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981.
1 IntroductionIn the recent years, the existence problem of BVP of second order functionaldifferential equations of the forms[p(t)i(t)]' = f(t, xf, x(t)), (1)i(t) = f(t, x(t), x(al(t)),'', x(a.(t)), i(t)), (2)x(t) = f(t, x(t), x(al(t)),'', x(U.(t)), i(t), i(n(t)),'', i(fu(t))), (3)t -- r 5 al(t),D(t) 5 t, as 0 5 t 5 T,i = 1,2,'' Ink j = 1,2,'',m, subjectto some boundary value conditions have been considered by several authors(please see [1-4],[6] and the references therein). In these pa… 相似文献
982.
The oxygen atom of dimethylformamide (DMF) is a good electron doaor site and in a proton donor solvent the solute-solvent interactions would include hydrogen bonding at this site. As this hydrogen bonding is expected to be relatively strong, it would predominate when both the lMF and the protonic acid are present at very low concentration in a solvent such as carbon tetrachloride, and the effect of this hydrogen bonding on the proton chemical shifts and coupling constants i n LMF can be observed. If the protonic acid is aromatic, such as phenol, and is in excess of the LMF, other form(s) of solut-olvent association would become significant and give rise to aromatic solvent induced shifts (ASIS), which would obscure the effect of hydrogen bonding at the oxygen site of the MF. The ASIS in DMF are well known, and the shifts have been attributed to the diamagnetic ring current effect of the aromatic solvent and specificsolut-olvent association.1 More recently, the ASIS has been interpreted as the result of time-averaged general solvation around the polar site of the solute.2 相似文献
983.
Xiaofeng Xu Ping Cai Yong Lu Ng Siu Choon Junwu Chen Xiao Hu Beng S. Ong 《Journal of polymer science. Part A, Polymer chemistry》2013,51(2):424-434
A novel class of thieno[3,2‐b]thiophene (TT) and isoindigo based copolymers were synthesized and evaluated as electron donor and hole transport materials in bulk‐heterojunction polymer solar cells (BHJ PSCs). These π‐conjugated donor‐acceptor polymers were derived from fused TT and isoindigo structures bridged by thiophene units. The band‐gaps and the highest occupied molecular orbital (HOMO) levels of the polymers were tuned using different conjugating lengths of thiophene units on the main chains, providing band‐gaps from 1.55 to 1.91 eV and HOMO levels from ?5.34 to ?5.71 eV, respectively. The corresponding lowest unoccupied molecular orbital (LUMO) levels were appropriately adjusted with the isoindigo units. Conventional BHJ PSCs (ITO/PEDOT:PSS/active layer/interlayer/Al) with an active layer composed of the polymer and PC71BM were fabricated for evaluation. Power conversion efficiency from a low of 1.25% to a high of 4.69% were achieved with the best performing device provided by the D?π?A polymer with a relatively board absorption spectrum, high absorption coefficient, and more uniform blend morphology. These results demonstrate the potential of this class of thieno[3,2‐b]thiophene‐isoindigo‐based polymers as efficient electron donor and hole transport polymers for BHJ PSCs. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013 相似文献
984.
Xue‐Gui Liu Weng‐Chao Zhang Pin‐Yi Gao Guo‐Sheng Wang Ling‐Zhi Li Shao‐Jiang Song Xiang Zhang Xin‐Sheng Yao Ke Liu Zhen‐Xue Zhang 《Helvetica chimica acta》2013,96(4):651-655
A phytochemical investigation of the MeOH extract of Valeriana fauriei Briq . roots resulted in the isolation of two new sesquiterpenes, isovalerianin A (=(1β,4Z,6β,8α)‐8‐(acetyloxy)‐1,10‐dihydroxy‐6,11‐cyclogermacr‐4‐en‐15‐al=rel‐(1R,2Z,6S,7R,9R,10S)‐9‐(acetyloxy)‐6,7‐dihydroxy‐7,11,11‐trimethylbicyclo[8.1.0]undec‐2‐ene‐3‐carboxaldehyde; 1 ) and valerianin C (=(2α,3α,6α,8α)‐3‐(acetyloxy)‐2,4,8‐trihydroxyguai‐1(10)‐ene‐12,6‐lactone=rel‐(3R,3aS,4R,7S,8S,9R,9aR,9bR)‐8‐(acetyloxy)‐3a,4,5,7,8,9,9a,9b‐ octahydro‐4,7,9‐trihydroxy‐3,6,9‐trimethylazuleno[4,5‐b]furan‐2(3H)‐one; 2 ), together with six known compounds, i.e., camphor, methyl 4‐hydroxybenzoate, 2‐methoxybenzoic acid, benzoic acid, quercetin, and kaempferol. The structures of the compounds were established by detailed spectral analysis and comparison with previously reported data. 相似文献
985.
