全文获取类型
收费全文 | 9653篇 |
免费 | 437篇 |
国内免费 | 4篇 |
专业分类
化学 | 6168篇 |
晶体学 | 89篇 |
力学 | 397篇 |
数学 | 1593篇 |
物理学 | 1847篇 |
出版年
2023年 | 68篇 |
2022年 | 88篇 |
2021年 | 121篇 |
2020年 | 196篇 |
2019年 | 206篇 |
2018年 | 261篇 |
2017年 | 215篇 |
2016年 | 408篇 |
2015年 | 312篇 |
2014年 | 343篇 |
2013年 | 827篇 |
2012年 | 621篇 |
2011年 | 685篇 |
2010年 | 388篇 |
2009年 | 350篇 |
2008年 | 608篇 |
2007年 | 622篇 |
2006年 | 560篇 |
2005年 | 492篇 |
2004年 | 368篇 |
2003年 | 326篇 |
2002年 | 289篇 |
2001年 | 130篇 |
2000年 | 107篇 |
1999年 | 105篇 |
1998年 | 86篇 |
1997年 | 74篇 |
1996年 | 88篇 |
1995年 | 70篇 |
1994年 | 64篇 |
1993年 | 62篇 |
1992年 | 52篇 |
1991年 | 33篇 |
1990年 | 30篇 |
1989年 | 36篇 |
1988年 | 27篇 |
1987年 | 33篇 |
1985年 | 64篇 |
1984年 | 47篇 |
1983年 | 26篇 |
1982年 | 58篇 |
1981年 | 50篇 |
1980年 | 58篇 |
1979年 | 48篇 |
1978年 | 38篇 |
1977年 | 37篇 |
1976年 | 47篇 |
1975年 | 48篇 |
1974年 | 30篇 |
1973年 | 31篇 |
排序方式: 共有10000条查询结果,搜索用时 109 毫秒
51.
Solubility of carbon dioxide in aqueous solutions of sodium chloride: Experimental results and correlation 总被引:2,自引:0,他引:2
The solubility of carbon dioxide in aqueous solutions of sodium chloride was measured in the temperature range from 40 to 160°C, up to 6 mol-kg salt solutions and total pressures up to 10 MPa. Pitzer's(1) equations as well as the Chen and Evans(2) model were used to correlate the new data. Results are reported and compared to literature data and correlations. 相似文献
52.
The complexification of a semi-algebraic set is the smallest complex algebraic set containing S. Let S be defined by s polynomials of degrees less than d. We prove that the geometric degree of the complexification is less than .
Received: 9 January 1997; in final form: 11 August 2000 / Published online: 17 May 2001 相似文献
53.
We consider a class of problems originating from a Raman laser amplification model, for which the equations can be written as a Poisson system with boundary conditions. Once reformulated, this system becomes an integro-differential equation that we study here in some detail. In particular, we show the existence of a smooth solution under general assumptions, and prove its uniqueness for boundary values that are not too far apart. Eventually, we completely solve the question of uniqueness for systems of dimensions one and two. To cite this article: F. Castella et al., C. R. Acad. Sci. Paris, Ser. I 336 (2003). 相似文献
54.
Electric and spatial characteristics of a pulse-periodic microsecond barrier discharge are investigated in different geometries—triangular
prism, plate, and corrugated electrode—that are in contact with a dielectric plate and form a dihedral angle with it. It is
established that, in the space of the dihedral angle, the regions of discharge represent alternating cylindrical layers with
the axes lying on the contact line. The first conducting layer is formed at some distance from the contact edge of the electrode.
The number of layers and their localization are determined by the angle formed between an electrode and the dielectric plate.
A physical model explaining the main features of the structure formation is proposed. 相似文献
55.
Al-Cu-Fe thin films were prepared by laser induced arc (laser-arc) method from a single source—Al63Cu25Fe12 alloy, which was proved to consist of quasicrystalline phase together with approximant phase. The composition of the deposited films meets the requirement for formation of icosahedral symmetry phase. Quasicrystalline phase was obtained after annealing the amorphous as-deposit film samples. The optical properties of the samples were investigated. Thin film samples of Al, Cu and Fe deposited under the same condition were employed for comparison. The results showed specific reflective properties of Al-Cu-Fe quasicrystal thin film in some wavelength range. The optical conductivity of the films exhibited a negative peak, centered about 440 nm in range of 190 to 800 nm. The Al-Cu-Fe quasicrystal thin films could absorb almost all the ray in the wavelength range from 420nm to 450 nm. The ratio of absorption was greater than 99%. 相似文献
56.
