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101.
Khaldun M. AL Azzam Bahruddin Saad Rohana Adnan Muhammad Idiris Saleh 《Mikrochimica acta》2009,166(3-4):311-317
A fast capillary electrophoretic method is described for the separation and determination of the enantiomers of the novel wake-promoting agent, modafinil. Several parameters affecting the separation were studied, including the type and concentration of chiral selector, buffer pH, buffer concentration, voltage and temperature. Good chiral separation of the racemic mixture was achieved in less than 5 min with resolution factor Rs?=?2.51, using a bare fused-silica capillary and a background electrolyte (BGE) of 25 mM H3PO4?1 M tris solution; pH 8.0; containing 30 mg mL?1 of sulfated-β-cyclodextrin (S-β-CD). The separation was carried out in normal polarity mode at 25 ?C, 18 kV and using hydrostatic injection. Acceptable validation criteria for selectivity, linearity, precision, and accuracy were included. The developed method was successfully applied to the assay of enantiomers of modafinil in pharmaceutical formulations. The computational calculations for the enantiomeric inclusion complexes rationalized the reasons for the different migration times between the modafinil enantiomers. 相似文献
102.
We investigate very weak solutions to the instationary Navier–Stokes system being contained in where is a bounded domain and . The chosen space of data is small enough to guarantee uniqueness of solutions and existence in case of small data or short
time intervals. On the other hand, the data space is large enough that every vector field in is a very weak solution for appropriate data. The solutions and the data depend continuously on each other.
相似文献
103.
D. Kraus A. OttenA. Frank V. BagnoudA. Bla?evi? D.O. GerickeG. Gregori A. Ortner G. SchaumannD. Schumacher J. VorbergerF. Wagner K. WünschM. Roth 《High Energy Density Physics》2012,8(1):46-49
We present measurements of the changes in the microscopic structure of graphite in a laser-driven shock experiment with X-ray scattering. Laser radiation with intensities of ∼2 × 1013 W/cm2 compressed the carbon samples by a factor of two reaching pressures of ∼90 GPa. Due to the change of the crystalline structure the scattered signals of the probe radiation were modified significantly in intensity and spectral composition compared to the scattering on cold samples. It is shown that the elastic scattering on tightly bound electrons increases strongly due to the phase transition whereas the inelastic scattering on weakly bound electrons remains nearly unchanged for the chosen geometry. 相似文献
104.
Marion B. Ansorge‐Schumacher 《Nachrichten aus der Chemie》2014,62(12):1175-1178
105.
Debdutta Lahiri Surinder M. Sharma Ashok K. Verma B. Vishwanadh G. K. Dey Gerhard Schumacher Tobias Scherb Heinrich Riesemeier Uwe Reinholz Martin Radtke S. Banerjee 《Journal of synchrotron radiation》2014,21(6):1296-1304
Short‐range order has been investigated in Zr69.5Cu12Ni11Al7.5 and Zr41.5Ti41.5Ni17 metallic glasses using X‐ray absorption spectroscopy and ab initio molecular dynamics simulations. While both of these alloys are good glass formers, there is a difference in their glass‐forming abilities (Zr41.5Ti41.5Ni17 > Zr69.5Cu12Ni11Al7.5). This difference is explained by inciting the relative importance of strong chemical order, icosahedral content, cluster symmetry and configuration diversity. 相似文献
106.
M. Leins J. Kopecki S. Gaiser A. Schulz M. Walker U. Schumacher U. Stroth T. Hirth 《等离子体物理论文集》2014,54(1):14-26
Microwave plasmas at atmospheric pressure are used for surface treatments like for example cleaning, sterilization or decontamination purposes, for a pre‐treatment to increase the adhesion of lacquer, paint, or glue, and for the deposition of different kind of layers and coatings. Micro plasma jets can also be applied for biomedical applications and for treatment of small and complex geometries like for example the inside of capillaries. Larger plasma torches which exhibit higher gas temperatures can also be used for chemical syntheses like waste gas decomposition, methane pyrolysis, or carbon dioxide dissociation and for plasma spraying purposes. In the present publication an overview on the development and the investigation of the operating principle of two atmospheric pressure microwave plasma torches at frequencies of 2.45 GHz and 915 MHz will be presented. The plasma sources are based on a cylindrical resonator combined with coaxial structures. To explain how these plasma sources work, simulations of the electric field distribution will be discussed. Furthermore, some physical characteristics of an air and an Ar/H2 atmospheric plasma like gas temperatures, excitation temperatures and densities as well as the heating of the plasma by the microwave will be investigated. (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
107.
Montgomery NA Hedley GJ Ruseckas A Denis JC Schumacher S Kanibolotsky AL Skabara PJ Galbraith I Turnbull GA Samuel ID 《Physical chemistry chemical physics : PCCP》2012,14(25):9176-9184
Star-shaped molecules are of growing interest as organic optoelectronic materials. Here a detailed study of their photophysics using fluorescence depolarisation is reported. Fluorescence depolarisation dynamics are studied in branched oligofluorene-truxene molecules with a truxene core and well-defined three-fold symmetry, and are compared with linear fluorene oligomers. An initial anisotropy value of 0.4 is observed which shows a two-exponential decay with time constants of 500 fs and 3-8 ps in addition to a long-lived component. The femtosecond component is attributed to exciton localisation on one branch of the molecule and its amplitude reduces when the excitation is tuned to the low energy tail of the absorption spectrum. The picosecond component shows a weak dependence on the excitation wavelength and is similar to the calculated rate of the resonant energy transfer of the localised exciton between the branches. These assignments are supported by density-functional theory calculations which show a disorder-induced splitting of the two degenerate excited states. Exciton localisation is much slower than previously reported in other branched molecules which suggests that efficient light-harvesting systems can be designed using oligofluorenes and truxenes as building blocks. 相似文献
108.
Recent experimental, numerical and theoretical advances in turbulent Rayleigh-Bénard convection are presented. Particular emphasis is given to the physics and structure of the thermal and velocity boundary layers which play a key role for the better understanding of the turbulent transport of heat and momentum in convection at high and very high Rayleigh numbers. We also discuss important extensions of Rayleigh-Bénard convection such as non-Oberbeck-Boussinesq effects and convection with phase changes. 相似文献
109.
110.
K. Jessen M. Bergström P. von Brentano A. Dewald B. Herskind H. Meise C. Schumacher G. Sletten O. Stuck D. Weißhaar I. Wiedenhöver J. Wrzesinski 《The European Physical Journal A - Hadrons and Nuclei》1998,2(2):113-114
An in-beam experiment with the reaction 122Sn(27Al,4np) at 127 MeV was performed at the Nordball multi-detector array in Roskilde. It provided evidence for a new high-spin
isomer in 144Sm. This isomer with T
1/2= (2.6 ± 0.5) ns at an excitation energy E
x= 9232 keV seems to belong to a family of isomers of similar configuration in neighbouring N= 82 nuclei.
Received: 16 November 1997 相似文献