Shou‐Ping Liu Hardy S. O. Chan Siu‐Choon Ng 《Journal of polymer science. Part A, Polymer chemistry》2004,42(19):4792-4801
A novel series of well‐defined alternating poly[2,7‐(9,9‐dihexylfluorenyl)‐alt‐pyridinyl] (PDHFP) with donor‐acceptor repeat units were synthesized using palladium (0)‐catalyzed Suzuki cross‐coupling reactions in good to high yields. In this series of alternating polymers, 2, 7‐(9,9‐dihexylfluorenyl) was used as the light emitting unit, and the electron deficient pyridinyl unit was employed to provide improved electron transportation. These polymers were characterized by 1H‐NMR and 13C‐NMR, gel permeation chromatography (GPC), thermal analyses, and UV‐vis and fluorescence spectroscopy. The glass transition temperature of copolymers in nitrogen ranged from 110 to 148 °C, and the copolymers showed high thermal stabilities with high decomposition temperatures in the range of 350 to 390 °C in air. The difference in linkage position of pyridinyl unit in the polymer backbone has significant effects on the electronic and optical properties of polymers in solution and in film phases. Meta‐linkage (3,5‐ and 2,6‐linkage) of pyridinyl units in the polymer backbone is more favorable to polymer for pure blue emission and prevention of aggregation of polymer chain than para‐linkage (2,5‐linkage) of the pyridinyl units. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4792–4801, 2004 相似文献
986.
探讨了仪器分析过程中的质量分析方法及分析中的数据处理、方法选择、质量监控、质量评估和信息管理等质量保证问题,为进一步提高仪器分析质量水平和管理水平经及最大限度地发挥仪器分析的作用作了一些有益的探索。 相似文献
987.
Hong Zhao Cheng Wu Weng Xin Tian Peng Xiang Lai Jian Jun Huang Wei Dong Xie 《中国化学快报》2010,21(5):613-615
<正>A novel eremophilane dimer,named fischelactone(1),was isolated from the roots of Ligularia fischeri.Complete structural elucidation of this compound was performed by HRESIMS,IR,1D NMR and 2D NMR(~1H-~1H COSY,HMBC,HMQC and NOESY) data. 相似文献
988.
Signal and image restoration problems are often solved by minimizing a cost function consisting of an l2 data-fidelity term and a regularization term. We consider a class of convex and edge-preserving regularization functions. In specific, half-quadratic regularization as a fixed-point iteration method is usually employed to solve this problem. The main aim of this paper is to solve the above-described signal and image restoration problems with the half-quadratic regularization technique by making use of the Newton method. At each iteration of the Newton method, the Newton equation is a structured system of linear equations of a symmetric positive definite coefficient matrix, and may be efficiently solved by the preconditioned conjugate gradient method accelerated with the modified block SSOR preconditioner. Our experimental results show that the modified block-SSOR preconditioned conjugate gradient method is feasible and effective for further improving the numerical performance of the half-quadratic regularization approach. 相似文献
989.
A chemo-electro-mechanical formulation, referred to as the multi-effect-coupling pH-stimulus (MECpH) model, is presented in this paper for the analysis of the effects of the initial geometrical size on the responsive behavior of pH-sensitive hydrogels subject to the coupled stimuli of environmental solution pH and externally applied electric voltage. The model is composed of coupled nonlinear partial differential equations, and it accounts for the diffusion of ionic species, distributive electric potential and large mechanical deformation. In addition, the correlation between the diffusive hydrogen ion within the hydrogel and charge groups fixed to the polymeric network chains is incorporated quantitatively into this MECpH model. For the simulation of the response characteristics of the smart hydrogel, we solve the one-dimensional steady-state problem using the Hermite–Cloud meshless technique. For the MECpH model, the present numerical simulations were compared with experimental data available from literature to validate the accuracy and robustness of the model, and good agreement was observed. Several parameter studies were then carried out in the analysis of the hydrogel swelling when immersed in solution, and it was observed that the initial geometrical size has significant influence on the volume variations of these pH-responsive hydrogels. 相似文献
990.
Suphanat Aphinyan Elisa Y. M. Ang Jingjie Yeo Teng Yong Ng K. R. Geethalakshmi 《Journal of polymer science. Part A, Polymer chemistry》2018,56(24):1615-1624
There is a pressing need in very small scale three-dimensional (3D) inkjet printing to control and reduce agglomeration, as agglomeration often leads to nozzle clogging. While agglomeration within ultraviolet ink has been studied, there has been, to our knowledge, no extensive studies conducted for surface agglomeration of the ink on nozzle's wall. This numerical study therefore focuses on investigating if surfactants can effectively control surface agglomeration during nanodroplet formation. Many-body dissipative particle dynamics is the numerical method of choice here. We found that small amount of surfactant of about 1 wt % is sufficient to effectively reduce ink deposition on the nozzle's wall. However, by using the properties of a commercially available surfactant, sodium dodecyl sulfate, it was found that the maximum reduction achieved by its addition is only 60%. Thus, further physical or chemical deagglomeration techniques are required, and we show that by considering these other techniques, reduction of surface agglomeration to nearly 92% can be achieved. Finally, we found that adding surfactants has the additional benefit of improving total kinetic energy of the ink compositions, lowering possibility of agglomerations within the ink. It also raises the nanodroplet velocity while reducing nanodroplet breakup time, which can help speed up the process of 3D printing process. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2018 , 56, 1615–1624 相似文献