全文获取类型
收费全文 | 266篇 |
免费 | 9篇 |
专业分类
化学 | 204篇 |
力学 | 4篇 |
数学 | 26篇 |
物理学 | 41篇 |
出版年
2023年 | 4篇 |
2022年 | 4篇 |
2020年 | 9篇 |
2019年 | 14篇 |
2018年 | 4篇 |
2017年 | 4篇 |
2016年 | 5篇 |
2015年 | 10篇 |
2014年 | 9篇 |
2013年 | 10篇 |
2012年 | 11篇 |
2011年 | 19篇 |
2010年 | 7篇 |
2009年 | 5篇 |
2008年 | 8篇 |
2007年 | 9篇 |
2006年 | 9篇 |
2005年 | 11篇 |
2004年 | 16篇 |
2003年 | 5篇 |
2002年 | 13篇 |
2001年 | 7篇 |
2000年 | 4篇 |
1999年 | 5篇 |
1998年 | 5篇 |
1996年 | 3篇 |
1995年 | 3篇 |
1994年 | 2篇 |
1993年 | 5篇 |
1992年 | 3篇 |
1991年 | 1篇 |
1990年 | 5篇 |
1989年 | 2篇 |
1988年 | 4篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 5篇 |
1984年 | 4篇 |
1983年 | 3篇 |
1982年 | 3篇 |
1981年 | 1篇 |
1980年 | 3篇 |
1979年 | 3篇 |
1978年 | 5篇 |
1976年 | 1篇 |
1974年 | 2篇 |
1970年 | 2篇 |
1969年 | 1篇 |
1967年 | 1篇 |
1965年 | 1篇 |
排序方式: 共有275条查询结果,搜索用时 15 毫秒
41.
Hiromu Asada 《Journal of statistical physics》2000,98(3-4):621-637
This paper presents an alternative statistical way to derive the cluster variation method (CVM) for lattice systems. The formulation is developed for a series of different clusters, each of which is the largest overlap cluster between two clusters of the next larger type. We arrive at the CVM expression of the lattice configuration factor by deriving the number of different ways of distributing clusters of a selected type in the lattice so that they overlap each other at the largest overlap clusters in a physically correct manner. The essential assumption employed is that individual overlapping events are statistically independent of each other. This reveals a new statistical aspect of the CVM: The CVM is based on a Bethe tree of clusters of the selected type. 相似文献
42.
43.
Kazuyuki Minami Toshiyuki Ishida Yasuki Asada Seiji Shirakawa Masanao Kobayashi Shoichi Suzuki Tomimasa Konishi Hidenori Mimura 《X射线光谱测定》2019,48(6):691-695
We investigate a miniaturized X-ray source using an ultraviolet (UV) laser and a pyroelectric crystal and discuss potential applications in medicine. The UV laser is the fourth harmonic of a Nd:YAG laser with a wavelength of 266 nm, repetition rate of 10 Hz, and pulse energy of 40 mJ. The pyroelectric crystal is a LiNbO3 cylinder of diameter 10 mm and length 6 mm. The prototype X-ray source we fabricated is an aluminum parallelepiped of dimensions 3 × 3 × 5 cm. The X-ray count rate of the X-ray source is maximized at approximately 1,400 cps for UV laser irradiation of approximately 5 min. After 30 min of irradiation by the UV laser, the temperature of the pyroelectric crystal rose from 295 K to 312 K. The principles of X-ray generation ensure that X-ray sources using UV lasers and pyroelectric crystals offer ample opportunity for miniaturization. We believe the X-ray source developed in this work is suitable for medical applications, although further study is needed to address points such as increasing the X-ray count rate and adjusting the temperature of the pyroelectric crystal. 相似文献
44.
Stefano Freguia Masaki Masuda Seiya Tsujimura Kenji Kano 《Bioelectrochemistry (Amsterdam, Netherlands)》2009,76(1-2):14
Lactococcus lactis is a gram-positive, normally homolactic fermenter that is known to produce several kinds of membrane associated quinones, which are able to mediate electron transfer to extracellular electron acceptors such as Fe3+, Cu2+ and hexacyanoferrate. Here we show that this bacterium is also capable of performing extracellular electron transfer to anodes by utilizing at least two soluble redox mediators, as suggested by the two-step catalytic current developed. One of these two mediators was herein suggested to be 2-amino-3-dicarboxy-1,4-naphthoquinone (ACNQ), via evaluation of standard redox potential, ability of the bacterium to exploit the quinone when exogenously provided, as well as by high performance liquid chromatography coupled with UV spectrum analysis. During electricity generation, L. lactis slightly deviated from its normal homolactic metabolism by excreting acetate and pyruvate in stoichiometric amounts with respect to the electrical current. In this metabolism, the anode takes on the role of electron sink for acetogenic fermentation. The finding that L. lactis self-catalyses anodic electron transfer by excretion of redox mediators is remarkable as the mechanisms of extracellular electron transfer by pure cultures of gram-positive bacteria had previously never been elucidated. 相似文献
45.
