Preconcentration of trace antimony in tap and sea water on activated alumina. Determination by graphite furnace atomic absorption spectrometry

Summary A method is described for antimony preconcentration based on retention on a column of activated alumina. Recovery is 80% when no pH-control and 4 mol/l HCl as eluent are used. The preconcentration factor is 400. The method was applied to the determination of antimony in spiked tap and sea water. The analytical performance of the method is discussed.     

On the piezoelectricity of anionic collagen films

In this paper, we report results of a study of the physicochemical, dielectric and piezoelectric properties of anionic and native collagen films, considering the development of new biomaterials which have potential applications in coating of cardiovascular prostheses, support for cellular growth and in systems for controlled drug delivery. The piezoelectric strain tensor element d₁₄, the elastic constant s₅₅, and the dielectric permittivity ?₁₁ were measured for the anionic and native collagen films. It was observed that the collagen samples submitted to the alkaline treatment present lower thermal stability than those made from native collagen. However, the treated samples present a higher piezoelectricity compared with the native collagen. The frequency constant fL and the piezoelectric strain element d₁₄, obtained for the alkaline-treated sample (72 h), present the highest values for the samples under study (444.1 kHz m and 0.079 pC/N, respectively). We believe that the alkaline treatment led to an increase of the organization of the microscopic fiber structure of the sample, which could result in an increase of the piezoelectricity.     

Special geometry,cubic polynomials and homogeneous quaternionic spaces

The existing classification of homogeneous quaternionic spaces is not complete. We study these spaces in the context of certainN=2 supergravity theories, where dimensional reduction induces a mapping betweenspecial real, Kähler and quaternionic spaces. The geometry of the real spaces is encoded in cubic polynomials, those of the Kähler and quaternionic manifolds in homogeneous holomorphic functions of second degree. We classify all cubic polynomials that have an invariance group that acts transitively on the real manifold. The corresponding Kähler and quaternionic manifolds are then homogeneous. We find that they lead to a well-defined subset of the normal quaternionic spaces classified by Alekseevskiî (and the corresponding special Kähler spaces given by Cecotti), but there is a new class of rank-3 spaces of quaternionic dimension larger than 3. We also point out that some of the rank-4 Alekseevskiî spaces were not fully specified and correspond to a finite variety of inequivalent spaces. A simpler version of the equation that underlies the classification of this paper also emerges in the context ofW ₃ algebras.Communicated by K. Gawedzki     

Principles and recent developments in ultrasound contrast agents

The behaviour of gas bubbles and gas encapsulated spheres as echographic contrast agents is reviewed. Compared with rigid spheres, gas bubbles are superior scattering agents and they offer a number of useful properties which can be exploited in a variety of ways. The analysis of their velocity of sound, back-scatter intensity, second harmonic emission and resonant frequency opens up new perspectives in the development of contrast agents for echocardiographic research with potential clinical applications.     

Averaged topological equations for dispersed two-phase flows

A general relationship between the volume fraction and the specific interfacial area for averaged dispersed two-phase flows is proposed. This relationship, expressed as a basic set of two scalar evolution equations and two vectorial non-uniformity state equations, is an analytical result obtained by a systematic approach using the derivatives of some generalized functions and a local volume-averaging technique. The proposed set of equations was expressed for measurable macroscopic parameters of the system and has the same generality as the averaged transport equations of two-phase flows. By combination of the basic set of equations, called the averaged topological equations (ATEs), second-order ATEs for the volume fraction were found. The second-order ATEs were expressed both by a Lagrangian formulation and by a Eulerian formulation. The importance and physical meaning of the ATEs developed in this study were clarified within the framework of the theory of kinematic waves.     

Local-moment and itinerant antiferromagnetism in the heavy-fermion system Ce(Cu1−xNix)2Ge2

Elastic and inelastic neutron-scattering studies on the system Ce(Cu_1?xNi_x)₂Ge₂ are reported. These measurements are complemented by measurements of the magnetic susceptibility, high-field magnetization, heat capacity, thermal expansion, electrical resistivity and thermopower. The results reveal an interesting T-x phase diagram consisting of two different antiferromagnetic phases for x < 0.2 and 0.2 < x < 0.75, respectively, and a heavy-Fermi-liquid regime at higher Ni concentrations. The experimental results are interpreted in terms of an alloying-induced transition from local-moment to itinerant heavy-fermion magnetism. Fingerprints of this latter phase are a strongly reduced ordered moment and a short incommensurate ordering wave vector, in accord with theoretical predictions. A surprisingly good agreement between theory and experiment is found for x > 0.5. Further experimental evidence for different types of antiferromagnetic ordering derives from a line-shape analysis of the quasielastic neutron-scattering intensity, from magnetization and thermopower experiments.