全文获取类型
收费全文 | 220645篇 |
免费 | 2980篇 |
国内免费 | 1319篇 |
专业分类
化学 | 122730篇 |
晶体学 | 3228篇 |
力学 | 8888篇 |
综合类 | 61篇 |
数学 | 24365篇 |
物理学 | 65672篇 |
出版年
2020年 | 1754篇 |
2019年 | 1896篇 |
2018年 | 2484篇 |
2017年 | 2531篇 |
2016年 | 3645篇 |
2015年 | 2424篇 |
2014年 | 3537篇 |
2013年 | 8873篇 |
2012年 | 7686篇 |
2011年 | 9396篇 |
2010年 | 6649篇 |
2009年 | 6451篇 |
2008年 | 8792篇 |
2007年 | 8900篇 |
2006年 | 8384篇 |
2005年 | 7705篇 |
2004年 | 6870篇 |
2003年 | 6053篇 |
2002年 | 5985篇 |
2001年 | 6703篇 |
2000年 | 5067篇 |
1999年 | 3669篇 |
1998年 | 3038篇 |
1997年 | 3008篇 |
1996年 | 3011篇 |
1995年 | 2618篇 |
1994年 | 2718篇 |
1993年 | 2581篇 |
1992年 | 2829篇 |
1991年 | 2894篇 |
1990年 | 2703篇 |
1989年 | 2616篇 |
1988年 | 2557篇 |
1987年 | 2497篇 |
1986年 | 2520篇 |
1985年 | 3300篇 |
1984年 | 3359篇 |
1983年 | 2804篇 |
1982年 | 3046篇 |
1981年 | 2811篇 |
1980年 | 2607篇 |
1979年 | 2790篇 |
1978年 | 2997篇 |
1977年 | 3032篇 |
1976年 | 3059篇 |
1975年 | 2793篇 |
1974年 | 2906篇 |
1973年 | 2956篇 |
1972年 | 2318篇 |
1971年 | 1845篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
51.
Thomas Marmin Prof. Yves L. Dory 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(27):6707-6711
Cyclohexane and cyclotri-β-alanyl have been used as scaffolds for the design of new C3-symmetric rings incorporating conjugated alkenes and dienes. All three C3-symmetric lactams share the same triangular shape and their crystal system is trigonal. They all belong to the R3 space group, R3m, R3 and R3c, for the increasingly large 12-, 18- and 24-membered rigid rings, respectively. All lactams stack on top of each other, through H-bonds and van der Waals noncovalent interactions, leading to endless supramolecular cylinders and tubes. The largest member of the family leads to tubes, the central pores of which is wide enough to let water in. A common feature of all the lactams is their very large dipole, of around 9 D, according to DFT calculations. Surprisingly, all the resulting cylinders and tubes pack side by side in the crystals, with all the dipoles pointing to the same direction. As a result, all three crystals are anisotropic and appear to be the first members of a new kind of highly polar crystals. 相似文献
52.
53.
J. Conrad J. Cohen-Tanugi L. E. Strigari 《Journal of Experimental and Theoretical Physics》2015,121(6):1104-1135
The launch of the gamma-ray telescope Fermi Large Area Telescope (Fermi-LAT) started a pivotal period in indirect detection of dark matter. By outperforming expectations, for the first time a robust and stringent test of the paradigm of weakly interacting massive particles (WIMPs) is within reach. In this paper, we discuss astrophysical targets for WIMP detection and the challenges they present, review the analysis tools which have been employed to tackle these challenges, and summarize the status of constraints on and the claimed detections in the WIMP parameter space. Methods and results will be discussed in comparison to Imaging Air Cherenkov Telescopes. We also provide an outlook on short term and longer term developments. 相似文献
54.
Kondakov N. N. Mel´nikova T. M. Chekryzhova T. V. Mel´nikova M. V. Zinin A. I. Torgov V. I. Chizhov A. O. Kononov L. O. 《Russian Chemical Bulletin》2015,64(5):1142-1148
Russian Chemical Bulletin - Terminal disaccharide fragment of phenolic glycolipid from Mycobacterium leprae (PGL-I) was synthesized as a glycoside with 4-(2-aminoethoxy)phenyl aglycon. The obtained... 相似文献
55.
Claudia Poloni Marc C. A. Stuart Pieter van der Meulen Wiktor Szymanski Ben L. Feringa 《Chemical science》2015,6(12):7311-7318
The external photocontrol over peptide folding, by the incorporation of molecular photoswitches into their structure, provides a powerful tool to study biological processes. However, it is limited so far to switches that exhibit only a rather limited geometrical change upon photoisomerization and that show thermal instability of the photoisomer. Here we describe the use of an overcrowded alkene photoswitch to control a model β-hairpin peptide. This photoresponsive unit undergoes a large conformational change and has two thermally stable isomers which has major influence on the secondary structure and the aggregation of the peptide, permitting the phototriggered formation of amyloid-like fibrils. 相似文献
56.
57.
58.
Natalia L. Calvo Sebastian O. SimonettiRubén M. Maggio Teodoro S. Kaufman 《Analytica chimica acta》2015
Exposure of cimetidine (CIM) to dry heat (160–180 °C) afforded, upon cooling, a glassy solid containing new and hitherto unknown products. The kinetics of this process was studied by a second order chemometrics-assisted multi-spectroscopic approach. Proton and carbon-13 nuclear magnetic resonance (NMR), as well as ultraviolet and infrared spectroscopic data were jointly used, whereas multivariate curve resolution with alternating least squares (MCR-ALS) was employed as the chemometrics method to extract process information. It was established that drug degradation follows a first order kinetics. 相似文献
59.
ABSTRACT A new density functional for the study of associating inhomogeneous fluids based on Wertheim's first-order thermodynamic perturbation theory is presented and compared to the most currently used associating density functionals. This functional is developed using the weighted density approximation in the range of association of hard spheres. We implement this functional within the framework of classical density functional theory together with modified fundamental measure theory to account for volume exclusion of hard spheres. This approach is tested against molecular simulations from literature of pure associating hard spheres and mixtures of non-associationg and associating hard spheres with different number of bonding sites close to a hard uniform wall. Furthermore, we compare and review our results with the performance of associating functionals from literature, one based on fundamental measure theory and the inhomogeneous version of Wertheim's perturbation theory. Results obtained with classical DFT and the three functionals show excellent agreement with molecular simulations in systems with one hard wall. For the cases of small pores where only one or two layers of fluid are allowed discrepancies between results with classical DFT and molecular simulations were found. 相似文献
60.