OXIDATIVE COUPLING OF METHANE OVER Mn_2O_3-Na_2WO_4/SiO_2 CATALYST Ⅰ.CHARACTERIZATION OF ACTIVE SITES ON THE CATALYST

EPR and Raman spectroscopy have been used to characterize the catalyst. F-centers with EPR parameter of g=2. 0046 form when gas phase oxygen is admitted onto the catalyst reduced with methane at 800℃- Molecular oxygen plays an induced role in the electron transfer from W4 to the oxygen ion vacancy which is produced by methane reduction. Raman spectra give the further evidence for the production of lattice oxygen from molecular oxygen.     

漂移管中相对论电子束引导的匹配条件

本文介绍了对连续型相对论电子束的两种引导及箍缩方法:磁场引导和离子通道的静电引导。在线性引导力的假定下,求得了单磁场引导、单静电引导以及同时使用磁场和电场的混合引导的这三种情况下的匹配条件的解析结果。解析公式表明。在混合引导情况下,为了使电子束匹配,当电子束的中和因子线性增加时,相应的引导磁场不是线性地减小。而是抛物线形地减小。本文还使用了模拟束片内电子横向运动的LGERKB编码,通过对N_0个束内电子的模拟计算,求得了电子束包络。电子束的均方根发射度、典型电子轨道、失配和匹配情况下的束内电子相空间分布(相图)及其演变过程等大量资料。线性模拟结果与解析分析结果完全一致。     

电子束装置运行稳定性的测量

 为了验证电子束装置的稳定性,分别对电流波形、电压波形进行了多次测量,对二极管放电时注入腔中电子均匀性进行了探测,最后改变二极管真空度测量了泵浦氩的荧光 谱的稳定性。     

EFFECTS OF K_2O AND MnO PROMOTERS ON THE PRODUCTION OF LIGHT ALKENES VIA SYNGAS OVER Fe/SILICALITE-2 CATALYST I.ACTIVITY OF K-Fe-MnO/SILICALIT-2 CATALYST

The activity and the selectivity to light alkenes of silicalite-2 (Si-2) zeolite supported F'e catalyst tor CO hydrogenation can he improved obviously with the addition of K2O and MnO promoters. The results of CO hydrogenation, CO-TPD, CO/H2-TPSR, C2H4/H2-TPSR and C2H4/H2 pulse reaction over K-Fe-MnO/Si-2 catalysts clearly show that the K2O additive into Fe-MnO/Si-2 catalyst leads to a remarkable increase in both the capacity and strength of the strong CO ad-species that will produce much more |Cad| via their disproportionation at higher temperatures. This results in an increase in the CO conversion and the selectivity to light olefins, and a decrease in CH4 formation. Moreover, K2O can suppress the disproportionate of C2H4 that occurs during the reaction as a side-reaction Meanwhile, the MnO promoter mainly prohibits the hydrogenation of C2H4 and C3H6, which is favorable to enhancing the selectivity to C2H4 and C3H6 and decreasing the formation of C2H6, and C3H8. It is also of interest that MnO has har     

杂氮硅三环成环反应的研究

本文报导了与硅原子直接相连的有机基团(R)对杂氮硅三环成环速率的影响。利用气相色谱检测成环反应的产物之一——乙醇的生成速率和数量,并同与硅相连的R基团对成环反应速率的影响作比较。实验结果表明五种杂氮硅三环成环速度顺序为Cl_2CH—>ClCH_2—>ClCH_2CH_2CH_2—>CH_2=CH—>CH_3—,这与理论推断相符。     

Hybrid-Trefftz有限元法的研究进展

系统概述了Ｈｙｂｒｉｄ Ｔｒｅｆｆｔｚ有限元法及其在弹性力学中的应用．该单元模型由于在插值函数上的灵活选择性使其比普通有限元能更有效地处理局部效应问题,如孔洞,集中荷载等．通过适当选择单元插值函数可构造出高精度的ｐ－扩展元和一系列满足特殊条件的新单元,以在同等条件下提高计算精度      

弹性大变形问题中的应力状态描述、奇异性问题和余能原理

对弹性大变形理论中的3方面问题进行了综述.首先,对各种应变度量的共轭应力进行综述.大变形问题引起的应力状态描述的复杂性引起了许多学者的兴趣,对这个问题的研究也促进了大变形弹性理论的发展.在各种特定问题中,人们提出了不同的应力张量来描述应力状态,如Caucby应力张量、第一类和第一二类Piola-Kirchhoff应力张...     

Two Chiral Building Blocks for the Stereocontrolled Synthesis of Anti-and Syn-1,3-Diols

During the last decade, chiral building blocks for 1, 3-diols of various configurations have been synthesized and applied widely in the total synthesis of natural polyene macrolide antibiotics1 and 1(, 25-dihydroxyvitamin D3 analogues2,3. The synthesis of the building block has attracted much interest in recent years. Herein, we report the synthesis of two chiral building blocks 1 and 2 in 8 steps and 7 steps respectively, starting from the readily available and inexpensive D (+)-xylose 3 as o…     

Response from the Analytical Methods Committee (AMC) to the paper “Uncertainty in repeated measurement of a small non-negative quantity: explanation and discussion of Bayesian methodology”

Willink’s paper, “Uncertainty in repeated measurement of a small non-negative quantity: explanation and discussion of Bayesian methodology” provides a clear exposition of the Bayesian paradigm but unfortunately reads like a rebuttal of a previous paper from the AMC: the reader is left with the impression that the AMC is recommending a procedure that performs poorly. The AMC here refutes any such impression by presenting a balanced assessment of the strengths and weaknesses of the Bayesian and frequentist approaches to formulating the uncertainty of small non-negative quantities.     

采用新型La_(0.07)Sr_(0.93)SnO_3电极制备外延透明BiFe_(0.95)Mn_(0.05)O_3铁电薄膜电容器

本文使用脉冲激光沉积的方法在SrTiO3(STO)单晶衬底上采用一种新型的透明导电氧化物材料La0.07Sr0.93SnO3(LSSO)薄膜作为电极材料制备了BiFe0.95Mn0.05O3(BFMO)铁电薄膜电容器.XRD表征结果证实BF-MO/LSSO/STO外延异质结具有很好的单晶质量.光透过率的测试结果表明在500~2500nm的波长范围内,整个异质结的透光率与单纯STO衬底基片相似.在波长500nm附近BFMO出现吸收边,通过对吸收边进行(hνα)2-hν曲线拟合得到BFMO的直接光学带隙约为2.8eV.利用Pt作为上电极,我们测得了饱和的电滞回线,剩余极化Pr~60μC/cm2.