Versions of separability in bitopological spaces

We study selective versions of separability in bitopological spaces. In particular, we investigate these properties in function spaces endowed with the topology of pointwise convergence and the compact-open topology.     

Experimental distribution of phases and pressure drop in a two-phase offset strip fin type compact heat exchanger

Uniform distribution of fluids is crucial to obtain high performance in compact heat exchangers. Maldistribution has been studied by many authors, especially for parallel channels heat exchangers. But theoretical models and experimental studies for predicting flow maldistribution in offset strip fins exchangers are scarce. Offset strip fins, besides their higher thermal hydraulic performances, favour lateral distribution due to their geometry. In this work, an experimental investigation has been carried out for this type of heat exchanger. The experimental set-up consists in a flat vertical compact heat exchanger (1 m × 1 m area and 7.13 mm thickness) equipped with offset strip fins with a hydraulic diameter of 1.397 mm. Air and water are the working fluids. The flow rates of each phase in seven zones regularly distributed at the outlet have been measured as well as the pressures at the inlet, the outlet and two intermediate positions. These measurements were completed with visualisations using a high-speed camera.     

Streamer-Like Electrical Discharges in Water: Part I. Fundamental Mechanisms

Electrical discharge plasma formed in liquid water is under intensive investigation for many possible applications in biomedical, environmental and chemical engineering as well as for general scientific issues in plasma chemistry and other engineering applications. The subject of pulsed breakdown of water has additionally begun to assume importance due to growing interest in decontamination, purification of water containing chemical impurities and industrial sludge, and also in the emerging area of bio-electrics. This review paper focuses on the plasma physics (Part I) and chemistry of electrical discharges in liquid water and the chemical effects of plasmas on the degradation of organic molecules (Part II). This part discusses dielectric liquid breakdown and its mechanisms, streamer propagation and the effect of electrode polarity on streamer dynamics.     

Dichloromethane alkylates a trithiolato-ruthenium complex to yield a methylene-bridged thioether core. Synthesis and structural comparison to the thiolato-ruthenium precursor

The previously reported triphosphino/trithiolato-ruthenium anion, [tris-(2-diphenylphosphinothia-phenolato)ruthenium(II)](-), [Ru(DPPBT)(3)](-), has been isolated as the PPN salt (PPN = bis(triphenylphosphoranylidene) ammonium), 1, from chlorobenzene/ether as light-orange crystalline plates, and the X-ray crystal structure has been determined. In dichloromethane, the cis positioned thiolates are alkylated by solvent yielding the methylene-bridged triphosphino/dithioether/thiolato complex [(bis-(2-diphenylphosphinothiaphenolato)methane)(2-diphenyl-phosphinothiaphenolato)ruthenium(II)]chloride, [Ru((DPPBT)(2)CH(2))(DPPBT)]Cl (2). Dichloromethane solutions of 1 layered with hexanes yield 2 as orange cubes. The ruthenium-sulfur bond distances in the alkylated, thioether product are slightly shorter than in the thiolate precursor. Within 2, the iron-thioether bond distances are comparable to the iron-thiolate distances.     

Molecular Dynamics Simulations of the First Steps of the Formation of Polysiloxane Layers at a Zinc Oxide Surface

Three different dissolved silane molecules adsorbed at a polar ZnO surface (000&1macr;) are studied by means of constant temperature molecular dynamics simulations. The adsorbed single silane molecules exhibit a different behavior depending on the chemical nature of their tail. For octyltrihydroxysilane molecules with their rather unpolar tail an orthogonal orientation at the polar metal oxide surface is statistically favored with all three polar hydroxide groups of the head being in contact with the polar ZnO surface and the unpolar tail remaining in the isopropanol phase. On the contrary, due to their highly polar tail, aminopropyltrihydroxysilane molecules show a more or less parallel orientation at the surface. Apart from some minor fluctuations two hydroxide groups as well as the amino group of the tail are in contact with the surface. The behavior of the thiolpropyltrihydroxysilane molecules is somehow located in between resulting in parallel as well as orthogonal orientations of the molecule at the surface. Though many of the results obtained for single adsorbed silane molecules can also be transferred to adsorbed silane molecules within whole layers a remarkable difference appears: Now even for aminopropyltrihydroxysilane molecules a mixture of parallel and orthogonal alignment of the molecules can be observed whereas some of the octyltrihydroxysilane molecules also show a parallel orientation.