粗糙热传导表面下激光介质温度场的计算分析

提出了一种计算温度场的面热源自适应调整算法,该方法通过在研究对象的封闭边界上引入虚拟面热源来求解稳态热传导方程的边值问题。建立了导热联结的具有粗糙表面介质的接触模型,在此基础上建立了随机分布的表面散热边界条件,并用面热源自适应调整算法计算了激光介质的温度场。结果表明,由于实际激光介质散热表面不能完全紧密接触,其温度场呈现一定程度的随机起伏,越靠近边界,随机起伏越明显,介质中心区域随机起伏则不明显;有效热接触面积越小,这种随机起伏越强烈。计算表明热接触面积占50%时,比接触面积占75%时温度场的随机性更明显。     

低光泽度印刷色谱色貌数据组的建立与评价

色貌预测是现代颜色科学领域的基本理论和技术。为了评价低光泽度彩色印刷色谱的色貌,以丽印胶版纸印制的彩色印刷色谱为研究对象,根据颜色科学和心理物理学相关实验,建立其色貌参数样本数据组。采用相对系数R2和差异系数CV等数理统计方法,评价这种印刷色谱中Y-M内页在三种不同的照明光源下色貌的视觉评估结果。实验数据分析表明,在D65、A和TL84三种光源中,人眼在A光源下对颜色的识别能力明显不同于D65和TL84光源;同样在这三种光源中人眼对明度和色调的评估准确度最高,彩度最差。     

基于复合干涉的光纤低相干干涉传感系统研究

研究一种能够进行远程及绝对测量的光纤低相干干涉传感系统。该系统包含两个光纤干涉仪,其中一个光纤干涉仪置于被测场中感应被测量的变化,可实现远程测量;另一个光纤干涉仪解调被测量的值。运用波分复用技术,使用于解调的光纤干涉仪同时工作于低相干干涉和高相干干涉状态。用低相干干涉信号决定被测量的幅值,对被测量实现绝对测量,并使测量量程不受波长限制;同时,用高相干干涉信号对被测量进行高精度的测量。系统的测量量程为6mm,测量分辨率小于1nm,位移实验结果的线性相关系数R为0.99。     

Optical and magnetic properties of Nd‐doped ZnO nanoparticles

Nd‐doped ZnO nanoparticles with different concentration were synthesized by sol‐gel method. The structures, magnetic and optical properties of as‐synthesized nanorods were investigated. X‐ray diffraction (XRD) and x‐ray photoelectron spectroscopy (XPS) results demonstrated that Nd ions were incorporated into ZnO lattice; but Zn_1‐xNd_xO nanoparticles with Nd concentration of x = 0.05 showed Nd₂O₃ phase, so the saturation concentration of Nd in Zn_1‐xNd_xO is less than 5 at%. Vibrating sample magnetometer (VSM) measurements indicated that Nd doped ZnO possessed dilute ferromagnetis behaviour at room temperature. Photoluminescence spectroscopy (PL) showed that Nd ions doping induced a red slight shift and decrease in UV emission with increase of Nd concentration.     

微波水热温度对合成Bi2MoO6微晶形貌和光学性能的影响

以硝酸铋和钼酸钠为起始原料,采用微波水热法制备了片状的Bi2MoO6微晶。利用X射线衍射仪(XRD)、透射电子显微镜(TEM)和紫外-可见吸收光谱(UV-vis)分别对产物的物相组成、形貌和光学性能进行分析。结果表明:随着微波水热温度的升高,衍射峰的强度增强,产物的结晶程度逐渐提高,晶粒尺寸逐渐增大,Bi2MoO6微晶由不规则的形状转变成规则的片状结构;紫外-可见吸收光谱分析表明,Bi2MoO6微晶在紫外光区具有优异的吸收性能,且随微波水热温度的降低,其吸收边出现略微蓝移,禁带宽度逐渐增大。     

I(2) promoted domino oxidative cyclization for one-pot synthesis of 2-acylbenzothiazoles via metal-free sp(3) C-H functionalization

An I(2) promoted domino protocol was developed to construct 2-acylbenzothiazoles from simple and readily available aromatic ketones/unsaturated methyl ketones and o-aminobenzenethiols. The reaction proceeded smoothly under metal-free and peroxide-free conditions.     

One pot glucose detection by [Fe(III)(biuret-amide)] immobilized on mesoporous silica nanoparticles: an efficient HRP mimic

An [Fe(III)(biuret-amide)] complex has been immobilized onto mesoporous silica nanoparticles via Cu(I) catalyzed azide-alkyne click chemistry. This hybrid material functions as an efficient peroxidase mimic and was successfully used for the quantitative determination of hydrogen peroxide and glucose via a one-pot colorimetric assay.     

Highly biocompatible, hollow coordination polymer nanoparticles as cisplatin carriers for efficient intracellular drug delivery

Highly biocompatible coordination polymer (Prussian Blue) nanoparticles (LC(50) > 1000 μg mL(-1)) with a hollow interior and a microporous framework (denoted as HPB) are utilized as an anticancer drug (i.e. cisplatin) capsule for chemotherapy of bladder cancer T24 cells.     

Activation of phosphorus by group 14 elements in low oxidation states

The activation of phosphorus remains a popular and competitive area of research driven by the dual goals of finding ways to avoid the environmentally questionable P-Cl compounds applied in many industrial processes and the target of catalytic functionalization of P(4). In recent years the activation, degradation, fragmentation, and functionalization of white phosphorus by compounds with heavier main group elements have become a fertile area of research. The isolation of various carbenes and functionalized silylenes has prompted chemists to investigate their reactions with white phosphorus. The most intriguing fact in these reactions is the subtle change in the substituents may afford strikingly different compounds. For example, from the reaction of P(4) with PhC(NtBu)(2)SiCl a cyclic Si(2)P(2) derivative is obtained, whereas the analogous reaction with PhC(NtBu)(2)SiN(SiMe(3))(2) resulted in an acyclic Si(2)P(4) framework. Similar phenomena have also been observed in the carbene mediated P(4) activation. Apart from these, a new entry point into phosphorus chemistry is the gentle activation of P(4) by an alkyne analogue of tin. In this feature article we have covered the activation of phosphorus by compounds with low valent group 14 elements with special concern to the recent developments in this topic.     

Abnormal N-heterocyclic carbene palladium complex: living catalyst for activation of aryl chlorides in Suzuki-Miyaura cross coupling

Palladium complexes bearing abnormal N-heterocyclic carbene were used as catalysts in Suzuki-Miyaura cross coupling of aryl chlorides at 25 °C. The catalyst remained active for 10 successive catalytic runs and can activate 4-chlorotoluene at 25 °C with 0.01 mol% catalyst loading resulting in a TON of 9500 within 6 h.