Cs6Re6S15 – eine Verbindung,in der [Re6S8]-Baueinheiten über Disulfidbrücken verknüpft eine Gerüststruktur bilden

Cs₆Re₆S₁₅ – a Compound, in which [Re₆S₈] Clusters are Linked by Disulphide-Bridges Giving a Framework Structure Cs₆Re₆S₁₅ was synthesized by the reaction of cesium carbonate with rhenium in a stream of H₂S at 800°C. Structural investigations on single crystals revealed an atomic arrangement in which [Re₆S₈] clusters are linked threedimensionally by S₂^2? bridges. Additionally inserted sulphide ions lead to the formula Cs₆S{[Re₆S₈](S₂)_6/2}. The nearly regular Re₆-octahedra correspond with a 24-electron configuration.     

Zur Kenntnis organischer Molekülverbindungen XI. Die Theorie Dolezaleks

Ohne Zusammenfassung     

The Ternary System Nickel/Silicon/Titanium Revisited

The constitution of the ternary system Ni/Si/Ti is investigated over the entire composition range using X‐ray diffraction (XRD), energy dispersive X‐ray spectroscopy (EDS), differential thermal analysis (DTA), and metallography. The solid state phase equilibria are determined for 900 °C. Eight ternary phases are found to be stable. The crystal structures for the phases τ₁NiSiTi, τ₂Ni₄Si₇Ti₄, τ₃Ni₄₀Si₃₁Ti₁₃, τ₄Ni₁₇Si₇Ti₆, and τ₅Ni₃SiTi₂ are corroborated. For the remaining phases the compositions are determined as Ni₆Si₄₁Ti₅₃ (τ₆), Ni₁₆Si₄₂Ti₄₂(τ₇), and Ni₁₂Si₄₅Ti₄₃ (τ₈). The reaction scheme linking the solid state equilibria with the liquidus surface is amended to account for these newly observed phases. The discrepancies between previous experimental conclusions and modeling results are addressed. The liquidus surface is dominated by the primary crystallisation field of τ₁NiSiTi, the only congruently melting phase.     

Production of a dual-species Bose-Einstein condensate of Rb and Cs atoms

We report the simultaneous production of Bose-Einstein condensates (BECs) of ⁸⁷Rb and ¹³³Cs atoms in separate optical traps. The two samples are mixed during laser cooling and loading but are separated by 400 μm for the final stage of evaporative cooling. This is done to avoid considerable interspecies three-body recombination, which causes heating and evaporative loss. We characterize the BEC production process, discuss limitations, and outline the use of the dual-species BEC in future experiments to produce rovibronic ground state molecules, including a scheme facilitated by the superfluid-to-Mott-insulator (SF-MI) phase transition.     

EPR Studies of Tl0.5Pb0.5Sr1.6Ba0.4CaCu2?xRuxO7?δ Superconductor

Bulk superconducting samples of type Tl_0.5Pb_0.5Sr_1.6Ba_0.4CaCu_2−x Ru _x O_7−δ, (Tl, Pb)/Sr-1212, with 0.0 ≤ x ≤ 0.525 were prepared by the conventional one-step solid-state reaction technique. The prepared samples were investigated using X-ray powder diffraction, electrical resistivity and electron paramagnetic resonance (EPR) measurements. Enhancement of the phase formation, superconducting transition temperature T _c and hole carriers concentration P was observed up to x = 0.075. For x > 0.075, a reverse trend was observed. EPR spectra were measured at different temperatures (120–290 K) for all prepared samples. The number of spins N participating in the resonance and the paramagnetic susceptibility χ were calculated as a function of both Ru-content and temperature. N and χ increased as the Ru-content increased. A linear relationship between logN and 1/T was established, from which the activation energy E _a was calculated as a function of the Ru-content. The temperature dependence of χ was fitted according to Curie–Weiss type of magnetic behavior. Curie constant C, Curie temperature θ, the effective magnetic moment μ and the electronic specific heat γ were estimated as a function of the Ru-content.     

Bending insensitivity of fiber Bragg gratings in suspended-core optical fibers

This Letter presents simulation and experimental results that explore bending insensitivity of fiber Bragg gratings in suspended-core optical fibers. The implementation of thin silica bridge in the fibers enhances index contrast of the fiber core and reduces bending-induced strain transfer to the fiber core. This fiber design lead to a reduction of over 7 times in strain-induced fiber Bragg grating resonant peak shifts in the suspended-core fiber compared with that in standard telecommunication fiber, and an 0.14 dB bending loss at a bending radius of 6.35 mm.