Rearragnement of 1-allyloxy-2-allylthio-4-methyl-benzene TO 2,4-dimethyl-6-allyl-7 hydroxy-2,3-dihydrobenzothiophene

1-Allyloxy-2-allylthio-4-methylbenzene rearranges in NN-diethylaniline at 215°C with migration of allyloxy and allylthio groups to form 2,4-dimethyl-6-allyl-7-hydroxy-2,3dihydrobenzothiophene.M. V. Lomonosov State University, Moscow 119899. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 480–482, 1994. Original article submitted March 5, 1994.     

Aziridinylketones and their cyclic anils. 12

We have measured the PMR spectra of 5, 7-diaryl-1, 4-diazabicyclo[4. ].O]hept-4-enes. We have studied the structure of the 5-(4-nitrophenyl)-7-phenyl derivative by x-ray diffraction. We show that the six-membered heterocycle has the half-chair form. The 6-H and 7-H protons of the aziridine ring are trans, while the 7-aryl is exo relative to the six-membered ring. Introduction of substituents into the aromatic ring has practically no effect on the geometry of the bicycle.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1117–1124, August, 1994.For Communication 11, see [1].     

Hydroxyl-containing mesogens. Synthesis and liquid-crystalline properties of 2-o-hydroxyarylpyrimidines

We have synthesized 5-alkyl(alkoxy)-2-(o-lzydroxy-p-alkoxyphenyl)pyrimidines and considered the effect of the OH group on the inesomorphism. We have found that in binuclear o-hydroxyarylpyrimidines, an ortho OH group forming an intramolecular hydrogen bond increases T_mp, inhibits the appearance of nematic properties, and promotes the appearance of a smectic A.Translated from Khimiya Geterotsiklicheskikh Soedinenii, Vol. 30, No. 1, pp. 90–92, January, 1994.     

Reversed phase behaviour of high molecular mass polystyrenes in ethyl acetate solvent mixtures

Chromatographia - The reversed phase behaviour of high molecular mass polystyrenes was investigated on C18 bonded phase columns with ethyl acetate-methanol and ethyl acetateacetonitrile mobile...     

Separation of 23 dansylated amino acids by micellar electrokinetic chromatography at low temperature

Summary The baseline separation of 23 dansylated amino acids (including 3 didansylated species) is reported. Lowering of the analysis temperature and fine control of the surfactant concentration were essential in obtaining this result. Calibration graphs with good linearity were obtained.     

Mechanical properties of polyester polymer-concrete

The properties of a polymer-concrete composed of polyester matrix and locally available rock aggregate are investigated. The formula of the concrete is found by an experimental-calculation approach in such a way as to attain a closer packing of the aggregate particles on the one hand, and to ensure the needed processing characteristics (placeability) of the mix on the other. It is shown experimentally that the material obtained has a rather high compression strength. Under prolonged compression loads, the polymer-concrete exhibits a noticeable creep behavior with a linear relation between the creep strains and stresses. After the action of half the ultimate load over 3000 h, the total strains exceed the instantaneous ones by 2.0 to 2.2 times. The accumulation of irreversible strains is also observed; however, their contribution to the total strain is small. It is found that the stress-strain relation can be represented by the equation of linear hereditary creep theory.Institute of Polymer Mechanics, University of Latvia, Riga, LV-1006, Latvia. Translated from Mekhanika Kompozitnykh Materialov, Vol. 35, No. 2, pp. 147–162, March–April, 1999.     

Selective photoconductivity induced in PbTe(Ga) by a local phonon mode

Selective photoconductivity at frequency ω=155 cm⁻ was discovered in PbTe(Ga) narrow-gap semiconductors at liquid-nitrogen temperatures. The corresponding energy is much lower than all characteristic energies of the electronic spectrum of the semiconductor. The effect is attributed to optical excitation of a local vibrational mode of an impurity center leading to delocalization of the electrons. Pis’ma Zh. éksp. Teor. Fiz. 63, No. 5, 342–346 (10 March 1996)