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81.
M. Číp L. Schreiberová I. Schreiber 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2011,85(13):2322-2326
Glucose-catalase-glucose oxidase-hydrogen peroxide reaction is one of the few known enzymatic systems studied in vitro in
the field of nonlinear chemical dynamics. This reaction belongs to the family of oscillatory enzymatic reactions, which form
a natural basis of oscillations in biological systems. A parametric study of dependence on mixing, temperature and initial
concentrations of components in a batch stirred reactor was carried out. A newly proposed mathematical model of the reaction
conforms to the obtained experimental data. Results of our experiments and simulations hint at further directions of research
of non-linear dynamics in this reaction. 相似文献
82.
Kuai L Ong SE Madison JM Wang X Duvall JR Lewis TA Luce CJ Conner SD Pearlman DA Wood JL Schreiber SL Carr SA Scolnick EM Haggarty SJ 《Chemistry & biology》2011,18(7):891-906
Target identification remains challenging for the field of chemical biology. We describe an integrative chemical genomic and proteomic approach combining the use of differentially active analogs of small molecule probes with stable isotope labeling by amino acids in cell culture-mediated affinity enrichment, followed by subsequent testing of candidate targets using RNA interference-mediated gene silencing. We applied this approach to characterizing the natural product K252a and its ability to potentiate neuregulin-1 (Nrg1)/ErbB4 (v-erb-a erythroblastic leukemia viral oncogene homolog 4)-dependent neurotrophic factor signaling and neuritogenesis. We show that AAK1 (adaptor-associated kinase 1) is a relevant target of K252a, and that the loss of?AAK1?alters ErbB4 trafficking and expression levels,?providing evidence for a previously unrecognized role for AAK1 in Nrg1-mediated neurotrophic?factor signaling. Similar strategies should lead to the discovery of novel targets for therapeutic development. 相似文献
83.
Hinderhofer A Frank C Hosokai T Resta A Gerlach A Schreiber F 《The Journal of chemical physics》2011,134(10):104702
The structural properties of coevaporated thin films of pentacene (PEN) and perfluoropentacene (PFP) on SiO(2) were studied using x-ray reflectivity and grazing incidence x-ray diffraction. Reciprocal space maps of the coevaporated thin films with different volume fractions reveal the coexistence of two different molecular mixed PEN-PFP phases together with the pure PEN and PFP crystallites. The crystal structure of PEN:PFP blends does not change continuously with volume fraction, instead the proportion of the appropriate phases changes, as seen from the diffraction analysis. Additional temperature dependent experiments reveal that the fraction of the two mixed PEN-PFP phases varies with growth temperature. The λ-phase (molecular plane parallel to the substrate) is metastable and induced by low growth temperature. The σ-phase (molecular plane nearly perpendicular to the substrate) is thermally stable and nucleates predominantly at high growth temperatures. 相似文献
84.
Scholz R Gisslén L Schuster BE Casu MB Chassé T Heinemeyer U Schreiber F 《The Journal of chemical physics》2011,134(1):014504
Resonant and preresonant Raman spectra obtained on diindenoperylene (DIP) thin films are interpreted with calculations of the deformation of a relaxed excited molecule with density functional theory (DFT). The comparison of excited state geometries based on time-dependent DFT or on a constrained DFT scheme with observed absorption spectra of dissolved DIP reveals that the deformation pattern deduced from constrained DFT is more reliable. Most observed Raman peaks can be assigned to calculated A(g)-symmetric breathing modes of DIP or their combinations. As the position of one of the laser lines used falls into a highly structured absorption band, we have carefully analyzed the Raman excitation profile arising from the frequency dependence of the dielectric tensor. This procedure gives Raman cross sections in good agreement with the observed relative intensities, both in the fully resonant and in the preresonant case. 相似文献
85.
86.
R. Schreiber 《Fresenius' Journal of Analytical Chemistry》1900,39(7):457
Ohne Zusammenfassung 相似文献
87.
M.A. Bouchene V. Blanchet C. Nicole N. Melikechi B. Girard H. Ruppe S. Rutz E. Schreiber L. Wöste 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》1998,2(2):131-141
The interaction of a sequence of two identical ultrashort laser pulses with an atomic system results in quantum interferences
as in Ramsey fringes experiments. These interferences allow achievement of temporal coherent control of the excitation probability.
We present the results of a temporal coherent control experiment on two different atomic systems: one-photon absorption in
K (4s-4p) and two-photon absorption in Cs (6s-7d). In K, the quantum interferences between the two excitation paths associated with the laser pulses are revealed through
rapid oscillations of the excitation probability as a function of the time delay between the two pulses. These oscillations
take place at the transition frequency (period T = 2.56 fs). The interferences are modulated by beats (at about 580 fs) resulting from the doublet structure of the excited
state (4p (2
P
1/2
, 2
P
3/2
)). Three complementary interpretations of this experiment are presented: in terms of beats of quantum interferences, of variation
in the spectrum intensity, and of wave packet interferences. Whenever the two laser pulses are temporally overlapped, optical
interferences are superimposed on to the quantum interferences. The distinction between these two types of interference is
clearly revealed in the two-photon excitation scheme performed on Cs (6s-7d (2
D
3/2
, 2
D
5/2
)) because quantum interferences occur at twice the frequency of the optical interferences.
Received: 30 December 1997 / Revised: 28 February 1998 / Accepted: 4 March 1998 相似文献
88.
89.
Peter Schreiber 《Mathematical Logic Quarterly》1993,39(1):131-132
The uniqueness of the parallel lines is independent from the analogous statement on parallel planes and the usual further axioms of three-dimensional affine geometry. MSC: 51A15, 03F65. 相似文献
90.