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31.
A review of atomistic simulation approaches including explicit water for the study of hydration forces between polar surfaces is presented. In particular, we discuss different methods for keeping the chemical potential of water constant and compare advantages and limitations of each method. It turns out that modifications of hydration forces due to surface softness can be accounted for by a convolution over the surface shape profile. Universal aspects of the hydration interaction observed in simulations of different surface chemistries are highlighted, while special attention is given to hydration forces between self-assembled phospholipid membranes. 相似文献
32.
K. El boussiri M. Clin J. Henocque J. Schneck J.C. Toledano D. Morin T. Rais 《Applied Physics A: Materials Science & Processing》1997,65(2):199-201
Received: 16 December 1996/Accepted: 2 April 1997 相似文献
33.
本文报导了采用氩离子激光器来泵浦Pr3+:YLF晶体,应用声光调制器实现了主动锁模;同时应用振动─高反射平面镜也实现了被动锁模,两种锁模均得到了ps光脉冲.据作者了解这是这种晶体材料的第一次锁模运转. 相似文献
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THE AVAILABILITY OF SOLAR RADIATION BELOW 290 nm AND ITS IMPORTANCE IN PHOTOMODIFICATION OF POLYMERS
R. E. BARKER JR. 《Photochemistry and photobiology》1968,7(3):275-295
Abstract— On a percentage basis, ozone is a very minor component of the atmosphere; at STP it would make a layer only about 2 mm thick. On almost every other basis (biological, meteorological, paleontological, photochemical, etc.) it is a major component, due mainly to the tremendous reduction in solar ultraviolet flux which it causes in the 220–290 nm region. Since no data are available for Λ < 285 nm, a rational basis for estimating the flux reaching the earth's surface in this region is discussed. Variations in ozone concentration are of great importance, and it is possible to have more radiation with Λ < 270 nm fall on a surface in one extreme day than in several years of typical days. Often, persons involved in studies of polymer degradation by sunlight mention that a negligible fraction (1 ppm) of the radiant flux reaching the earth's surface is associated with wavelengths below 290 nm and infer that studies at shorter wavelengths will not be of much practical value. Such inferences are questionable for at least two reasons. (1) The quantum flux density below 290 nm is about 1016 photons cm-2 month-1 , so that considerable long-term damage is possible since most of the flux will be absorbed in a layer only a few microns thick. (2) Even if solar radiation below 290 nm were completely absent, the existence of correlations between absorption peaks in the near ultraviolet and visible, and in the infrared with ionization potentials typically 6–12 eV or 200-100 nm) is evidence that we may expect studies in the ultraviolet and extreme ultraviolet (EUV) to provide important clues to the problem of improving the resistance of polymers to sunlight. 相似文献
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EFFECT OF ULTRAVIOLET RADIATION ON THE ENERGY METABOLISM OF THE CORNEAL EPITHELIUM OF THE RABBIT 总被引:2,自引:0,他引:2
The present research was directed at quantifying possible alterations in corneal epithelial metabolic activity secondary to in vivo exposure to ultraviolet radiation (UVR). Microfluorometric energy metabolite assays on microgram (microgram) sized, freeze-dried tissue samples were used as an in vitro means of assessing overall metabolic activity in the epithelium of control rabbit corneas and in the epithelium of UVR-exposed rabbit corneas 2 min after discontinuation of exposure. The specific assays were for glucose, glycogen, adenosine triphosphate (ATP), and phosphocreatine (PCr). The radiant exposures were kept constant at 0.05 J cm-2 for all UVR wavelengths utilized (290, 300, 310 and 360 nm). Experimental UVR exposure conditions served to increase epithelial glucose and glycogen concentrations. Although the epithelial ATP concentrations were unchanged, the epithelial PCr concentrations (a high energy phosphate bond reservoir) decreased as a result of UVR exposure. Overall, the data demonstrate a decrease in corneal epithelial metabolic activity, which may be wavelength-dependent, as a result of UVR exposure. It is suggested that immediate metabolic stress can be responsible for the pattern of epithelial cell loss seen in photokeratitis. 相似文献
40.
Abstract— Total diffuse reflectance spectra of air-dried surfaces of free and neutralized amino acid preparations before and after irradiation in vitro are reported. It was found that some free or neutralized amino acid surfaces underwent modification which resulted in changes in the diffuse reflectance spectra after U.V. exposure. It is suggested that these reflectance changes result from transformations in the side chains of the amino acids and that the transformations may differ from those occurring when amino acids in solution are irradiated. Histidine, cystine, hydroxyproline and some protein surfaces showed changes in reflectance of 330–400 nm light similar to those reported in skin after U.V. irradiation in viuo. 相似文献