全文获取类型
收费全文 | 33721篇 |
免费 | 273篇 |
国内免费 | 271篇 |
专业分类
化学 | 12930篇 |
晶体学 | 285篇 |
力学 | 1481篇 |
综合类 | 12篇 |
数学 | 9624篇 |
物理学 | 9933篇 |
出版年
2022年 | 69篇 |
2021年 | 97篇 |
2020年 | 88篇 |
2019年 | 77篇 |
2018年 | 1259篇 |
2017年 | 1508篇 |
2016年 | 860篇 |
2015年 | 646篇 |
2014年 | 591篇 |
2013年 | 887篇 |
2012年 | 3312篇 |
2011年 | 2548篇 |
2010年 | 1897篇 |
2009年 | 1617篇 |
2008年 | 766篇 |
2007年 | 786篇 |
2006年 | 754篇 |
2005年 | 4587篇 |
2004年 | 4010篇 |
2003年 | 2395篇 |
2002年 | 560篇 |
2001年 | 363篇 |
2000年 | 175篇 |
1999年 | 235篇 |
1998年 | 163篇 |
1997年 | 128篇 |
1996年 | 110篇 |
1995年 | 113篇 |
1994年 | 98篇 |
1993年 | 90篇 |
1992年 | 238篇 |
1991年 | 203篇 |
1990年 | 189篇 |
1989年 | 144篇 |
1988年 | 147篇 |
1987年 | 102篇 |
1986年 | 89篇 |
1985年 | 93篇 |
1984年 | 86篇 |
1983年 | 75篇 |
1982年 | 76篇 |
1981年 | 80篇 |
1979年 | 81篇 |
1978年 | 78篇 |
1976年 | 128篇 |
1975年 | 99篇 |
1974年 | 80篇 |
1973年 | 94篇 |
1967年 | 71篇 |
1966年 | 69篇 |
排序方式: 共有10000条查询结果,搜索用时 171 毫秒
51.
Celik Tarimci Anda? Karamustafa Kutalmi? Güven Mehmet Kabak Akgül Ye?ilada 《Analytical sciences》2003,19(9):1347-1348
The crystal structure of 1-[3-(3,4-dimethoxyphenyl)-2-propenoyl]pyrrolidine (C15H19NO3) (I) has been determined by X-ray analysis. It crystallizes orthorhombic space group Pbca with a = 24.295(3), b = 15.086(3), c = 7.552(3)A, V = 2768(1)A3, Z = 8, Dcalc = 1.254 g/cm3, mu = (Mo K(alpha)) = 0.87 cm(-1). The title compound has analgesic activity of cycloaliphatic amine part. The molecule is deviated from planar configuration. 相似文献
52.
We introduce and investigate the properties of Hochschild cohomology of algebras in an abelian monoidal category M. We show that the second Hochschild cohomology group of an algebra in M classifies extensions of A up to an equivalence. We characterize algebras of Hochschild dimension 0 (separable algebras), and of Hochschild dimension ≤1 (formally smooth algebras). Several particular cases and applications are included in the last section of the paper. 相似文献
53.
54.
C. B?uerle Yu M. Bunkov S. N. Fisher H. Godfrin G. R. Pickett 《Czechoslovak Journal of Physics》1996,46(Z1):5-6
During studies of the impact of single neutrons on superfluid3He at around 100μK we have measured the thermal energy released in the superfluid following the nuclear reaction, n+3He→p+3H+764keV. However, we find that the measured energy deposited in the quasiparticle system shortly after this reaction is substantially
less than what we expect. We believe that this energy deficit represents that energy which has gone into the creation of vortices,
in analogy to the creation of cosmic strings in the early universe via the Kibble mechanism. Furthermore, from the magnitude
of the deficit, we can infer the vortex density which compares favorably with that predicted in Zurek’s scenairo. 相似文献
55.
The pion cloud renormalises the light-cone wavefunction of the nucleon which is measured in hard, exclusive photon-nucleon reactions. We discuss the leading twist contributions to high-energy exclusive reactions taking into account both the pion cloud and perturbative QCD physics. The nucleon’s electromagnetic form-factor at high Q2 is proportional to the bare nucleon probability Z and the cross-sections for hard (real at large angle or deeply virtual) Compton scattering are proportional to Z2. Our present knowledge of the pion-nucleon system is consistent with Z = 0.7 ± 0.2. If we apply just perturbative QCD to extract a light-cone wavefunction directly from these hard exclusive cross-sections, then the light-cone wavefunction that we extract measures the three valence quarks partially screened by the pion cloud of the nucleon. We discuss how this pion cloud renormalisation effect might be understood at the quark level in terms of the (in-)stability of the perturbative Dirac vacuum in low energy QCD. 相似文献
56.
