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221.
Tobias Gruber Max Peukert Diana Schindler Wilhelm Seichter Edwin Weber Petra Bombicz 《Journal of inclusion phenomena and macrocyclic chemistry》2008,62(3-4):311-324
Three lower rim n-propyl substituted calix[4]arenes (1–3) with varied number and position of the modifying groups have been prepared. Inclusion compounds (five species) involving different kinds of guest solvents have been isolated. Their X-ray crystal structures were determined and comparatively discussed using isostructurality calculations. Two of the inclusion compounds obtained (1a and 1b) are polymorphs containing the same host and guest molecules in equal stoichiometric ratio but different Z′ values caused by a phase transition around 140 K. The inclusion compounds 2a and 2b refer to the interesting case of a mixed solvent complex while 3a allows studying the effect of full lower rim n-propyl substitution. 相似文献
222.
Kinetic Studies on the Hydrogenation of Carbon Dioxide to Formic Acid using a Rhodium Complex as Catalyst A detailed kinetic analysis has been performed on the hydrogenation of carbon dioxide with the complex [(dppp)2RhH] (dppp = 1,3‐bis(diphenyl‐phosphino)propane in DMSO using stopped‐flow techniques. Activation parameters including the activation volume for this reaction as well as for the related reaction of the formation of the dihydrogen complex [(dppp)2RhH2]HCO2 were obtained and thus allowed the formulation of a mechanism for this reaction cycle. 相似文献
223.
224.
225.
L. Benvegnin A. Jermstad O. Östby E. Monti de Astis F. Holzbach G. Amadio L. Paronetta A. A. Perazzo A. C. Arbrecchi R. Marcille P. Jaulmes L. Ferré P. Archinard L. Espil E. Capt C. Sumuleanu G. Ghimicescu M. V. Ionescu F. Konek E. Wettstein C. Béis E. Peynaud J. Schindler K. Kozák P. Berg G. Schulze A. Heiduschka H. Sommer H. Mohler Internationales Landwirtschaftsinstitut 《Analytical and bioanalytical chemistry》1938,115(3-4):148-158
226.
H. W. Gonell H. Wagner J. C. Sprague W. Becker A. Foschini S. Karpatschew S. Rempel A. Ssessjunin W. Hornke A. Steopoe E. I. Nagerowa N. I. Kolendsjan H. R. Brandenburg W. Anselm K. Schindler K. I. Staub A. Panowa W. H. Glanville S. M. Rojak E. N. Nagerowa 《Analytical and bioanalytical chemistry》1938,115(9-10):375-378
227.
Stefan Schaub Andreas Miska Dr. Jonathan Becker Dr. Stefan Zahn Prof. Dr. Doreen Mollenhauer Dr. Sadashivaiah Sakshath Prof. Dr. Volker Schünemann Prof. Dr. Siegfried Schindler 《Angewandte Chemie (International ed. in English)》2018,57(19):5355-5358
The iron(IV) oxido complex [(tmc)Fe=O(OTf)]OTf with the macrocyclic ligand 1,4,8,11‐tetramethyl‐1,4,8,11‐tetraazacyclo‐tetradecane (tmc) has been synthesized using ozone as an oxidant. By adding water to this compound the complex [(H2O)(tmc)Fe=O)](OTf)2 could be prepared. This complex is important in regard to a better understanding of the reactivity of FeIV oxido complexes. Mössbauer measurements using the solid compound showed an isomer shift of δ=0.19 mm s?1 and a quadrupole splitting ΔEQ=1.38 mm s?1, confirming the high‐valent FeIV state. DFT calculations were performed and led to an assignment of triplet spin multiplicity. Crystallographic characterization of [(H2O)(tmc)Fe=O)](OTf)2 as well as of starting materials [(tmc)Fe(CH3CN)](OTf)2 and [(tmc)Fe(OTf)]OTf together with previous results strongly suggest that [(H2O)(tmc)Fe=O)](OTf)2 was formed similar to the oxido–hydroxido tautomerism analogous to heme systems. 相似文献
228.
Christopher C. McAtee Duncan C. Ellinwood Rory C. McAtee Corinna S. Schindler 《Tetrahedron》2018,74(26):3306-3313
We report herein the intramolecular α-tert-alkylation of unsaturated β-ketoesters which gives rise to highly functionalized cyclopentanes. This transformation is characterized by its operational simplicity, mild reaction conditions and the use of scandium (III) triflate as a Lewis acid catalyst. Of interest, cyclopentanes bearing heterocycles, sites for post reaction functionalization and spirocyclic architectures are accessible with this strategy. 相似文献
229.
Video-enhanced optical fluorescence microscopy has been used to determine the direction of the transition dipole moment of individual molecules. Fast electro-optical switching of the polarization of the excitation allowed us to detect the linear dichroism of single fluorophores in solid phospholipid membranes. Quantitative analysis of the fluorescence signal showed that rotational mobility is absent in solid biomembranes. 相似文献
230.
Christian Schindler 《Foundations of Physics》1990,20(5):561-573
We show that a finite orthomodular poset with a strong section of states (probability measures) is distributive if and only if has the unique Jordan-Hahn decomposition property(UJHDP). That this result does not extend to infinite orthomodular posets is shown by the projection lattices of von Neumann algebras without direct summand of typeI
2, for which the set of completely additive states is strong and has theUJHDP. There also exist nondistributive -classes for which the set of countably additive states has theUJHDP.Research supported by Schweizerischer Nationalfonds/Fonds National Suisse under grant number 2.445-0.87. 相似文献