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91.
N. Yasuda K. Uchikawa K. Amemiya N. Watanabe H. Takahashi M. Nakazawa M. Yamamoto K. Ogura 《Radiation measurements》2001,34(1-6):45-49
As a frame work of the study for the latent track size measurement using atomic force microscope, we have measured the minute etch pits and the extremely small amount of bulk etch of CR-39 at the beginning of chemical etching, and obtained its growth curves in nanometer dimensions. The pieces of CR-39 were exposed to 6 MeV/nC and Fe ions with normal incidence angle and were etched in 70°C 7 N NaOH solution for 0.5,1,2,3,5 min. The diameters of latent track were estimated to be 17 nm for Fe ions and 8 nm for C ions, respectively. These values are comparable to the experimental data on the average ‘track core diameters’ that have been obtained by various experimental techniques. 相似文献
92.
The magnetic properties and the hyperfine interactions of Fe4N and Fe4C under high pressures are discussed on the basis of first-principles electronic structure calculations performed by the KKR
Green's function method and its extention into a full potential scheme (FP-KKR). The results show that both Fe4N and Fe4C undergo a weak first order transition from high to low spin states under pressure. This transition is sensitively reflected
not only by H
hf but also by EFG. The calculated Curie temperature, magnetic moments and H
hf well reproduce the experimental observations. 相似文献
93.
Tsuneo Itoh Ikuko Fujii Yasuo Tomii Ichiro Ishikawa Hamo Ogura Yoshihisa Mizuno Norio Kawahara 《Journal of heterocyclic chemistry》1987,24(5):1453-1455
An improved and efficient synthesis of 1,3-dialkylpyrido[2,3-d]pyrimidine-2,4-(1H,3H)-diones from 6-methylaminouracils and methyl propiolate or diethyl ethoxymethylenemalonate is described. 相似文献
94.
M Nakamura K Furuhata K Yamazaki H Ogura H Kamiya H Ida 《Chemical & pharmaceutical bulletin》1989,37(8):2204-2206
A method for analysis of 3-deoxy-D-glycero-D-galacto-2-nonulopyranosonic acid (KDN) by high-performance liquid chromatography (HPLC) with a strongly basic anion-exchange resin was developed. The method was applied to detect free KDN in water used to rinse of fertilized eggs of chum salmon, Oncorhynchus keta. Furthermore, KDN was isolated from the water as a fully protected derivative. 相似文献
95.
96.
The electric field gradients (EFGs) of B, N, O and Na in TiO2 were calculated by the full potential Korringa–Kohn–Rostoker (KKR) Greens function method in the framework of the density
functional theory. The agreement with the experiments was much improved from the previous calculations that were based on
the muffin-tin potential model. 相似文献
97.
98.
Associating polymers are hydrophilic long-chain molecules containing a small number of hydrophobic groups, and act as flocculants in aqueous suspensions. The effects of associating and nonassociating polymers on viscosity behavior are studied for silica suspensions. Since flocculation is induced by polymer bridging, the viscosity behavior is converted from Newtonian to shear-thinning profiles. The additions of surfactant cause an increase in viscosity for suspensions prepared with associating polymer, whereas the flow behavior of suspensions with nonassociating polymer is not significantly influenced. In adsorption of associating polymers onto silica particles, the chain may adopt a conformation with a water-soluble backbone attached to the particle surfaces. The hydrophobic groups extending from the chains adsorbed onto different particles can form a micelle by association with surfactant. Therefore, the bridging flocculation is enhanced by surfactant. The cooperative micellar formation between associating polymer and surfactant is responsible for viscosity increase in suspensions. 相似文献
99.
K. Ogura K. Kisaka H. Furukawa 《Journal of polymer science. Part A, Polymer chemistry》1995,33(8):1375-1380
Poly(vinyl chloride) (PVC) has been converted to an electrically conductive structure by combined electrochemical and photochemical methods. PVC was cast on a polypyrrole (PPy) film electrode which had been electrochemically prepared. The PVC layer in the laminated PVC/PPy films was first dehydrochlorinated under the illumination of UV light, and the generated polyenes were subsequently doped with I2 and FeCl3. The maximum electrical conductivity achieved for such PVC film was 2.51 X 10?2 and 8.63 10?2 S cm?1 after I2 and FeCl3 doping, respectively. The temperature dependence of the electrical conductivity showed different behavior in higher and lower temperature ranges. In the former (T > 243 K), the T?1 law held, and the activation energy and bandgap were estimated as 0.25 and 0.49 eV, respectively. In the latter (T < 243 K), the conductivity mechanism followed the variable range hopping model (T?1/4 law) in which the radius of the localized state wave function and the density of the localized states at the Fermi level were 1.25 × 103 Å and 1.03 X 1015 eV?1 cm?3, respectively. © 1995 John Wiley & Sons, Inc. 相似文献
100.
By reaction of the appropriate 2-(ω-chloroalkyl)benzimidazoles with thiourea, 2-(α-mercaptoalkyl)benzimidazoles (IV) have been prepared. The attempted preparation of 2-(β- and γ-mercaptoalkyl)benzimidazoles failed. β-Elimination was observed by alkaline treatment of S-[2-(2-benzimidazolyl)-propyl]isothiuronium chloride (VII), whereas 2-(γ-chlorobutyl)benzimidazoles did not give an isothiuronium chloride. 相似文献