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61.
Seifert U 《Physical review letters》2011,106(2):020601
We consider nanosized artificial or biological machines working in steady state enforced by imposing nonequilibrium concentrations of solutes or by applying external forces, torques, or electric fields. For unicyclic and strongly coupled multicyclic machines, efficiency at maximum power is not bounded by the linear response value 1/2. For strong driving, it can even approach the thermodynamic limit 1. Quite generally, such machines fall into three different classes characterized, respectively, as "strong and efficient," "strong and inefficient," and "balanced." For weakly coupled multicyclic machines, efficiency at maximum power has lost any universality even in the linear response regime. 相似文献
62.
Kirilina E Kühne A Lindel T Hoffmann W Rhein KH Riemer T Seifert F 《Applied magnetic resonance》2011,41(2-4):507-523
A novel intrinsically decoupled transmit and receive radio-frequency coil element is presented for applications in parallel imaging and parallel excitation techniques in high-field magnetic resonance imaging. Decoupling is achieved by a twofold strategy: during transmission elements are driven by current sources, while during signal reception resonant elements are switched to a high input impedance preamplifier. To avoid B(0) distortions by magnetic impurities or DC currents a resonant transmission line is used to relocate electronic components from the vicinity of the imaged object. The performance of a four-element array for 3 T magnetic resonance tomograph is analyzed by means of simulation, measurements of electromagnetic fields and bench experiments. The feasibility of parallel acquisition and parallel excitation is demonstrated and compared to that of a conventional power source-driven array of equivalent geometry. Due to their intrinsic decoupling the current-controlled elements are ideal basic building blocks for multi-element transmit and receive arrays of flexible geometry. 相似文献
63.
T.?RublackEmail author S.?Hartnauer P.?Kappe C.?Swiatkowski G.?Seifert 《Applied Physics A: Materials Science & Processing》2011,103(1):43-50
The selective ablation of thin (∼100 nm) SiO2 layers from silicon wafers has been investigated by applying ultra-short laser pulses at a wavelength of 800 nm with pulse
durations in the range from 50 to 2000 fs. We found a strong, monotonic decrease of the laser fluence needed for complete
ablation of the dielectric layer with decreasing pulse duration. The threshold fluence for 100% ablation probability decreased
from 750 mJ/cm2 at 2 ps to 480 mJ/cm2 at 50 fs. Significant corruption of the opened Si surface has been observed above ∼1200 mJ/cm2, independent of pulse duration. By a detailed analysis of the experimental series the values for melting and breaking thresholds
are obtained; the physical mechanisms responsible for the significant dependence on the laser pulse duration are discussed. 相似文献
64.
Miriam Isabel Seifert 《Extremes》2014,17(2):193-219
An effective approach for studying the asymptotics of bivariate random vectors is to search for the limits of conditional probabilities where the conditioning variable becomes large. In this context, elliptical and related distributions have been extensively investigated. A quite general model was presented by Fougères and Soulier (Limit conditional distributions for bivariate vectors with polar representation in Stochastic Models, 2010), who derived a conditional limit theorem for random vectors (X, Y) with a polar representation R · (u(T), v(T)), where R, T are stochastically independent and R is in the Gumbel max-domain of attraction. We reformulate their assumptions, such that they have a simpler structure, display more clearly the geometry of the curves (u(t), v(t)) and allow us to deduce interesting generalizations into two directions: u has several global maxima instead of only one, the curve (u(t), v(t)) is no longer differentiable, but forms a “cusp”. The latter generalization yields results where only random norming leads to a non-degenerate limit statement. Ideas and results are elucidated by several figures. 相似文献
65.
M. E. Keillor L. E. Erikson C. E. Aalseth A. R. Day E. S. Fuller B. D. Glasgow E. W. Hoppe T. W. Hossbach L. K. Mizouni A. W. Myers C. T. Overman A. Seifert T. J. Stavenger 《Journal of Radioanalytical and Nuclear Chemistry》2013,296(2):683-687
The Pacific Northwest National Laboratory (PNNL) is currently developing a custom software suite capable of automating many of the tasks required to accurately analyze coincident signals within gamma spectrometer arrays. During the course of this work, significant crosstalk was identified in the energy determination for spectra collected with a new low-background intrinsic germanium (HPGe) array at PNNL. The HPGe array is designed for high detection efficiency, ultra-low-background performance, and sensitive γ–γ coincidence detection. The first half of the array, a single cryostat containing seven HPGe crystals, was recently installed into a new shallow underground laboratory facility. This update will present a brief review of the germanium array, describe the observed crosstalk, and present a straight-forward empirical correction that significantly reduces the impact of this crosstalk on the spectroscopic performance of the system. 相似文献
66.
E. Svatek W. Czysz B. Seifert R. H. S. F. Jancik und K.F. Becker 《Fresenius' Journal of Analytical Chemistry》1986,323(4):398-401
Ohne Zusammenfassung 相似文献
67.
68.
S. Gemming J. Tamuliene G. Seifert N. Bertram Y.D. Kim G. Ganteför 《Applied Physics A: Materials Science & Processing》2006,82(1):161-166
Electronic and geometric structures of MxSy (M = W, Mo; x=1,2,4;y=1–12) clusters have been studied using density functional theory calculations, and compared to experimental photoelectron spectra. For the metal atoms, an uptake of up to six sulfur atoms has been observed, which can be explained by the bonding of S3
- chains. A structural difference to the corresponding oxides is the preference of bridging sites for S, which might be the origin of the differences between the structures of bulk MO3 and MS2. For x=1,2 the HOMO–LUMO gaps vary irregularly. For x=4, a large HOMO–LUMO gap has been found for y=6,7, and 8 and the W4S6 and Mo4S6 clusters have been found to be magic with an extraordinarily high stability. PACS 73.22.-f; 61.46.+w 相似文献
69.
70.
H. L. Seifert J. M. Wouters D. J. Vieira H. Wollnik X. G. Zhou X. L. Tu Z. Y. Zhou G. W. Butler 《Zeitschrift für Physik A Hadrons and Nuclei》1994,349(1):25-32
The ground state masses of thirty-nine neutronrich nuclei from51Ca to72Ni have been measured using the Time-of-Flight Isochronous (TOFI) spectrometer. Eight of these masses have been measured for the first time and thirty-one are remeasurements of neutron-rich nuclei previously reported. Good agreement between these results and a previous TOFI experiment was observed except for the most neutron-rich isotopes of vanadium through iron with the present results being more bound and in better agreement with theory. The low binding energy of68Ni, as indicated by an unreasonably low two-neutron separation energy, suggests the presence of a high-lying, long-lived isomeric state in this nucleus. 相似文献