P E S?rensen R A McClelland R D Gandour 《Acta chemica Scandinavica (Copenhagen, Denmark : 1989)》1991,45(6):558-566
The ring-chain tautomerism in aqueous solution of some aryl-substituted morpholinium salts (bromides), has been studied and equilibrium constants are reported. In the crystals the substrates exist entirely in their cyclic forms as hemiacetals, but in aqueous solution NMR measurements reveal that an equilibrium is established between the cyclic (hemiacetal) and the noncyclic (ketone) form, the degree of ring-opening being more pronounced with electron-donating aryl substituents at the carbonyl carbon. The kinetics of the ring-chain interconversion in water has been investigated spectrophotometrically by a 'pH jump' stopped-flow technique. General base catalysis is observed with a Br?nsted beta value apparently independent of substituent and equal to 0.60. The Hammett rho values for various base catalysts are close to those for very similar intermolecular reactions involving hemiacetal breakdown, leading to the suggestion of a 'normal' class n mechanism for base catalysis. For acid catalysis, however, a quite different situation is encountered, since no general acid but only (weak) catalysis by the hydronium ion can be detected. We believe this deviation from 'normal' general acid catalysis is caused by an electrostatic interaction, and we suggest that it might result from a change in the usual class e mechanism for general acid catalysis by a situation in which rate-limiting concerted proton transfer is replaced by rate-limiting preprotonation. This is supported by the observed drastic change in Hammett rho value for catalysis by the hydronium ion, compared with the 'normal' case. An interesting case is encountered for the 4-aminophenyl-substituted substrate, in which the amino group becomes protonated in acid solution, thus representing a new substituent. Despite this complication, the various equilibrium and rate constants may also be evaluated experimentally for this substrate. 相似文献
57.
P Nürnberg I Barth E Fuhrmann C Lenzner T Losanova C Peters H P?che G Thiel 《Electrophoresis》1991,12(2-3):186-192
Germline and somatic instability of the human genome was studied, using synthetic oligonucleotides specific for simple repeat motifs. The following probes were used: (GTG)5, (GACA)4, (GATA)4, (CT)8, (TTAGGG)3, (GT)8, (GAA)6 and (GGAT)4. Each of them is unique with respect to the target regions recognized in the genome. Thus compilation of the various fingerprint data provides a complex map of the genome (and its deviations). While the fingerprints of differentiated somatic tissues never showed any alterations, in tumor tissues (namely gliomas) many changes could be detected. Most of the latter reflect secondary karyological aberrations. In nearly one third of the gliomas, drastically amplified and apparently monomorphic DNA fragments were identified. This marker should make it possible to deal with causal pathogenetic mechanisms as well as novel diagnostic strategies. 相似文献
58.
59.
F. Cannata J. P. Dedonder L. Le?niak 《Zeitschrift für Physik A Hadrons and Nuclei》1992,343(4):451-460
We investigate the origin of the attraction in theK¯K channel around the threshold by introducing an additional channel to theππ andK¯K channels in a separable potential formalism assuming, in general, no direct interaction in theK¯K channel. To reproduce the features of the data, we find that the threshold of the additional channel is much above thef 0(975) meson position. We show that this three-channel problem can be reduced to an effective two-channel problem where thef 0(975) behaves as if it were aK¯K molecule bound by the coupling to the exotic channel. This picture is also supported by the fact that a single pole only, in the complexK¯K momentum plane, is associated to thef 0(975) meson. Various physical observables, like the decay branching ratio and theK¯K scattering length, are then discussed in an effective two-channel framework. 相似文献
60.
V. M. Baev J. Eschner E. Paeth R. Schüler P. E. Toschek 《Applied physics. B, Lasers and optics》1992,55(6):463-477
A multi-mode diode laser with an external cavity is studied experimentally and theoretically for its application to intra-cavity spectroscopy. One facet of a typical Ga0.89Al0.11As laser diode was antireflection-coated by deposition of HfO2 such that 10–3 residual reflectivity was left over. This diode was placed in an external optical cavity. The emission spectrum of this diode laser is highly sensitive to any frequency-dependent loss in the cavity, and the detectivity of such a loss grows with the pump rate. Even close to threshold, the absorption at 780 nm of Rb atoms with a density of 5×1010 cm–3 has been detected. An adequate model for diode lasers based on rate equations and including frequency-dependent gain saturation is developed and applied to the calculations of output spectra. The sensitivity of these spectra to intra-cavity absorption is determined by the overall cavity loss — which is rather high — and the fraction of spontaneous emission in the total emission, in contrast with dye lasers where it is limited by nonlinear mode coupling. Various criteria for the sensitivity are suggested. The smallest detectable absorption with a perfectly antireflection-coated laser is 10–6 cm–1. Improvement of the characteristics of the laser diode would increase the sensitivity. 相似文献