Chemie der Pleuromutiline, 10. Mitt.: 1,2-Transposition der Carbonylfunktion im Cyclopentanonteil des tricyclischen Gerüstes

2-Hydroxy-19,20-dihydropleuromutilin (10) undergoes a stereospecific ketolisomerisation when treated with base under phase/transfer conditions (11, 12). The subsequent reductive elimination of the 3-acetoxygroup afforded mutilin with a 1,2-transposed ketofunction (13).

     

A High-Order Finite Difference Scheme for 3D Unsteady Convection Diffusion Reaction Equations北大核心CSCD

针对三维非稳态对流扩散反应方程,构造了一种高精度紧致有限差分格式,对空间的离散采用四阶紧致差分方法,对时间的离散采用Taylor级数展开和余项修正技术,所提格式在时间上的精度为二阶、在空间上的精度为四阶。利用Fourier稳定性分析法证明了该格式是无条件稳定的。最后给出数值算例验证了理论结果。     

区块链技术影响下的供应链系统动态响应性研究

为解决供应链系统中信息时滞和不对称问题,加快推动区块链技术在供应链管理中的创新发展,本文运用控制理论构建由分销商和零售商组成的二级供应链系统控制模型,引入区块链技术影响下的信息校正因子,推导系统的传递函数,通过MATLAB仿真不同需求信号下的订单可变性和库存波动。仿真结果表明:(1)区块链技术的应用提高了库存系统的精准性和稳定性;(2)高库存可变性伴随着高订单可变性;(3)指数平滑系数和区块链技术影响下的信息校正因子有效抑制供应链中的牛鞭效应;(4)信息延迟时间越长,区块链技术影响下的信息校正因子对控制系统的抑制作用越显著。本研究量化了区块链技术对供应链中牛鞭效应的影响,提高了供应链系统的精准性和稳定性,丰富了区块链技术在供应链管理中的应用,为企业管理者提供新的研究思路。     

Micro raman spectroscopy on a single carbon fibre under stress

An example is given for the application of Raman spectroscopy in material characterization. Raman spectra of carbonaceous materials obtained with the microscope attachment have been used to study orientation of graphite planes in a single carbon fibre under stress with a lateral resolution of 1 m.Dedicated to Professor Dr. H. Kriegsmann on the occasion of his 70th birthday     

A new inorganic-organic polymer for the passivation of thin film capacitors

Inorganic-organic polymers with barrier properties against water vapor, excellent electrical data (3, 2, R _D>10¹⁶ cm, E _D up to 400 V/µm) and good adhesion to various substrate materials have been developed. Tailored modifications of these materials provide an excellent protective coating for thin film capacitors. Several mm thick, expensive, encapsulations could be replaced by thin coatings (up to 10 µm). The polymer coating allows the use of thin film chip capacitors in surface-mount technology. As a measure for the efficiency of the coating, the capacitance decrease under controlled humidity has been used. The influence of the material composition, the type of catalyst during sol-gel processing and the curing conditions have been studied. Adhesion and water vapor permeation properties of the polymers and rheological properties of the coating solutions have been investigated. A protective coating is developed, which increases the withstandness of capacitors against humid conditions (90°C, 100% rel. humidity) by a factor of about 30 (compared to uncoated capacitors) and shows no crack formation during thermal cycling.