Effects of initial humidity and temperature on laser-filamentation-induced condensation and snow formation

We investigated the effects of initial humidity and temperature on the formation of water condensation and various snowflake patterns by firing high-repetition filaments of femtosecond Ti-sapphire laser pulses at 9 mJ/50 fs per pulse into a cloud chamber. While adjusting initial temperature and humidity distributions near the filaments, snowflakes and ice particles with various shapes and sizes were observed on the bottom cold plate. In addition, significant differences were found in the weights of the laser-induced snow below the filament center. From those data, initial conditions of low temperature (<?15 °C) and high humidity (relative to water RH_w > (90 ± 11) % and to ice RH_i > (120 ± 15) %) were found being important to assist an efficient laser-filamentation-induced condensation and snow formation.     

Laser-filamentation-induced condensation and snow formation in a cloud chamber

Using 1 kHz, 9 mJ femtosecond laser pulses, we demonstrate laser-filamentation-induced spectacular snow formation in a cloud chamber. An intense updraft of warm moist air is generated owing to the continuous heating by the high-repetition filamentation. As it encounters the cold air above, water condensation and large-sized particles spread unevenly across the whole cloud chamber via convection and cyclone like action on a macroscopic scale. This indicates that high-repetition filamentation plays a significant role in macroscopic laser-induced water condensation and snow formation.     

Coefficient estimates for bi-univalent Ma-Minda starlike and convex functions

Estimates on the initial coefficients are obtained for normalized analytic functions f in the open unit disk with f and its inverse g=f⁻¹ satisfying the conditions that zf^′(z)/f(z) and zg^′(z)/g(z) are both subordinate to a univalent function whose range is symmetric with respect to the real axis. Several related classes of functions are also considered, and connections to earlier known results are made.     

Supercritical Carbon Dioxide‐Treated Electrospun Poly(vinylidene fluoride) Nanofibrous Membranes: Morphology,Structures and Properties as an Ionic‐Liquid Host

A reverse‐barrier technique is used to enable the treatment of electrospun poly(vinylidene fluoride) nanofibrous membranes with supercritical carbon dioxide. The treatment induces the formation of nanopores and extended‐chain β crystallites of small lateral dimensions in the nanofibers. It also creates interfiber junctions, resulting in a remarkable improvement in mechanical properties of the membranes. The treated membranes are able to retain their shape very well after loading with an ionic liquid (IL). The ionic conductivity of the IL‐loaded membrane is very close to that of the neat IL.

     

Rapid quantification of quinine by multi‐stacking in a portable microchip electrophoresis system

A new multi‐stacking pre‐concentration procedure based on field‐enhanced sample injection (FESI), field‐amplified sample stacking, and transient isotachophoresis was developed and implemented in a compact microchip electrophoresis (MCE) with a double T‐junction glass chip, coupled with an on‐chip capacitively coupled contactless conductivity detection (C⁴D) system. A mixture of the cationic target analyte and the terminating electrolyte (TE) from the two sample reservoirs was injected under FESI conditions within the two sample‐loading channels. At the double T‐junction, the stacked analyte zones were further concentrated under field‐amplified stacking conditions and then subsequently focused by transient‐isotachophoresis and separated along the separation channels. The proposed multi‐stacking strategy was verified under a Universal Serial Bus (USB) fluorescence microscope employing Rhodamine 6G as the model analyte. This developed approach was subsequently used to monitor the target quinine present in human plasma samples. The total analysis time for quinine was approximately 200 s with a sensitivity enhancement factor of approximately 61 when compared to the typical gated injection. The detection and quantification limits of the developed approach for quinine were 3.0 μg/mL and 10 μg/mL, respectively, with intraday and interday repeatability (%RSDs, n = 5) of 3.6 and 4.4%. Recoveries in spiked human plasma were 98.1–99.8%.     

A new aspect of azo-hydrazone tautomerism

Structures of 3,5-dimethoxy-4-hydroxyazobenzene and of a new parent compound, 2,6-dimethoxy-4-hydroxyazobenzene, are investigated. Owing to their very high solubility it was possible to proceed to a comparison of the UV, ¹H NMR and ¹³C NMR data for the same solvent. Symmetric substitution by two OMe groups in the ring bearing the OH group results in the isolation of the azo or hydrazone tautomer, using the available positions of substitution. The usefulness of the ¹³C NMR technique in the investigation of azo-hydrazone tautomerism is underlined.     

Hexagonal‐Shaped Tin Glycolate Particles: A Preliminary Study of Their Suitability as Li‐Ion Insertion Electrodes

Tin glycolate particles were prepared by a simple, one‐step, polyol‐mediated synthesis in air in which tin oxalate precursor was added to ethylene glycol and heated at reflux. Hexagonal‐shaped, micron‐sized tin glycolate particles were formed when the solution had cooled. A series of tin oxides was produced by calcination of the synthesized tin glycolate at 600–800 °C. It was revealed that the micron‐sized, hexagonal‐shaped tin glycolate now consisted of nanosized tin‐based particles (80–120 nm), encapsulated within a tin glycolate shell. XRD, TGA, and FT‐IR measurements were conducted to account for the three‐dimensional growth of the tin glycolate particles. When applied as an anode material for Li‐ion batteries, the synthesized tin glycolate particles showed good electrochemical reactivity in Li‐ion insertion/deinsertion, retaining a specific capacity of 416 mAh g^?1 beyond 50 cycles. This performance was significantly better than those of all the other tin oxides nanoparticles (<160 mAh g^?1) obtained after heat treatment in air. We strongly believe that the buffering of the volume expansion by the glycolate upon Li–Sn alloying is the main factor for the improved cycling of the electrode.