Ha Yong Lee Se Hun Jung Soo Yong Lee Young Ho You Kyung Hyun Ko 《Applied Surface Science》2005,252(5):1891-1898
Al-Al2O3 composite coatings with different Al2O3 particle shapes were prepared on Si and Al substrate by cold spray. The powder compositions of metal (Al) and ceramic (Al2O3) having different sizes and agglomerations were varied into ratios of 10:1 wt% and 1:1 wt%. Al2O3 particles were successfully incorporated into the soft metal matrix of Al. It was found that crater formation between the coatings and substrate, which is typical characteristic signature of cold spray could be affected by initial starting Al2O3 particles. In addition, when the large hard particles of fused Al2O3 were employed, the deep and big craters were generated at the interface between coatings and hard substrates. In the case of pure soft metal coating such as Al on hard substrate, it is very hard to get proper adhesion due to lack of crater formation. Therefore, the composite coating would have certain advantages. 相似文献
57.
This study compared the fracture strength of Class II slot cavities restored with polymerizable restorative materials. Sixty, caries-free, posterior teeth were divided into five groups of 12 teeth. The Class II slot cavities were prepared. The teeth were restored with two packable composites (Filtek P60, Surefil), a microhybrid composite (Filtek Z250)and two ormocer (Definite, Admira). The restorations were then subjected to fracture resistance tests. The marginal ridges of the restorations were loaded at an angle of 13.5° to the long axis of the tooth in an Universal Testing Machine until failure. Analysis of mean forces indicated that, Filtek P60, Surefil and Filtek Z250 exhibited better performance than Definite and Admira. The tested resin composites differed in their mechanical properties. This study suggested that fracture behavior were highly influenced by the filler system. Overall, Filtek P60, Surefil, Filtek Z250, demonstrated good fracture resistance. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
58.
Jean-Pierre Françoise 《Journal of Dynamics and Differential Equations》2008,20(4):777-786
This article is devoted to one-dimensional perturbative theory on R × S
1. There is a recursive formula for the successive obstructions to parametric center at any order of the perturbation parameter.
The first obstruction is studied by means of complex analysis techniques. This extends to the trigonometric case what was
done previously for the polynomial case (Israel J. Math. 142, 273–283, 2004).
This article is dedicated to Professor Zhang Zhi-Fen on the occasion of her 80th Birthday 相似文献
59.
Volkan Kseli Zakir M. O. Rzaev Erhan Pikin 《Journal of polymer science. Part A, Polymer chemistry》2003,41(11):1580-1593
Stimuli‐responsive poly[(N‐isopropylacrylamide‐co‐maleic anhydride)‐g‐poly(ethylene oxide)]/poly(ethylene imine) macrobranched macrocomplexes were synthesized by (1) the radical copolymerization of N‐isopropylacrylamide and maleic anhydride with α,α′‐azobisisobutyronitrile as an initiator in 1,4‐dioxane at 65 °C under a nitrogen atmosphere, (2) the polyesterification (grafting) of prepared poly(N‐isopropylacrylamide‐co‐maleic anhydride) containing less than 20 mol % anhydride units with α‐hydroxy‐ω‐methoxy‐poly(ethylene oxide)s having different number‐average molecular weights (Mn = 4000, 10,000, or 20,000), and (3) the incorporation of macrobranched copolymers with poly(ethylene imine) (Mn = 60,000). The composition and structure of the synthesized copolymer systems were determined by Fourier transform infrared, 1H and 13C NMR spectroscopy, and chemical and elemental analyses. The important properties of the copolymer systems (e.g., the viscosity, thermal and pH sensitivities, and lower critical solution temperature behavior) changed with increases in the molecular weight, composition, and length of the macrobranched hydrophobic domains. These copolymers with reactive anhydride and carboxylic groups were used for the stabilization of penicillin G acylase (PGA). The conjugation of the enzyme with the copolymers significantly increased the thermal stability of PGA (three times at 45 °C and two times at 65 °C). © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1580–1593, 2003 相似文献
60.
J. Salgado E. Martinho I. F. Gonçalves 《Journal of Radioanalytical and Nuclear Chemistry》2004,260(2):317-320
The resonance neutron self-shielding factor, G
res, is required in neutron metrology and activation data analysis. In a previous paper, the authors have shown that a dimensionless
variable can be introduced which converts the dependence of G
res on the physical and nuclear properties of the material samples into an universal curve, valid for the isolated resonances
of any nuclide. This work presents a methodology based on the universal curve, which enables to calculate G
res for a group of isolated resonances by weighting its individual contributions. A good agreement was reached with results calculated
by the MCNP code and with experimental values for Mo foils and wires.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献