全文获取类型
收费全文 | 860篇 |
免费 | 22篇 |
国内免费 | 4篇 |
专业分类
化学 | 581篇 |
晶体学 | 4篇 |
力学 | 11篇 |
数学 | 107篇 |
物理学 | 183篇 |
出版年
2021年 | 8篇 |
2020年 | 7篇 |
2019年 | 6篇 |
2016年 | 5篇 |
2015年 | 14篇 |
2014年 | 14篇 |
2013年 | 29篇 |
2012年 | 37篇 |
2011年 | 40篇 |
2010年 | 30篇 |
2009年 | 15篇 |
2008年 | 44篇 |
2007年 | 45篇 |
2006年 | 47篇 |
2005年 | 40篇 |
2004年 | 40篇 |
2003年 | 30篇 |
2002年 | 28篇 |
2001年 | 17篇 |
2000年 | 9篇 |
1999年 | 14篇 |
1998年 | 9篇 |
1997年 | 9篇 |
1996年 | 11篇 |
1995年 | 11篇 |
1994年 | 12篇 |
1993年 | 18篇 |
1992年 | 24篇 |
1991年 | 11篇 |
1990年 | 14篇 |
1989年 | 12篇 |
1988年 | 7篇 |
1987年 | 19篇 |
1986年 | 13篇 |
1985年 | 5篇 |
1984年 | 14篇 |
1983年 | 9篇 |
1982年 | 9篇 |
1981年 | 9篇 |
1977年 | 5篇 |
1976年 | 6篇 |
1974年 | 6篇 |
1971年 | 6篇 |
1970年 | 5篇 |
1959年 | 5篇 |
1955年 | 5篇 |
1931年 | 4篇 |
1930年 | 4篇 |
1928年 | 6篇 |
1923年 | 9篇 |
排序方式: 共有886条查询结果,搜索用时 31 毫秒
11.
12.
13.
On a New Copper Cobalt Borate Oxide with Isolated B2O5 Units: Cu2Co(B2O5)O Single crystals of a new compound with the empirical formula Cu2CoB2O6 were obtained by using a B2O3 flux technique. X-ray single crystal technique led to a new structure type. Cu2CoB2O6 crystallizes monoclinic, space group C-P21/c (No. 14); a = 3.2250(6); b = 14.847(1); c = 9.1171(6) Å; β = 93.67°; Z = 4. All metal sites are octahedrally coordinated and form a two dimensional framework consisting of edge sharing octahedra ribbons. In addition one observes isolated B2O5-units and oxygen which is not coordinated to boron. The far relation to the crystal structure of the mineral Warwickite is illustrated. 相似文献
14.
The coulometric electrolytic principle is utilized for the measurement of moisture sorbed on sintered thorium dioxide. Moisture is removed from the sample by heating and is swept by dry argon gas through a hygrometer. The resulting hygrometer output is converted into frequency pulses and counted cumulatively. The instrument is calibrated by use of standard hydrated chemicals. The number of counts/mu;g of water obtained from standards compares favourably with the theoretical number of counts/mu;g calculated from performance specifications of the components employed. The error is <5% for 1-350mu;g of water. A high sensitivity and low operating blank recommends application of this method to materials other than thorium dioxide, having very low moisture contents. 相似文献
15.
The ground (X (3)Sigma(-)) and first excited triplet (A (3)Pi) electronic states of diazocarbene (CNN) have been investigated systematically starting from the self-consistent-field theory and proceeding to the coupled cluster with single, double, and full triple excitations (CCSDT) method with a wide range of basis sets. While the linear X (3)Sigma(-) ground state of CNN has a real degenerate bending vibrational frequency, the A (3)Pi state of CNN is subject to the Renner-Teller effect and presents two distinct real vibrational frequencies along the bending coordinate. The bending vibrational frequencies of the A (3)Pi state were evaluated via the equation-of-motion coupled cluster (EOM-CC) techniques. The significant sensitivity to level of theory in predicting the ground-state geometry, harmonic vibrational frequencies, and associated infrared intensities has been attributed to the fact that the reference wave function is strongly perturbed by the excitations of 1pi-->3pi followed by a spin flip. At the highest level of theory with the largest basis set, correlation-consistent polarized valence quadruple zeta (cc-pVQZ) CCSDT, the classical X-A splitting (T(e) value) was predicted to be 68.5 kcal/mol (2.97 eV, 24 000 cm(-1)) and the quantum mechanical splitting (T(0) value) to be 69.7 kcal/mol (3.02 eV, 24 400 cm(-1)), which are in excellent agreement with the experimental T(0) values, 67.5-68.2 kcal/mol (2.93-2.96 eV, 23 600-23 900 cm(-1)). With the EOM-CCSD method the Renner parameter (epsilon) and averaged bending vibrational frequency (omega(2)) for the A (3)Pi state were evaluated to be epsilon=-0.118 and omega(2)=615 cm(-1), respectively. They are in fair agreement with the experimental values of epsilon=-0.07 and nu(2)=525 cm(-1). 相似文献
16.
