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61.
The aim of this paper is to show the effect of secondary flows caused by natural convection on the laminar-turbulent hydrodynamic transition. It is not a question of measuring a critical threshold value of Reynolds number of transition but only to estimate the degree of turbulence in the transition regime, i.e. weak turbulence in the case of superposition (mixed convection) or not (forced convection) of secondary flows on the forced flow. This is possible thanks to the application of the wavelet transform. The calculation of the H?lder exponent, associated with the maximum value of the singularity spectrum for two configurations, vertical (forced convection) and horizontal (mixed convection) allows the degree of turbulence to be measured in both cases. The variation of the H?lder exponent versus the Reynolds number has enabled it to be shown that the secondary flows stabilise the main flow and stifle the beginnings of the turbulence during the regime of transition to turbulence; these kinds of results have also been shown in literature. Generally, large-sized secondary flows (for example Dean's flows) stabilise the turbulence. Our work confirms this, through an experiment carried out in identical conditions for mixed convection (horizontal flow) and forced convection (vertical flow). Received 30 March 1998 and Received in final form 28 April 1999  相似文献   
62.
Ultrasound-assisted extraction (UAE) was used to extract carotenoids from the carrot pomace. To investigate the effect of independent variables on the UAE, the response surface methodology (RSM) with central-composite design (CCD) was employed. The study was conducted with three independent variables including extraction time (min), temperature (°C), and ethanol concentration (%). The results showed that the optimal conditions for UAE were achieved with an extraction time of 17 min, temperature of 32 °C, and ethanol concentration of 51% of total carotenoids (31.82 ± 0.55); extraction time of 16 min, temperature of 29 °C, and ethanol concentration of 59% for a combination of β-carotene (14.89 ± 0.40), lutein (5.77 ± 0.19), and lycopene (2.65 ± 0.12). The non-significant (p > 0.05) correlation under optimal extraction conditions between predicted and experimental values suggested that UAE is the more productive process than conventional techniques for the extraction of carotenoids from the carrot pomace.  相似文献   
63.
This study aims to investigate the time-dependent squeezing of nanofluid flow, comprising carbon nanotubes of dual nature, e.g. single-walled carbon nanotubes, and multi-walled carbon nanotubes,between two parallel disks. Numerical simulations of the proposed novel model are conducted,accompanied by Cattaneo-Christov heat flux in a Darcy-Forchheimer permeable media. Additional impacts of homogeneous–heterogeneous reactions are also noted, including melting heat. A relevant transformation procedure is implemented for the transition of partial differential equations to the ordinary variety. A computer software-based MATLAB function, bvp4c, is implemented to handle the envisioned mathematical model. Sketches portraying impacts on radial velocity, temperature, and concentration of the included parameters are given, and deliberated upon. Skin friction coefficient and local Nusselt number are evaluated via graphical illustrations. It is observed that the local inertia coefficient has an opposite impact on radial velocity and temperature field. It is further perceived that melting and radiation parameters demonstrate a retarding effect on temperature profile.  相似文献   
64.
Using the plane wave version of the full potential linear muffin-tin orbital (FPLMTO) method, which enables an accurate treatment of the interstitial regions, the electronic properties of ScN, YN, LaN and GdN rocksalt/rocksalt superlattices are calculated. It is found that apart from YN/ScN, all the other superlattices have negative bandgaps. However, it is shown that these systems can be semiconductors if a correction is made to the local density approximation (LDA).  相似文献   
65.
In this paper we obtain a generalisation of a theorem of Mohanty and Ray  相似文献   
66.
67.
Isoelectric focusing in a polyacrylamide pH gradient gel is used to analyze the size distribution of gold nanoparticles synthesized by a chemical route with mercaptosuccinic acid as a ligand. The isoelectric point of the nanoparticles is shown to be size dependent, allowing fractionation by electrophoresis. Each fraction has a narrow size distribution with a standard deviation lower than 0.4 nm.  相似文献   
68.
A new method is proposed for the fabrication of a well-defined size and shape distribution of silver nanoparticles in solution; the method employs direct laser irradiation of an aqueous solution containing a silver salt and a surfactant in the absence of reducing agents.  相似文献   
69.
Single crystals of (4‐ClC7H6NH3)9[Nd(P6O18)2]·9H2O were synthesized in aqueous solution. This compound crystallizes in a triclinic P1 unit‐cell, with a = 14.898(6), b = 18.049(7), c = 20.695(6)Å, α = 102.04(3), β = 100.49(3), γ = 98.82(3)°, V = 5245(4) Å3 and Z = 2. The crystal structure has been solved and refined to R = 0.043 (Rw = 0.061) for 20420 observed reflections. The atomic arrangement of the title compound can be described as infinite layers built by complex of Neodyme [Nd(P6O18)2] and nine water molecules. The organic cations are located in the space delimited by the successive inorganic layers. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   
70.
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