cyclization–allylation reaction of ortho-azido propynylbenzenes 1 and allyl methyl carbonate 2d gives the corresponding allylated quinolines in moderate to good yields. The reaction of 1-azido-2-(2-propynyl)benzene 1a proceeds smoothly with 10 mol % Pd(PPh₃)₄ and 5 equiv K₃PO₄ or NaOAc in DMF at 100 °C to afford 3,4-diallylquinoline 3a in 69% yield in the case of R² = H and 3-allylquinoline 4 in 67% yield in the case of R² ≠ H.     

One‐Dimensional Channels Encapsulated in Supramolecular Networks Constructed of Zinc(II), Manganese(II), or ­Nickel(II) Atoms with 3‐(Carboxymethyl)‐2, 7‐dimethyl‐3H‐benzo[d]imidazole‐5‐carboxylic Acid

Four complexes with supramolecular architectures, namely, MZCA · 3H₂O ( 1 ), [Zn(H₂O)₆]²⁺ · [MZCA]₂ · [H₂O]₆ ( 2 ), [Mn(MZCA)₂(H₂O)₄] · 2H₂O ( 3 ), and [Ni(MZCA)₂(H₂O)₄] · 2H₂O ( 4 ) [MZCA = 3‐(carboxymethyl)‐2, 7‐dimethyl‐3H‐benzo[d]imidazole‐5‐carboxylic acid], were synthesized and characterized by elemental analysis, IR spectroscopy, and single‐crystal X‐ray diffraction. Complexes 1 and 2 display a remarkable 3D network with 1D hydrophilic channels. Complexes 3 and 4 are isostructural and exhibit a 3D structure encapsulating 1D 24‐membered ring microporous channels. The UV/Vis and fluorescent spectra were measured to characterize complexes 1 – 4 . The thermal stability of complexes 2 – 4 were also examined.     

A New Tricarboxylate‐Terbium(III) Compound: Synthesis,Structure, and Luminescent Property

The Tb^III compound [Tb(tci)(H₂O)]_n · n(DMF) ( 1 ) [H₃tci = tri(2‐carboxythyl)isocyanurate, DMF = N,N′‐dimethylformamide] was synthesized by the reaction of terbium oxide, H₃tci, and two drops of concentrated nitric acid in the presence of DMF and H₂O. Single crystal X‐ray analysis reveals that it features a three‐dimensional (3D) framework based on infinite –Tb–COO–Tb– chains. The tci ligand in 1 links six different Tb^III ions with its two carboxylate groups in μ₂‐κ¹O;κ²O,O′ mode and the third in μ₂‐κ¹O;κ¹O′ mode. Thermal analysis reveals that it remains high thermal stability until 390 °C. Luminescence investigation shows that it emits characteristic green light of Tb^III ions.     

Synthesis,Structure, Photoluminescence,and Theoretical ­Calculation of an rtl‐type Zinc(II) Compound with Linear Trinuclear [Zn3(COO)4(μ2‐H2O)2] Subunits

The zinc(II) coordination polymer [Zn₃(BPT)₂(μ₂‐H₂O)₂(H₂O)₂]_n · n(DMA) ( 1 ) (H₃BPT = biphenyl‐3,4′,5‐tricarboxylic acid, DMA = N,N′‐dimethylactamide) was obtained by the solvothermal reaction of H₃BPT with Zn(NO₃)₂ in DMA/H₂O mixed solvent. Single crystal X‐ray analysis reveals that compound 1 has a complicated 3D framework containing linear trinuclear [Zn₃(COO)₄(μ₂‐H₂O)₂] clusters as building subunits, which can be simplified into a (3,6)‐connected rtl topological network with the Schläfli symbol {4.6²}₂{4².6¹⁰.8³}. The calculated results of total and partial density of states (DOS) indicate that the luminescence of 1 mainly originates from intraligand charge transfer.     

Topography and field effects in the inner side of microvia hole using ToF‐SIMS

We have developed a simple and powerful method, which is called ‘angled sample holder method’, to characterize a topographic structured sample such as microsized via hole of ball grid array using time‐of‐flight SIMS. The diameter of via holes was 100 µm and the depth was 70 µm. To remove the shaded area by incidence primary ion beam and to extract secondary ions from the bottom of a via hole, several types of angled sample holders with compensation steering plate were applied on the basis of simulation results using SIMION code. And the analyses using angled sample holder method enabled us to characterize the bottom and side wall of a via hole in clear. Copyright © 2014 John Wiley & Sons, Ltd.     

Rational design of donor–π–acceptor n-butyl-1,8-naphthalimide-cored branched molecules as charge transport and luminescent materials for organic light-emitting diodes

Four D–π–A bipolar molecules with n-butyl-1,8-naphthalimide (BNI) fragments as acceptors, acetylenes as π-spacers, and different aromatic groups as donors have been designed to explore their optical, electronic, and charge transport properties as charge transport and luminescent materials for organic light-emitting diodes (OLEDs). The frontier molecular orbitals (FMOs) and local density of states analysis have turned out that the vertical electronic transitions of absorption and emission are characterized as intramolecular charge transfer (ICT). The calculated results show that their optical and electronic properties are affected by the different donors of the bipolar molecules. Our results suggest that D–π–A 1,8-naphthalimide derivatives with donors triphenylamine (1), 1-nitrobenzene (2), anisole (3), and 4-phenylbenzo[c][1,2,5]thiadiazole (4) fragments are expected to be promising luminescent materials. Furthermore, 2–4 are expected to be promising candidates for both electron and hole transport materials as well as potential ambipolar charge transport material, whereas BNI and 1 can serve as hole transfer materials only. We have also predicted the mobility of 4 with better performance in three different space groups. On the basis of investigated results, we proposed a rational way for the design of charge transport and/or luminescent materials simultaneously.