D Matsumura K Kitazawa S Terai T Kochi Y Ie M Nitani Y Aso F Kakiuchi 《Organic letters》2012,14(15):3882-3885
A convenient method for the synthesis of tetraalkylanthracenes and -pentacenes by means of ruthenium-catalyzed regioselective C-H alkylation of the corresponding acenequinones was developed. Dialkyldiarylpentacene was also synthesized using chemoselective tandem C-H alkylation/C-O arylation of dimethoxypentacenequinone. It was suggested that a tetraalkylpentacene is stable under air in the dark and possesses an appropriate HOMO level as active material for p-type organic field-effect transistors (OFETs). 相似文献
46.
SK Podiyanachari R Fröhlich CG Daniliuc JL Petersen G Kehr G Erker N Suzuki S Yuasa K Hagimori S Inoue T Asada T Takemoto Y Masuyama 《Dalton transactions (Cambridge, England : 2003)》2012,41(35):10811-10816
The reaction of η(2)-iminozirconocene chloride complexes with trimethylsilylethynyl lithium leads to rapid C-C coupling at room temperature to yield the corresponding five-membered aza-zirconacycloallenoids. Such compounds were also obtained by trapping of in situ generated zirconocene with alkynyl imines. 相似文献
47.
Seiya Tanaka Tsuneaki Sakurai Yoshihito Honsho Dr. Akinori Saeki Prof. Dr. Shu Seki Dr. Kenichi Kato Prof. Dr. Masaki Takata Prof. Dr. Atsuhiro Osuka Prof. Dr. Takuzo Aida 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(34):10554-10561
In contrast with their dimeric homologue, triply fused zinc porphyrin trimer–pentamer, as extra‐large π‐extended mesogens, assemble into columnar liquid crystals (LCs) when combined with 3,4,5‐tri(dodecyloxy)phenyl side groups ( 3 PZn – 5 PZn , Figure 1 ). Their LC mesophases develop over a wide temperature range, namely, 41–280 °C (on heating) for 5 PZn , and all adopt an oblique columnar geometry, typically seen in columnar LC materials involving strong mesogenic interactions. These LC materials are characterized by their wide light‐absorption windows from the entire visible region up to a near infrared (NIR) region. Such ultralow‐bandgap LC materials are chemically stable and serve as hole transporters, in which 5 PZn gives the largest charge carrier mobility (2.4×10?2 cm V?1 s?1) among the series. Despite a big dimensional difference, they coassemble without phase separation, in which the resultant LC materials display essentially no deterioration of the intrinsic conducting properties. 相似文献
48.
An efficient approach for achieving radical cyclizations by using hydroxamate ester as a coordination tether with Lewis acid was studied. The chiral Lewis acid-mediated cascade radical addition-cyclization-trapping reaction proceeded smoothly with good enantio- and diastereoselectivities, providing various chiral γ-lactams. 相似文献
49.
Yoichi Asada Keith Slevin Tomi Ohtsuki 《Physica E: Low-dimensional Systems and Nanostructures》2006,34(1-2):228
Electron transport phenomena in disordered electron systems with spin–orbit coupling in two dimensions and below are studied numerically. The scaling hypothesis is checked by analyzing the scaling of the quasi-1D localization length. A logarithmic increase of the mean conductance is also confirmed. These support the theoretical prediction that the two-dimensional metal in systems with spin–orbit coupling has a perfect conductivity. Transport through a Sierpinski carpet is also reported. 相似文献
50.
Jing Chen Masahiro Ueda Katsuhiko Asada Keiji Taniguchi 《Optics and Lasers in Engineering》1998,29(1):221
An optical method to measure the weight density of raw glass wool has been developed for use in a manufacturing plant. The method is based on the light attenuation theory. The system consists of the usual white light as a light source, a solar cell as a light-sensitive receiver, an amplifier, a personal computer with an A/D converter for data acquisition and a monitor for display of the data. The accuracy of the system was found to be above 98% and the system can be effectively applied to practical use in the factory. The system may be further applied for quality control in manufacturing raw glass wool. 相似文献