Cylindrical spike model for the formation of diamondlike thin films by ion deposition

T /n_S of n_T rearrangements and n_S atoms in the spike volume as the crucial parameter characterizing the ability of a given ion–target combination to achieve complete rearrangement of the spike volume. n_T/n_S>1 is the optimum condition for diamondlike film growth. For aC films the ion energy dependence of n_T/n_S agrees well with the measured sp³ bond fraction. For Ar⁺-ion-assisted deposition of aC we find n_T/n_S>1 above 50 eV with no pronounced ion energy dependence. Furthermore, our model predicts optimum conditions for the formation of cubic boron nitride between 50 eV and 3 keV. Accepted: 14 October 1997     

Comparative study of the specific heat of superconducting and non-superconducting YBa2Cu3O7−x

We have measured the specific heat, the electrical resistance and the magnetic susceptibility of YBa₂Cu₃O_7–x in a superconducting (sc) and in a non-superconducting (nsc) version. The latter was obtained by inducing a small loss of oxygen. In the sc sample we find a jump of the specific heat with C=3.6 J mole^–1 K^–1. Below the maximum nearT _c the specific heat of the sc version drops too fast for an electronic effect alone: there is a cross-over from excess to deficiency already at 0.9T _c . The specific heat of the nsc version shows a change of slope in the temperature range between 70 and 80 K, which indicates the existence of a second specific heat anomaly, which apparently exists independently of that due to the onset of superconductivity and explains at least partially the premature crossover.Alexander von Humboldt fellow. On leave in absence from Centro Atomico Bariloche—CNEA Argentina     

Γ-Lakton-cis-anellierung an Δ2- und Δ3- Cholesten

γ-Lactone-cis-annulation to Δ²- and Δ³- Cholestene. From Δ²- and Δ³- cholestene the γ-lactones 11a , 11b , 12a , and 12b are synthesized through the dibromocarbene adducts 3 and 4 , the bromohydrines 5 and 6 , the oxapiropentanes 7 and 8 , and the cyclobutanones 9a , 9b and 10a , 10b , respectively. The ¹³C-NMR.-spectra of 1–8 and 11 as well as the ORD.-spectra of the cyclobutanones 9 and 10 are reported.