Micro raman spectroscopy on a single carbon fibre under stress

An example is given for the application of Raman spectroscopy in material characterization. Raman spectra of carbonaceous materials obtained with the microscope attachment have been used to study orientation of graphite planes in a single carbon fibre under stress with a lateral resolution of 1 m.Dedicated to Professor Dr. H. Kriegsmann on the occasion of his 70th birthday     

A new inorganic-organic polymer for the passivation of thin film capacitors

Inorganic-organic polymers with barrier properties against water vapor, excellent electrical data (3, 2, R _D>10¹⁶ cm, E _D up to 400 V/µm) and good adhesion to various substrate materials have been developed. Tailored modifications of these materials provide an excellent protective coating for thin film capacitors. Several mm thick, expensive, encapsulations could be replaced by thin coatings (up to 10 µm). The polymer coating allows the use of thin film chip capacitors in surface-mount technology. As a measure for the efficiency of the coating, the capacitance decrease under controlled humidity has been used. The influence of the material composition, the type of catalyst during sol-gel processing and the curing conditions have been studied. Adhesion and water vapor permeation properties of the polymers and rheological properties of the coating solutions have been investigated. A protective coating is developed, which increases the withstandness of capacitors against humid conditions (90°C, 100% rel. humidity) by a factor of about 30 (compared to uncoated capacitors) and shows no crack formation during thermal cycling.     

Electron impact dissociation of H2O: emission cross sections for OH*, OH+*, H*, and H2O+* fragments

The optical emission spectrum in the near ultraviolet and visible following electron impact on H₂O was studied in a crossed-beam and a static gas-target experiment. Emissions of H*, OH*, OH⁺*, and H₂O⁺* fragments were detected and absolute emission cross sections for the different fragments were determined. A nonthermal rotational population was observed for the diatomic fragments which gives insight into the dissociation process. Further conclusions on the dissociation mechanism are possible based on appearance potentials and the shape of the emission cross sections as a function of impact energy.     

[(C6H5)3P]2Ni(Me3Si?CC?SiMe3). Darstellung,Eigenschaften und Struktur des ersten stabilen Nickel(0)-Komplexes von Bis-trimethylsilylacetylen

[(C₆H₅)₃P]₂Ni(Me₃Si? C?C? SiMe₃). Preparation, Properties, and Structure of the First Stable Nickel(0) Complex with Bis(trimethylsilyl)acetylene The title compound is the first example of a nickel(0) complex with bis(trimethylsilyl)acetylene and obtained from (ph₃P)₂Ni(C₂H₄) and bis(trimethylsilyl)acetylene in tetrahydrofuran. The complex is characterized by some reactions, the i.r. spectrum and by a structural analysis with the aid of X-ray diffraction data. (ph₃P)₂Ni(Me₃Si? C?C? SiMe₃) crystallizes monoclinic in the space group C2/c with four formula units per unit cell (2468 observed, independent reflexions, R = 0.038). The cell dimensions are a = 20.927, b = 13.812, c = 14.238 Å, α = γ = 90°, β = 91.02°. The molecules are monomer in crystalls. The molecule is planar with ligands arranged trigonally about the central atome but distorted to the tetrahedral complex.