全文获取类型
收费全文 | 2734篇 |
免费 | 74篇 |
国内免费 | 20篇 |
专业分类
化学 | 1938篇 |
晶体学 | 24篇 |
力学 | 41篇 |
数学 | 232篇 |
物理学 | 593篇 |
出版年
2023年 | 22篇 |
2022年 | 27篇 |
2021年 | 30篇 |
2020年 | 36篇 |
2019年 | 46篇 |
2018年 | 24篇 |
2017年 | 42篇 |
2016年 | 72篇 |
2015年 | 57篇 |
2014年 | 57篇 |
2013年 | 127篇 |
2012年 | 155篇 |
2011年 | 166篇 |
2010年 | 73篇 |
2009年 | 74篇 |
2008年 | 156篇 |
2007年 | 160篇 |
2006年 | 201篇 |
2005年 | 161篇 |
2004年 | 150篇 |
2003年 | 106篇 |
2002年 | 140篇 |
2001年 | 47篇 |
2000年 | 51篇 |
1999年 | 33篇 |
1998年 | 23篇 |
1997年 | 22篇 |
1996年 | 34篇 |
1995年 | 14篇 |
1994年 | 30篇 |
1993年 | 26篇 |
1992年 | 27篇 |
1991年 | 18篇 |
1990年 | 13篇 |
1989年 | 27篇 |
1988年 | 22篇 |
1987年 | 21篇 |
1986年 | 19篇 |
1985年 | 28篇 |
1984年 | 25篇 |
1982年 | 15篇 |
1981年 | 24篇 |
1979年 | 12篇 |
1978年 | 26篇 |
1977年 | 18篇 |
1976年 | 14篇 |
1975年 | 13篇 |
1974年 | 21篇 |
1973年 | 25篇 |
1972年 | 12篇 |
排序方式: 共有2828条查询结果,搜索用时 62 毫秒
41.
The interaction of organotin halides with lithium salts of mono-substituted phosphorus ylids and also with disubstituted ylids is described. 相似文献
42.
43.
Turney K Drake TJ Smith JE Tan W Harrison WW 《Rapid communications in mass spectrometry : RCM》2004,18(20):2367-2374
Nanoparticles for the extraction of peptides and subsequent analysis using atmospheric pressure matrix-assisted laser desorption/ionization (APMALDI) have been evaluated. The atmospheric pressure source allows for particles to be directly introduced in the liquid matrix, minimizing sample loss and analysis time. Described in this work are two sample preparation procedures for liquid APMALDI analysis: a C18 functionalized silica nanoparticle for hydrophobic extractions, and an aptamer functionalized magnetite core nanoparticle for rapid, affinity extractions. The C18 particles provide a non-selective support for rapid profiling applications, while the aptamer particles are directed towards reducing the complexity in biological samples. The aptamer functionalized particles provide a more selective analyte-nanoparticle interaction whereby the tertiary structure of the analyte becomes more critical to the extraction. In both cases, the liquid APMALDI matrix provides a support for ionization, and acts as the releasing agent for the analyte-particle interaction. Additionally, analyte enrichment was possible due to the large surface-to-volume ratio of the particles. The experiments conducted with functionalized nanoparticles, in an atmospheric pressure liquid matrix, present a basis for further methodologies and utilities of silica nanoparticles to be developed. 相似文献
44.
Turan K. Yazicilar Omer Andac Yunus Bekdemir Halil Kutuk Veysel T. Yilmaz William T. A. Harrison 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(1):m21-m22
The title compound, alternatively named sodium 6‐nitro‐3H‐1,2,3‐benzoxathiazole 2,2‐dioxide monohydrate, Na+·C6H3N2O5S?·H2O, consists of chains of NaO7 units, with the seven donor‐O atoms coming from two water molecules and five p‐nitrobenzoxasulfamate anions. The seven‐coordinate geometry around the Na+ ion is described as monocapped trigonal prismatic, but with a large distortion from ideal geometry. Each triangular face is defined by one O atom each from a water molecule, a nitro group and a sulfonyl group. An O atom from a sulfonyl group caps one of the square faces of the trigonal prism in an unsymmetrical fashion. The water molecules and one sulfonyl O atom are involved in bridging adjacent units, as is the nitro group of the anion. The sulfamate ions adopt an antiparallel alignment between the NaO7 units and are connected to each other by C—H?O and π–π interactions. The three‐dimensional crystal structure is stabilized by a network of strong O—H?N hydrogen bonds. 相似文献
45.
The double-T injector design employed in many microchip capillary electrophoresis devices allows for the formation of very small (50-500 pL) sample plugs for subsequent analysis on-chip. In this study, we show that sample plugs formed at the channel junction can be geometrically defined. The channel width and injector symmetry prove to be of great importance to good performance. A unique pushback of solvent into the side channels can be induced when the side channels have a very low resistance to flow, and this helps to better define the injected sample plug. Samples and running buffers of differing ionic strength (e.g., 10 mM KCl buffer and 20 mM KCl sample) can yield widely variable results in terms of plug shape and amount injected (variations of 1.5 to 10x). Applying bias voltages to all the intersecting channels aids in controlling the plug shape. However, when the ionic strengths of buffer and sample are not matched, the actual amount injected (up to 10x variations) can be inconsistent with the appearance of the plug formed in the injector (up to only 30 % variations). Operating at constant pH and ionic strength produced the most consistent results. This report examines the effects of altering the injector geometry and solution ionic strengths, and presents the results of using bias voltages to control plug formation. The observed results should provide a benchmark for modeling of the fluid dynamics in channel intersections. 相似文献
46.
47.
48.
Mercury dissolution in HCl and Pb in H2SO4 have been investigated using automated equipment of new design. The characteristic electrochemical parameter curves derived from the steady-state impedance and current-potential curves are reported. The data spans the active-passive transition and the passive region. An interpretation of the data in the passive region, based on a reaction kinetic model, is discussed. 相似文献
49.
Continued efforts to identify compatible or incompatible blends have demonstrated a need to separate overlapping curves or peaks in a thermal trace. One way to do this is by using the derivatives of these curves. While the function is available on most modern thermal analysis units, its usefulness is often limited by noise in the system. Two techniques which can help to greatly reduce noise are digital filtering and Fourier transformation of the data. Both approaches have been used on identical sets of noisy data. The FT method appears to offer greater potential for producing useful derivatives from noisy composite curves.
Zusammenfassung Ständige Versuche zur Identifizierung kompatibler und nichtkompatibler Gemische haben die Notwendigkeit mit sich gebracht, sich überlappende Kurven oder Peaks in thermischen Kurvenverläufen zu trennen. Eine Möglichkeit dafür bietet die Registrierung difierenzieller Kurven. Diese können mit den meisten modernen Geräten aufgenommen werden, ihre Brauchbarkeit wird aber oft durch den Geräuschpegel im System limitiert. Der Geräuschpegel kann durch digitale Filterung und durch Fourier-Transformation der Daten herabgesetzt werden. Beide Methoden wurden unter Verwendung identischer Datenserien geprüft. Die FT-Methode scheint bessere Möglichkeiten zu bieten, geeignete Differentialkurven aus starkes Rauschen aufweisenden Kurvenverläufen zu erhalten.
. . , . , , - . . - .相似文献
50.