Hydrogen Bonding Effects on Electron Population and 13C Chemical Shift of Base: Alcohol Pyridine Complexes

The carbon chemical shifts of pyridine associated to various aliphatic and aromatic alcohols are measured. Actual effects of hydrogen bonding formation on 13c shifts, have been characterized by evaluating in first, anisotropy and non specific medium effects. Linear relationships are obtained between 13C shifts and the IR frequency shifts. Positive slopes are observed for C-β and C-γ in agreement with the electron population change, but a reverse slope results for C-α carbon.     

Growth and characterization of epitaxial Fe0.8Ga0.2/0.69PMN-0.31PT heterostructures

Fe_0.8Ga_0.2 films were deposited on bulk single-crystal (0 0 1) 0.69PMN-0.31PT substrates by DC magnetron sputtering to make magnetoelectric bilayer composites. Films deposited at temperatures below 600 °C were X-ray amorphous. Films deposited at temperatures of 600 °C and higher exhibited a single-crystal (0 0 1) disordered BCC structure. The crystalline FeGa films demonstrate a 45° twisted cube-on-cube epitaxial relationship with the PMN–PT substrates. Heterostructures with an X-ray amorphous FeGa film exhibited zero magnetoelectric response. Heterostructures with a 990 nm epitaxial FeGa film exhibited a large inverse magnetoelectric voltage coefficient of 13.4 (G cm)/V.     

Numerical simulation of gas flow in a magnetically stabilized coaxial laser discharge

The neutral gas flow profile within a magnetically stabilized coaxial laser gas discharge is analyzed by using a single fluid magnetogasdynamic model. Equations describing the rotational, radial and axial gas transport are solved by using an iterative alternating direction implicit method. Steady state rotational velocities of the order of 20 m/s are found.     

Comparative reactions between aziridines and F2, COF2, CF3OF

In CFCl₃, aziridines $\text{I}$ react with F₂(6 %/N₂,  20°C), COF₂ (20 %/N₂,  40°C) and CF₃OF [1] (20 %/N₂,  40°C).Substitution products are obtained : l-(aziridine)carbonyl fluorides $\text{II}$ and l-Fluoroaziridines $\text{III}$

In (Et)₂O, aziridines $\text{I}$ react with COF₂ (20 %/N₂, 10°C) and we have the carbonyl fluorides $\text{IV}$.

Products IV can be thermally decomposed into β fluoro isocyanates.In CFCl₃, N substituted aziridines $\text{V}$ react with F₂(6%/N₂, 20°C) and with CF₃OF [2] (20%/N₂, 40°C). No reaction is observed with COF₂in our conditions (5% to 25%/N₂, 80°C to + 40°C).Addition products are obtained : N Fluoro amines β fluorinated $\text{VI}$, N Fluoro and NN difluoro amines β trifluoro methoxylated $\text{VII}$ and $\text{VIII}$.

with R = SO₂Ø, COØNO₂, Cl.     

Coupling of general Lagrangian systems

This work is devoted to the coupling of two fluid models, such as two Euler systems in Lagrangian coordinates, at a fixed interface. We define coupling conditions which can be expressed in terms of continuity of some well chosen variables and then solve the coupled Riemann problem. In the present setting where the interface is characteristic, a particular choice of dependent variables which are transmitted ensures the overall conservativity.

     

A magnetically stabilized coaxial laser discharge

A new magnetic discharge stabilization technique for coaxial laser systems is described. The approach utilizes crosses electric and magnetic fields to create and maintain a large and rapidly rotating plasma volume which does not experience glow-to-arc transitions. Very high cw specific discharge power loadings have been achieved even without the benefit of external gas cooling or circulation.Performance is insensitive to gas composition and pressure such that high power coaxial discharges have been run in CO₂ laser gas mixtures up to several hundred torr. Stable cw discharges have also been obtained in mixtures containing several torr of SF₆.The technique appears to be readily scalable to give very large excited volumes in systems with comparatively small overall physical dimensions.     

Vision-based system for automatic stabilization of mode,beam steer,and output power of a high-power laser

As advancements in laser technology result in higher-power devices, increased thermal loads experienced by resonator optical components generate instabilities in the output beam. Consequently, methods for maintaining and optimizing output-beam parameters are necessary for efficient long-term operation. This study examines a vision-based feedback control system which monitors a sampled cross-sectional image of the laser's output, and regulates both cavity mirrors, as well as the excitation level, to stabilize beam uniformity, beam steer, and output-power level.The system optimizes the output-power distribution achievable from a given laser, while significantly reducing beam steering effects. Direction of beam propagation is restricted to within 60 rad of the desired setpoint, while the output power is stabilized to within 4%. Results clearly document a considerable improvement in laser performance through maximization of beam uniformity, minimization of beam steering, and stabilization of total output power. As such, an important degree of consistency and repeatability in output-beam parameters, essential to precision laser applications, is easily achieved. Valuable diagnostic capabilities pertaining to output beam intensity and energy profiles are also incorporated into the control system. These data may be monitored on-line or stored for subsequent analysis.