全文获取类型
收费全文 | 455篇 |
免费 | 19篇 |
国内免费 | 1篇 |
专业分类
化学 | 269篇 |
晶体学 | 3篇 |
力学 | 6篇 |
数学 | 52篇 |
物理学 | 145篇 |
出版年
2019年 | 4篇 |
2018年 | 7篇 |
2017年 | 6篇 |
2016年 | 12篇 |
2015年 | 14篇 |
2014年 | 6篇 |
2013年 | 24篇 |
2012年 | 8篇 |
2011年 | 12篇 |
2010年 | 13篇 |
2009年 | 13篇 |
2008年 | 17篇 |
2007年 | 14篇 |
2006年 | 16篇 |
2005年 | 11篇 |
2004年 | 14篇 |
2003年 | 8篇 |
2001年 | 5篇 |
2000年 | 5篇 |
1999年 | 5篇 |
1998年 | 7篇 |
1997年 | 6篇 |
1996年 | 8篇 |
1995年 | 11篇 |
1994年 | 4篇 |
1993年 | 10篇 |
1992年 | 14篇 |
1991年 | 11篇 |
1990年 | 15篇 |
1989年 | 11篇 |
1988年 | 6篇 |
1987年 | 7篇 |
1986年 | 5篇 |
1985年 | 9篇 |
1981年 | 8篇 |
1980年 | 11篇 |
1979年 | 4篇 |
1978年 | 6篇 |
1977年 | 3篇 |
1976年 | 4篇 |
1975年 | 4篇 |
1972年 | 5篇 |
1971年 | 4篇 |
1970年 | 4篇 |
1969年 | 7篇 |
1968年 | 7篇 |
1967年 | 4篇 |
1966年 | 5篇 |
1960年 | 3篇 |
1938年 | 3篇 |
排序方式: 共有475条查询结果,搜索用时 15 毫秒
31.
32.
The dinuclear copper(I) complex [Cu(2)L(1)(CH(3)CN)(2)](ClO(4))(2) (1, L(1) = 3,6,9,17,20,23-hexaazatricyclo[23.3.1.1]triaconta-1(29),2,9,11(30),12(13),14,16,23,25,27-decaene) has been structurally characterized. As previously described, intramolecular ligand hydroxylation (at the aromatic ring) was observed when 1 was reacted with dioxygen. A stopped-flow analysis of the reaction of 1 with dioxygen under different conditions did not allow a "dioxygen intermediate" to be spectroscopically detected. Detailed NMR and electrochemical data on 1 are also presented and evaluated for the first time. No copper(II) complexes of L(1) could be characterized due to hydrolysis of the compounds. In contrast, complex 2-differing from 1 only in an increase in the size of the chelate rings-did not undergo intramolecular hydroxylation when it was oxidized. The crystal structure of 2 is also described. 相似文献
33.
Ralf Schindler 《Monatshefte für Mathematik》2003,139(4):335-340
We state different versions of the P=?NP problem for infinite time Turing machines. It is observed that PNP collapses to the fact that there are analytic sets which are not Borel.The author thanks J. D. Hamkins, R. Schipperus, and P. Welch for comments on earlier versions of this paper. He thanks Sanders Seliverstov for pointing out an inaccuracy in the first version of the proof of Theorem 2.10.Received April 19, 2002; in revised form June 10, 2002
Published online May 16, 2003 相似文献
34.
The topography evolution of simultaneously rotated and Ar (+) ion sputtered InP surfaces was studied using scanning force microscopy. For certain sputter conditions, the formation of a highly regular hexagonal pattern of close-packed mounds was observed with a characteristic spatial wavelength which increases with sputter time t according to lambda approximately t(gamma) with gamma approximately 0.26. Based on the analysis of the dynamic scaling behavior of the surface roughness, the evolution of the surface topography will be discussed within the limits of existing models for surface erosion by ion sputtering. 相似文献
35.
We consider a new approach to the nucleon-nucleon scattering problem in the framework of the higher-derivative formulation of baryon chiral perturbation theory. Starting with a Lorentz-invariant form of the effective Lagrangian we work out a new symmetry-preserving framework where the leading-order amplitude is calculated by solving renormalizable equations and corrections are taken into account perturbatively. Analogously to the KSW approach, the (leading) renormalization scale dependence to any finite order is absorbed in the redefinition of a finite number of parameters of the effective potential at given order. On the other hand, analogously to Weinberg’s power counting, the one-pion-exchange potential is of leading order and is treated non-perturbatively. 相似文献
36.
37.
W.R. Christian BeyerKatharina Woithe Bettina LükeMichael Schindler Horst AntonicekJürgen Scherkenbeck 《Tetrahedron》2011,67(17):3062-3070
The indole alkaloid α-cyclopiazonic acid (CPA) is one of the few known inhibitors of sarco(endo)plasmic reticulum Ca2+-ATPase (SERCA) besides the terpenoids thapsigargin and artemisinin. We report here the first asymmetric total synthesis of cyclopiazonic acid by a modification of the Knight synthesis, currently the most efficient route to CPA. First structure-activity data of CPA derivatives and stereoisomers are presented and will be discussed in connection with the published crystal structures of CPA-SERCA complexes. 相似文献
38.
39.
The resistance behavior of TaN/Ta diffusion barrier bilayers has been investigated. The dependence of the Ta-phase on the TaN layer thickness was examined by means of X-ray micro-diffraction and resistivity measurements. Furthermore, the influence of the geometry of a damascene trench structure on the Ta-phase of the deposited TaN/Ta barrier bilayers has been studied and compared to the results obtained with blanket wafers. The influence of the Ta-phase on the via resistance of Cu interconnects is discussed. 相似文献
40.