Novel C3V-symmetric tripodal scaffold, triethyl cis,cis,cis-2,5,8- tribenzyltrindane-2,5,8-tricarboxylate, for the construction of artificial receptors

[reaction: see text] A novel C3V-symmetric scaffold, trindane 7, has been efficiently synthesized from 1,3,5-tris(bromomethyl)-2,4,6-tris(chloromethyl)benzene (1) in six steps with 47% overall yield. The control of all-syn stereochemistry in the tribenzylation step has been achieved by blocking one side of the trindane ring as metal carbonyl complexes. The potential utility of trindane 7 as a receptor skeleton has been examined with a urea derivative 12 toward several anionic guests.     

Relativistic Hydrodynamic Cosmological Perturbations

Relativistic cosmological perturbation analysescan be made based on several different fundamental gaugeconditions. In the pressureless limit the variables incertain gauge conditions show the correct Newtonian behaviors. Considering the generalcurvature (K) and the cosmological constant ()in the background medium, the perturbed density in thecomoving gauge, and the perturbed velocity and the perturbed potential in the zero-shear gaugeshow the same behavior as the Newtonian ones in generalscales. In the first part, we elaborate these Newtoniancorrespondences. In the second part, using the identified gauge-in variant variables withcorrect Newtonian correspondences, we present therelativistic results with general pressures in thebackground and perturbation. We present the generalsuper-sound-horizon scale solutions of the above mentionedvariables valid for general K, Lambda, and generallyevolving equation of state. We show that, for vanishingK, the super-sound-horizon scale evolution ischaracterised by a conserved variable which is the perturbedthree-space curvature in the comoving gauge. We alsopresent equations for the multi-component hydrodynamicsituation and for the rotation and gravitational wave.     

On the intermediate eigenvalues of symmetric sparse matrices

An algorithm has been developed for finding the eigenvalues of a symmetric matrixA in a given interval [a, b] and the corresponding eigenvectors using a modification of the method of simultaneous iteration with the same favorable convergence properties. The technique is most suitable for large sparse matrices and can be effectively implemented on a parallel computer such as the ILLIAC IV.     

Ferromagnetism induced by clustered Co in Co-doped anatase TiO2 thin films

We investigated ferromagnetism of a newly discovered ferromagnetic semiconductor Co-doped anatase TiO2 thin film, using the magnetic circular dichroism (MCD) at the Co L(2,3) absorption edges. The magnetic moment was observed to be approximately 0.1 micro(B)/Co in the measurements, but the MCD spectral line shape is nearly identical to that of Co metal, showing that the ferromagnetism is induced by a small amount of clustered Co. With thermal treatments at approximately 400 degrees C, the MCD signal increases, and the moment reaches up to approximately 1.55 micro(B)/Co, which is approximately 90% of the moment in Co metal. In the latter case, the cluster size was observed to be 20-60 nm.     

An experimental study on the effect of mesoporous silica addition on ion conductivity of poly(ethylene oxide) electrolytes

Solid polymer electrolyte (SPE) composites, which are composed of poly(ethylene oxide) (PEO), mesoporous silica (SBA-15), and lithium salt were prepared in order to investigate the influence of SBA-15 content on the ionic conductivity of the composites. The ionic conductivity of the SPE composites was monitored by frequency response analyzer (FRA), and the crystallinity of the SPE composites was evaluated by using XRD. As a result, the addition of SBA-15 to the polymer mixture inhibited the growth of PEO crystalline domain, due to the mesoporous structure of the SBA-15. Also, the PEO₁₆LiClO₄/SBA-15 composite electrolytes show an increased ion conductivity as a function of SBA-15 content up to 15 wt.%. These ion conductivity characteristics are dependent on crystallinity with SBA-15 content.     

Output characteristics of a simple FP-LD/FBG module

We propose a simple laser diode module that consists of a Fabry–Perot laser diode (FP-LD) and a fiber Bragg grating (FBG) for a compact, stable and low-cost wavelength division multiplexing light source. The spectral bandwidth of the laser output from the FP-LD/FBG module was measured to be 0.024 nm. The side mode suppression ratio (SMSR) was 44.42 dB at the injected electric current of 14 mA and at 25 °C. Both the BER characteristics and the eye diagram were measured, and they confirmed that the present laser diode module could be used as an alternative configuration for a low-cost light source.     

Influence of ceramic oxide materials on lithium based potentiometric CO2 sensors

In these potentiometric sensors, a mixed binary carbonate sensing material consisting of 90 mol% Li₂CO₃ and 10 mol% BaCO₃ was modified by adding ceramic oxide materials such as SiO₂, B₂O₃, La₂O₃, Bi₂O₃, CeO₂ and In₂O₃ in different mol% concentrations. Various sensors mixed with these external oxides have shown good performance at operating temperatures below 300 °C. Scanning electron microscopy reveals that a glassy sensing phase is formed in the sensing bi-carbonate by the addition of ceramic oxides and sintered at 600 °C for 1 h. The sensor mixed with SiO₂:B₂O₃:Bi₂O₃ in 1:2:1 mol% showed an excellent response and recovery characteristics and followed a fair Nernstian behavior with a ΔEMF/dec value of −48.18 at as low as 150 °C. The decrease in operating temperature is attributed to the enhanced lithium ion migration through the glassy sensing phase of the sensing electrode.     

Visualization of the Barkhausen effect by magnetic force microscopy

By visualization of the Barkhausen effect using magnetic force microscopy we are able to provide detailed information about the physical principles that govern the magnetization reversal of a granular ferromagnetic thin film with perpendicular anisotropy. Individual Barkhausen volumes are localized and distinguished as either newly nucleated or grown by domain wall propagation. The Gaussian size distribution of nucleated Barkhausen volumes indicates an uncorrelated random process, while grown Barkhausen volumes exhibit an inverse power law distribution, which points towards a critical behavior during domain wall motion.     

Kinetic roughening of ion-sputtered Pd(001) surface: beyond the Kuramoto-Sivashinsky model

We investigate the kinetic roughening of Ar+ ion-sputtered Pd(001) surface both experimentally and theoretically. In situ real-time x-ray reflectivity and in situ scanning tunneling microscopy show that nanoscale adatom islands form and grow with increasing sputter time t. Surface roughness W(t) and lateral correlation length xi(t) follow the scaling laws W(t) approximately t(beta) and xi(t) approximately t(1/z) with the exponents beta approximately 0.20 and 1/z approximately 0.20, for an ion beam energy epsilon=0.5 keV, which is inconsistent with the prediction of the Kuramoto-Sivashinsky (KS) model. We thereby extend the KS model by applying the coarse-grained continuum approach of the Sigmund theory to the order of O(inverted Delta(4),h(2)), where h is the surface height, and derive a new term of the form inverted Delta(2)(inverted Delta h)(2) which plays a decisive role in describing the observed morphological evolution of the sputtered surface.