全文获取类型
收费全文 | 446篇 |
免费 | 49篇 |
国内免费 | 2篇 |
专业分类
化学 | 430篇 |
力学 | 7篇 |
数学 | 11篇 |
物理学 | 49篇 |
出版年
2023年 | 5篇 |
2022年 | 7篇 |
2021年 | 6篇 |
2020年 | 9篇 |
2019年 | 10篇 |
2018年 | 4篇 |
2017年 | 7篇 |
2016年 | 25篇 |
2015年 | 18篇 |
2014年 | 17篇 |
2013年 | 25篇 |
2012年 | 30篇 |
2011年 | 37篇 |
2010年 | 15篇 |
2009年 | 20篇 |
2008年 | 32篇 |
2007年 | 23篇 |
2006年 | 31篇 |
2005年 | 38篇 |
2004年 | 27篇 |
2003年 | 20篇 |
2002年 | 25篇 |
2001年 | 6篇 |
2000年 | 2篇 |
1999年 | 3篇 |
1998年 | 4篇 |
1997年 | 2篇 |
1996年 | 7篇 |
1995年 | 5篇 |
1994年 | 3篇 |
1993年 | 3篇 |
1991年 | 3篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1987年 | 1篇 |
1985年 | 3篇 |
1984年 | 4篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1980年 | 3篇 |
1979年 | 2篇 |
1977年 | 3篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1960年 | 1篇 |
排序方式: 共有497条查询结果,搜索用时 15 毫秒
31.
Enhancement of Solar Hydrogen Evolution from Water by Surface Modification with CdS and TiO2 on Porous CuInS2 Photocathodes Prepared by an Electrodeposition–Sulfurization Method
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dr. Jiao Zhao Dr. Tsutomu Minegishi Li Zhang Dr. Miao Zhong Gunawan Dr. Mamiko Nakabayashi Dr. Guijun Ma Dr. Takashi Hisatomi Dr. Masao Katayama Prof. Dr. Shigeru Ikeda Prof. Dr. Naoya Shibata Prof. Dr. Taro Yamada Prof. Dr. Kazunari Domen 《Angewandte Chemie (International ed. in English)》2014,53(44):11808-11812
Porous films of p‐type CuInS2, prepared by sulfurization of electrodeposited metals, are surface‐modified with thin layers of CdS and TiO2. This specific porous electrode evolved H2 from photoelectrochemical water reduction under simulated sunlight. Modification with thin n‐type CdS and TiO2 layers significantly increased the cathodic photocurrent and onset potential through the formation of a p–n junction on the surface. The modified photocathodes showed a relatively high efficiency and stable H2 production under the present reaction conditions. 相似文献
32.
Jin Su Takashi Hisatomi Tsutomu Minegishi Kazunari Domen 《Angewandte Chemie (International ed. in English)》2020,59(33):13800-13806
Most CdTe photoanodes and photocathodes show positive and negative photocurrent onset potentials for water oxidation and reduction, respectively, and are thus unable to drive photoelectrochemical (PEC) water splitting without external applied biases. Herein, the activity of a CdTe photoanode having an internal p‐n junction during PEC water oxidation was enhanced by applying a CdCl2 annealing treatment together with surface modifications. The resulting CdTe photoanode generated photocurrents of 1.8 and 5.4 mA cm?2 at 0.6 and 1.2 VRHE, respectively, with a photoanodic current onset potential of 0.22 VRHE under simulated sunlight (AM 1.5G). The CdCl2 annealing increased the grain sizes and lowered the density of grain boundaries, allowing more efficient charge separation. Consequently, a two‐electrode tandem PEC cell comprising a CdTe‐based photoanode and photocathode split water without any external bias at a solar‐to‐hydrogen conversion efficiency of 0.51 % at the beginning of the reaction. 相似文献
33.
34.
35.
Polycationic‐Shelled Capsular and Tubular Nanostructures and Their Anionic–Guest Binding Properties
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dr. Kohei Yazaki Dr. Yoshihisa Sei Prof. Dr. Munetaka Akita Dr. Michito Yoshizawa 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(49):17557-17561
For the development of novel nanospace with unique electrostatic character, we prepared new capsular and tubular nanostructures by the quantitative assembly of metal ions and bent bisacridinium ligands. The capsule and tube have closed spherical and open cylindrical cavities, respectively, with diameters of around 1 nm surrounded by cationic polyaromatic panels. Thanks to the facile synthetic protocol (three steps), another polycationic capsule with an elliptical nanocavity was also prepared by using an elongated ligand. In spite of the absence of pendant hydrophilic groups, the spherical polyaromatic capsule shows sufficient water solubility due to the polycationic shell. Moreover, the highly cationic cavity (12+) can selectively encapsulate anionic organic compounds in water. 相似文献
36.
37.
Yasuhiko H. Mori Hiroshi Sano Kazunari Komotori 《International Journal of Multiphase Flow》1980,6(3):255-266
Cinemicrophotography is applied to the boiling of emulsions of water dispersed in oils whose boiling points are higher than that of water. The layer of emulsion is made thin enough to make possible a microscopic observation by transmitted light through the layer. Two alternative processes of bubble formation are found: a periodical bubble formation at specified sites on the heated solid surface contacting the emulsion and a casual bubble formation some distance away from the surface. The basic mechanisms of those processes are discussed. 相似文献
38.
Chun Gil PARK Jin Chuan HOU Sei Qwon OH 《数学学报(英文版)》2005,21(6):1391-1398
It is shown that every almost *-homomorphism h : A→B of a unital JC*-algebra A to a unital JC*-algebra B is a *-homomorphism when h(rx) = rh(x) (r 〉 1) for all x∈A, and that every almost linear mapping h : A→B is a *-homomorphism when h(2^nu o y) - h(2^nu) o h(y), h(3^nu o y) - h(3^nu) o h(y) or h(q^nu o y) = h(q^nu) o h(y) for all unitaries u ∈A, all y ∈A, and n = 0, 1,.... Here the numbers 2, 3, q depend on the functional equations given in the almost linear mappings. We prove that every almost *-homomorphism h : A→B of a unital Lie C*-algebra A to a unital Lie C*-algebra B is a *-homomorphism when h(rx) = rh(x) (r 〉 1) for all x ∈A. 相似文献
39.
40.
A carbon material as a strong protonic acid 总被引:9,自引:0,他引:9
Hara M Yoshida T Takagaki A Takata T Kondo JN Hayashi S Domen K 《Angewandte Chemie (International ed. in English)》2004,43(22):2955-2958