Determination of arsenic species in water, soils and plants

Ion chromatographic separation coupled with ICP-MS was used to determine arsenic species in plant and soil extracts. A scheme for growth, harvesting, sample pre-treatment and analysis was developed for the arsenic species to enable determination. Preliminary results obtained with ten herb plants grown on arsenic-contaminated soil compared to non-contaminated soil show a heterogeneous pattern of accumulation rate, metabolization and detoxification mechanisms in monocots and dicots. Arsenite appears to be the major component in plants with good growth. Organic arsenic species were even detected at very low concentrations (< 150 microg kg(-1) (dry mass)).     

Synthesis of C-Disaccharides An Unusual Ring Closure Reaction

Abstract

Reaction of the 4-C-lithiomethyl intermediates, obtained from 4-deoxy-4-C-iodomethylglucopyranosides 5a,b, with open-chain glucose derivative 8 afforded 4-deoxy-4-C-heptitylglucopyranosides 9a,b. Mesylation of the newly generated hydroxy group and then desilylation gave 11a,b which were subjected to ring closure under basic conditions. Surprisingly, no C-bridged cellobiosides 12a,b (or, alternatively the corresponding maltosides) were obtained as major products; with loss of one benzyl alcohol residue the furanosides 13a,b were preferentially formed. Their generation and structural assignment is discussed.     

Critical distance for fusion and fusion barriers of very-heavy-ion collisions

For the fusion barriers of very-heavy-ion collisions we derive a simple analytical formulae which is based on the concept of the critical distance for fusion. The analytical expression reproduces the experimental fusion barriers within a large range of target-projectile combinations.     

Distribution of Ir and Pt isotopes produced as fragments of 1 A GeV Au projectiles: a thermometer for peripheral nuclear collisions

Cross sections of iridium and platinum isotopes have been measured, which were produced as fragments from ¹⁹⁷Au projectiles interacting with aluminum target nuclei at 1 A GeV. The fragments were identified by a kinematic analysis (ΔE−Bρ-time-of-flight) and by an ion-optical separation at the projectile-fragment separator FRS at GSI. Indications are found for high excitation energies and weak proton-neutron correlations in the peripheral nuclear-collision process.     

Material parameter computation for multi-layered vocal fold models

Today, the prevention and treatment of voice disorders is an ever-increasing health concern. Since many occupations rely on verbal communication, vocal health is necessary just to maintain one's livelihood. Commonly applied models to study vocal fold vibrations and air flow distributions are self sustained physical models of the larynx composed of artificial silicone vocal folds. Choosing appropriate mechanical parameters for these vocal fold models while considering simplifications due to manufacturing restrictions is difficult but crucial for achieving realistic behavior. In the present work, a combination of experimental and numerical approaches to compute material parameters for synthetic vocal fold models is presented. The material parameters are derived from deformation behaviors of excised human larynges. The resulting deformations are used as reference displacements for a tracking functional to be optimized. Material optimization was applied to three-dimensional vocal fold models based on isotropic and transverse-isotropic material laws, considering both a layered model with homogeneous material properties on each layer and an inhomogeneous model. The best results exhibited a transversal-isotropic inhomogeneous (i.e., not producible) model. For the homogeneous model (three layers), the transversal-isotropic material parameters were also computed for each layer yielding deformations similar to the measured human vocal fold deformations.     

Bi-directional terahertz emission from gold-coated nanogratings by excitation via femtosecond laser pulses

We report on the investigation of terahertz (THz) emission from gold-coated nanogratings (500 nm grating constant) upon femtosecond laser irradiation (785?nm, 150?fs, 1?kHz, ??1?mJ/pulse). Unlike common assumptions, THz emission is not only observed in case of rear side irradiation (through substrate (Welsh et al. in Phys. Rev. Lett. 98:026803, 2007; Welsh and Wynne in Opt. Express 17:2470?C2480, 2009)) of the nanograting, but also in case of front side excitation (through air). Furthermore in both cases, THz emission propagates in the direction of laser beam propagation and reverse. Based on these findings, we suggest a new approach to describe the newly observed phenomena. Using a highly sensitive and fast superconducting transition edge sensor (TES) as calorimeter, it was possible to directly measure the absolute energy of the emitted THz pulses in a defined spectral and spatial range, enabling for the first time a quantitative analysis of the THz emission process.     

Spin-dependent electron dynamics in front of a ferromagnetic surface

Exchange splitting and dynamics of image-potential states in front of a 3 monolayer iron film on Cu(100) have been studied with time-, energy-, and spin-resolved bichromatic two-photon photoemission. For the first image-potential state n=1 we observe an exchange splitting of 56 +/- 10 meV and spin-dependent lifetimes of 16 +/- 2 fs for majority-spin and of 11 +/- 2 fs for minority-spin electrons, respectively. The time-resolved studies of both the population and the linewidth of image-potential states manifest that at the magnetic surface not only inelastic but also quasielastic scattering processes are spin dependent.