Carrier cooling and recombination heating in intermixed GaAs/AlGaAs quantum wires and dots

Il Nuovo Cimento D - The cooling of photoexcited hot carriers in 2D, 1D and 0D systems is studied experimentally. In comparison with a theoretical carrier relaxation model which holds for 2D and 1D...     

Charakterisierung und Quantifizierung von Mineralstoffbindungen in Lebensmitteln

Summary Ion-exchange on Chelex-100, donnan dialysis and the method of ion-retardation are applied to characterize the bonding strengths of the minerals Ca, Mg and Zn in milk and extracts of meat and flour. Another ion-exchange procedure and direkt potentiometry with an Ca-selective electrode are applicate for the quantification of weak bindings. By use of the above mentioned methods it is possible to calculate element species stabilities, which represent characteristic values. Both methods give comparable results for milk, extracts of meat and spinach, grape-juice, red and white wine. Detailed examinations of binding conditions in milk proved citrate to the strength binding compound for Ca and Mg. Model-examinations with citrate, caseine and phosphate agree well with calculations and measurements in milk. Furthermore differences in the binding of Ca and Mg in raw and cream spinach are examined. The above mentioned methods are suitable to characterize and quantify the binding of elements in foodstuffs. The results give informations about chemical changes due to technological processes e.g., in regard to storage life.     

Three-dimensional pictures of industrial scenes applying an optical radar

For small scale ranging, a light beam, modulated with a wavelength typical for radio waves, is a suitable means of scanning. The ranging beam can be focussed to illuminate only a small spot. The diffuse reflection on the spot ensures that an echo appears. By applying phase comparison techniques to the ranging and echo beam the optical path length and thus the height of the illuminated surface element can be determined. By systematically deflecting the beam and thereby scanning the scene, a discrete height map is obtained. The realisation of such a small scale ‘optical radar’ is described, the main elements of which are a semiconductor diode laser for emission, an avalanche photo diode for detection, and a two-dimensional beam deflection mechanics for scanning. The typical performance is taking a picture of a volume of about 0·5 m × 0·5 m × 0·5 m within 1s, consisting of about 64 000 pixels.     

Properties of dysprosium-doped gallium lanthanum sulfide fiber amplifiers operating at 1.3 microm

In light of recent progress in the fabrication of gallium lanthanum sulfide (GaLaS) fibers, we have modeled the performance of dysprosium-doped GaLaS fiber amplifiers operating at 1.3mum . Based on experimental data, we find that the incorporation of a codopant (terbium) in the fiber core significantly shortens the optimum amplifier length from >30 m to ~3 m . Such a device may be practical, given the fiber losses currently achieved in GaLaS fibers.     

In 2- und 3-Stellung verzweigte,enantiomerenreine 4,4,4-Trifluor-3-hydroxy-buttersäure-Derivate aus 6-Trifluormethyl-1,3-dioxan-und -dioxin-4-onen

Preparation of Enantiomerically Pure 4,4,4-Trifluoro-3-hydroxy-butanoic Acid Derivatives, Branched in the 2- or 3-Position, from 6-Trifluoromethyl-1,3-dioxan- and -dioxin-4-ones Enantiomerically pure 3-hydroxy-3-trifluoromethyl-propionic acid and esters, substituted in the 2- or 3-position, are prepared (13 examples) from (R)- or (S)-4,4,4-trifluoro-3-hydroxy-butanoic acid. Key intermediates are the 2-t-butyl-6-trifluoromethyl-1,3-dioxan- and -dioxin-4-ones. The Li enolate of the cis-dioxanone is generated with t-BuLi and reacts with electrophiles (alkyl halides, aldehydes, imines, nitroolefins, Br₂, I₂) with predominant formation of trans,trans-2,5,6-trisubstituted dioxanones (9 examples). Elimination of HBr from the 5-Br-substituted dioxanone gives the (R)- or (S)-dioxinone, a chiral derivative of 4,4,4-trifluoro-3-oxo-butanoic acid (trifluoro-acetoacetate). Michael additions of cuprates or of CuCl-doped Grignard reagents to the dioxinone produce 6,6-disubstituted dioxanones (10 examples) bearing a CF₃ group in the 6-position. In most cases this addition is highly diastereoselective, with the new substituent winding up in the trans position. There are, however, surprising exceptions, such as the product formed with benzylmagnesium chloride which is an abnormal adduct with a p-quinoid structure ( 26 ) and with the newly introduced group in the cis position with respect to the t-Bu group. The structures of four trisubstituted dioxanones bearing CF₃ groups are determined by X-ray crystal structure analysis (Figure 1, Table 1), one of them including the absolute configuration (by anomalous diffraction). Besides the well-known sofa, a twist-boat conformation of dioxanones appears to be favorable. The solution conformations of the different types of CF₃-substituted dioxanones are derived from Nuclear Overhauser NMR measurements and compared with the crystal structures (Figure 3).