Structure of anisomycin 总被引:1,自引:0,他引:1
17.
Summary Diaromatics are geochemically significant constituents of crude oils. Their determination is usually achieved by elaborate prefractionation methods, such as medium pressure liquid chromatography and HPLC, prior to capillary gas chromatography. The present contribution describes the quantitative analysis of methylnaphthalenes, ethylnaphthalenes, and dimethylnaphthalenes in selected crude oils by two-dimensional capillary GC. Since the method does not comprise any work-up procedure the determination of geochemical parameters (alkylnaphthalene concentration ratios) is performed on the original, untreated crude oil samples. Accordingly, the analytical results reflect the original composition. The influence by evaporational losses in the laboratory is minimized. 相似文献
18.
采用正电子寿命谱和双探头Doppler展宽测量在原子尺度上研究了α-Fe/Nd2Fe14B复合纳米晶的界面结构.正电子寿命研究表明, α-Fe/Nd2Fe14B复合纳米晶存在两类界面.一类为非晶界面层, 正电子湮没寿命为155 ps; 另一类为具有原子空位的松懈界面, 含有空位尺寸大于1~2个铁原子空位的结构自由体积, 正电子湮没寿命为246 ps.电子-正电子湮没光子的共谐Doppler展宽测量表明这类松懈界面富集非磁性原子Nd和B, 这将削弱α-Fe/Nd2Fe14B复合纳米晶晶粒间的磁交换耦合. 相似文献
19.
Henry F. Schaefer 《Journal of Molecular Structure》1981,76(2):117-135
In theoretical studies of the electronic structure of organometallic complexes, the choice of basis set is critical, much more so than for analogous studies of molecules containing only H, C, N, and O. This problem is discussed in the light of structural predictions for the transition metal hydrides MH, MH2, and MH4, for the fluorides MF2 and MF3, and for Ni(CO)4, Ni(C2H4)3, (CO)3NiCH2, and Ni(C4H4)2. 相似文献
20.
Schaefer M Gross W Preuss M Ackemann J Gebhard MM 《Bioelectrochemistry (Amsterdam, Netherlands)》2003,61(1-2):85-92
We determined water content and water distribution by fitting dielectric spectra of ischemic canine hearts between 5 MHz and 3 GHz with a newly developed model which describes heart cells and subcellular organelles as rotational ellipsoids filled with electrolyte enclosed by an isolating membrane. The fraction of dry material is modelled by spherical particles with a small dielectric permittivity. Free model parameters were water content, cell volume fraction, and the conductivity of the electrolytes. Resulting model parameters were compared to data from tissue desiccation and to conductivity changes produced by protons and lactate ions. We investigated hearts in two states: during ischemia after interruption of blood flow (pure ischemia, PI, n=5) and during ischemia after resuscitation with Tyrode's solution (IAR, n=14).The difference between water content determined by tissue desiccation and by dielectric spectroscopy was less than 0.5%. During 360 min of ischemia, water content in IAR decreased from 85+/-1.6% to 83+/-2.2% and in PI from 80+/-0.8% to 78+/-1.5%. Cellular volume fraction in IAR increased from 0.47+/-0.045 to 0.63+/-0.031 and in PI from 0.62+/-0.014 to 0.73+/-0.013, which is consistent with published morphometric data. After 180 min of ischemia, the increase of the cytosolic conductivity was 0.14+/-0.02 S/m as calculated from the dielectric spectrum and was similar to the conductivity increase which was roughly estimated on the basis of tissue lactate concentration.In conclusion, dielectric spectroscopy combined with our model analysis facilitates the monitoring of water content and distribution by means of nondestructive surface probes. 相似文献