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81.
Highly coercive magnetic powder was obtained by growing cobalt ferrite on the surface of γ-Fe2O3 particles in highly alkaline suspensions containing cobalt and ferrous ions in a Co/Fe molar ratio = 12. The mechanism of the growth and the structure of cobalt ferrite on γ-Fe2O3 were studied by X-ray diffraction and electron diffraction techniques. Results show that crystals of cobalt ferrite CoFe2O4 with a spinel type crystal structure of lattice constant 8.415 Å grew epitaxially on γ-Fe2O3. The acicular direction of the epitaxially grown Co-γ-Fe2O3 as well as γ-Fe2O3 was in the [101] direction. It was found that from the lattice constant value and the half width of X-ray diffraction peaks, the lattice constant epitaxially grown Co γ-Fe2O3 may be attributed to two kinds of crystals, viz., seed γ-Fe2O3 (a = 8.35 ~ 8.37 A?) which was partly reduced to Fe3O4, and surface layer CoFe2O4 (a = 8.415 A?). The crystal growth in the interface between the seed crystals and the growth layer was affected by the crystal structure of the seed crystals. The lattice constant of CoFe2O4 which was located in the vicinity of the interface was almost equal to that of the seed crystals.  相似文献   
82.
The validity of the assumption that Jψ decays into mesons proceed via ω, φ and ?0 poles followed by cascade decays is examined. Λ(JψBπ) is well reproduced by using Λ(Jψ → ?π), Λ(ω → ?π), Λ(B → ωπ) and the B → ωπ helicity structure. The structure of OZI-violating Jψ ? V0 transitions including the electromagnetic contribution is examined, and compared with the data on inclusive Jψ decay.  相似文献   
83.
A novel coordination gelator exhibits reversible chromatic and sol-gel phase-transition phenomena triggered by thermal and chemical stimuli.  相似文献   
84.
85.
We already found that beta-1,3-glucan polysaccharides form polymeric complexes with certain polynucleotides, but the parallel vs. anti-parallel orientation in those complexes had remained unsolved. In this paper, this controversial problem has been discussed for curdlan/oligo(dA) complexes utilizing two different energy transfer techniques. The first system consists of a combination of fluorescein-labeled curdlan and 3'-(or 5'-)tetramethyl-rhodamine (TAMRA)-labeled oligo(dA). The second system utilizes gold nanoparticles: that is, two curdlan chains were linked by a disulfide bond and after complexation with oligo(dA), the complex was immobilized on gold nanoparticles. In this system, TAMRA was attached to the 3'(or 5') end of oligo(dA) and the gold particle acted as a fluorescence quencher (energy acceptor). These experiments have led us to conclude that in the curdlan/oligo(dA) complex, parallel orientation is more favourable than anti-parallel orientation. These findings have enabled us to envision a clearer image for the complexation mode between beta-1,3-glucan polysaccharides and polynucleotides.  相似文献   
86.
Suga S  Suzuki S  Yoshida J 《Organic letters》2005,7(21):4717-4720
[reaction: see text] Alkoxycarbenium ions having no substituents on the cationic carbon have been accumulated as "cation pools" by the introduction of an ether group in an appropriate position. Intramolecular participation of the ether oxygen is suggested to be responsible for stabilization of the alkoxycarbenium ions.  相似文献   
87.
88.
An acid-stable hydride complex [Cp*IrIII(bpy)H]+ {1, Cp* = eta5-C5Me5, bpy = 2,2'-bipyridine} serves as the active catalyst for the highly chemoselective synthesis of alpha-amino acids by reductive amination of alpha-keto acids with aqueous NH3 and HCOO- in water at pH 5-8. pH-dependent catalytic 15N- and 2H-double-labeling has also been accomplished by using 15NH3 and DCOONa, which are ideal amine and hydride ion sources, respectively.  相似文献   
89.
Elastic wave scattering off a layer containing a single set of vertical periodic fractures is examined using a numerical technique based on the work of Hennion et al. [J. Acoust. Soc. Am. 87, 1861-1870 (1990)]. This technique combines the finite element method and plane wave method to simulate three-dimensional scattering off a two-dimensional fractured layer structure. Each fracture is modeled explicitly, so that the model can simulate both discrete arrivals of scattered waves from individual fractures and multiply scattered waves between the fractures. Using this technique, we examine changes in scattering characteristics of plane elastic waves as a function of wave frequency, angle of incidence, and fracture properties such as fracture stiffness, height, and regular and irregular spacing.  相似文献   
90.
Highly selective Friedel-Crafts monoalkylation of aromatic compounds with N-acyliminium ions has been achieved by efficient 1:1 mixing using a multilamination-type micromixer.  相似文献   
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