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121.
We consider subordinators in the domain of attraction at 0 of a stable subordinator (where ); thus, with the property that , the tail function of the canonical measure of , is regularly varying of index as . We also analyse the boundary case, , when is slowly varying at 0. When , we show that converges in distribution, as , to the random variable . This latter random variable, as a function of , converges in distribution as to the inverse of an exponential random variable. We prove these convergences, also generalised to functional versions (convergence in ), and to trimmed versions, whereby a fixed number of its largest jumps up to a specified time are subtracted from the process. The case produces convergence to an extremal process constructed from ordered jumps of a Cauchy subordinator. Our results generalise random walk and stable process results of Darling, Cressie, Kasahara, Kotani and Watanabe. 相似文献
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Andrea Schindler Gábor Balázs Manfred Zabel Christian Gröger Robert Kalbitzer Manfred Scheer 《Comptes Rendus Chimie》2010,13(8-9):1241-1248
The reaction of the 1,2,4-triphosphaferrocene [Cp*Fe(η5-P3C2tBu2)] (1) with CuX (X = Cl, Br, I) in a 1:1 stoichiometric ratio leads to the formation of the oligomeric compounds [{Cu(μ-X)}6(μ6-X)Cu(MeCN)3{μ,η2-(Cp*Fe(η5-P3C2tBu2))}2{μ3,η3-(Cp*Fe(η5-P3C2tBu2))}] (X = Cl (2), Br (3)) and [{Cu(μ-I)}3{Cu(μ3-I)}3Cu(μ6-I){μ,η2-(Cp*Fe(η5-P3C2tBu2))}3{η1-(Cp*Fe(η5-P3C2tBu2))}] (4) revealing Cu(I) halide cages surrounded by 1,2,4-triphosphaferrocene moieties. The reaction of [Cp*Fe(η5-P3C2tBu2)] with CuI in a 1:4 stoichiometry leads to the formation of the two-dimensional polymer [{Cu(μ-I)}4{Cu(μ3-I)(MeCN)}2{μ3,η3-(Cp*Fe(P3C2tBu2))}]n (5). The oligomeric compounds show dynamic behavior in solution monitored by 31P NMR spectroscopy. All compounds are additionally characterized by single crystal X-ray diffraction. 相似文献
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The solubility and the complex equilibria in the system Mn2+-CO2-H2O have been investigated at 25°C in solutions of the constant ionic strength 3 M (Na)ClO4. From experimental data the following values for equilibrium constants and Gibbs free energies of formation are deduced: A predominance area diagram for the system Mn2+-H2-CO2(g)-H2S(g) including MnCO3(ppt.), α-MnS and Mn2+ is given. 相似文献
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Michael Schindler Frank C. Hawthorne Rory A. Kutluoglu Petre Mandaliev Roger H. Mitchell 《Journal of solid state chemistry》2006,179(8):2616-2628
The potential insertion-electrode compounds Na1.2[V3O8] (NaV) and Na0.7Li0.7[V3O8] (NaLiV) were synthesized from mixtures of Na2CO3, Li2CO3 and V2O5, which were melted at 750° and subsequently cooled to room temperature. The structures of NaV and LiV contain sheets of polymerized (VOn) polyhedra, which are topologically identical to the sheet of polymerized polyhedra in Li1.2[V3O8] (LiV). Vanadium occurs in three different coordination environments: [2+3] V(1), [2+2+2] V(2) and [1+4+1] V(3). Calculated bond-valence sums indicate that V4+ occurs preferentially at the V(3) site, which agrees with the general observation that [6]-coordinated V4+ prefers [1+4+1]-rather than [2+2+2]-coordination. The M-cations Na and Li occur at three distinct sites, M(1), M(2) and M(3) between the vanadate sheets. The M(1)-site is fully occupied and has octahedral coordination. The M(2) sites are partly occupied in NaV and NaLiV, in which they occur in [4]- and [6]-coordination, respectively. Li partly occupies the M(3) site in NaLiV, in which it occurs in [3]-coordination. The M(2) and M(3) sites in NaLiV occur closer to the vanadate sheets than the M(2) sites in NaV and LiV. The shift in these cation positions is a result of the larger distance between the vanadate sheets in NaLiV than in LiV, which forces interstitial Li to move toward one of the vanadate sheets to satisfy its coordination requirements. Bond-valence maps for the interstitial cations Na and Li are presented for NaV, NaLiV and LiV. These maps are used to determine other potential cation positions in the interlayer and to map the regions of the structure where the Na and Li have their bond-valence requirements satisfied. These regions are potential pathways for Na and Li diffusion in these structures, and are used to explain chemical diffusion properties of Na and Li in the Na-Li-[V3O8] compounds. 相似文献