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Patrick Achenbach Sebastian Bleser Josef Pochodzalla Alicia Sanchez Lorente Marcel Steinen 《Hyperfine Interactions》2012,208(1-3):99-104
Samples obtained as a result of the valleriite synthesis process under different conditions (temperature and proportion Cu:Fe:Mg in the initial mixture) were investigated by 57Fe M?ssbauer spectroscopy with attraction data of X-ray diffraction. Parameters of hyperfine interactions for valleriite were determined and crystal chemical identification of 57Fe subspectra was carried out. It was found that valleriite was formed in samples synthesized at 150°C and 180°C and not formed in samples synthesized at 250°C. 相似文献
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Sebastian Aland Stephan Schwarz Jochen Fröhlich Axel Voigt 《The European physical journal. Special topics》2013,220(1):185-194
In simulations of liquid metals, various model approximations, each of which justified by experimental results lead to a simplified two-phase flow problem. This paper discusses numerical justifications for these approaches and provides quantitative results for a single rising bubble as a benchmark. Representing a bubble as a rigid object is shown to be valid for low Eötvös numbers in contaminated systems. Qualitative differences can be observed for larger Eötvös numbers. Further simulations are undertaken with different ratios of inner and outer viscosity. The benchmark problem considered may also be interesting for more general applications. 相似文献
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Bozena Pietrzyk Sebastian Miszczak Hieronim Szymanowski Anna Sobczyk-Guzenda Zbigniew Gawronski 《Journal of Sol-Gel Science and Technology》2013,68(3):455-463
The sol–gel process is widely used for the production of powders, coatings and bulk materials. However, being a wet-chemical technique, it has certain limitations related to properties of aqueous colloidal solution, especially when applied as a coating. The most frequently used methods, such as dip- and spin-coating, are difficult to apply onto more complex substrates. In these cases, the aerosol–gel deposition method can be regarded as the solution of this problem. In the present article, a novel plasma enhanced aerosol–gel method of coatings production is presented. A novelty of this method is based on an integration of the aerosol–gel deposition of thin films and their low temperature plasma treatment. Owing to the above, all stages of the coatings production process—substrate preparation, film deposition, and its plasma treatment, can be carried out in a single reactor. The design and operational scheme of such device is presented in this work. Using this device, thin coatings were first deposited on substrates and then plasma treated. The effect of deposition and plasma discharge conditions on morphology and chemical structure of the films has been studied. It was found that plasma treatment had a substantial influence on all the examined properties of the aerosol–gel deposited coatings. 相似文献
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Marcin Śnieżek Sebastian Stecko Irma Panfil Bartłomiej Furman Zofia Urbańczyk-Lipkowska Marek Chmielewski 《Tetrahedron: Asymmetry》2013,24(2-3):89-103
The stereoselectivity of 1,3-dipolar cycloaddition reactions of C-phenyl open-chain nitrones and α,β-unsaturated γ- and δ-lactones was investigated under thermal and catalytic conditions. It was found that under thermal conditions, the endo approach of the reactants was preferred leading to the thermodynamic product. In the presence of Sc(OTf)3 the exo adduct was obtained in high yield and selectivity. The energies of the cycloaddition reactions were investigated by means of molecular orbital calculations at the B3LYP/6-31+G(d,p) and MP3/6-31+G(d,p) theory level. Different reaction channels and reactant approaches, fitting the individual regio- and stereochemical preferences, are discussed. The computational results were compared with the corresponding experimental data and found to be in good agreement. 相似文献
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