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21.
Ranjan K. Mohapatra Pradeep K. Das Manoj K. Pradhan Abdussalam A. Maihub Marei M. El-ajaily 《Journal of the Iranian Chemical Society》2018,15(10):2193-2227
Schiff bases are stable imines containing C=N, where N is bonded to an alkyl or aryl group, but not with hydrogen and are prepared by condensation of aliphatic or aromatic primary amine with carbonyl compounds. They have the general formula R1R2C?=?NR3, where R3?≠?H. The presence of the basic donor N atom and the stability of the imine function render Schiff bases as the most favored ligands that have the ability to stabilize metal ions in different oxidation states. The chelating environment in a Schiff base profoundly influences the electron distribution in the coordination sphere of metal in a complex and thereby regulates the property of the compounds in a big way. The structural diversity in some of the metal complexes with multidentate Schiff base ligands has triggered a wide range of applications of this class of compounds in sensors, catalysis, biology, medicines, and photonics. This review compiles the synthesis and biological activities (antimicrobial, antioxidant, anticancer, antitubercular, DNA interaction studies) of benzaldehyde-based Schiff bases and their metal complexes. 相似文献
22.
23.
Francis R. Costa Sudip Pradhan Udo Wagenknecht Anil K. Bhowmick Gert Heinrich 《Journal of Polymer Science.Polymer Physics》2010,48(22):2302-2311
In elastomer/organo clay nanocomposites, the morphological characteristics, and hence the mechanical properties, of the vulcanizates are strongly influenced by the organic modifier and the vulcanization process. When the elastomer itself undergoes strain‐induced crystallization, both the organic modifier and the dispersed filler particles could significantly influence the crystallization process. These phenomena are very common in case of natural rubber‐based vulcanizates. In this study, the similar effects have been demonstrated with carboxylated nitrile rubber (XNBR) and organically modified layered double hydroxide (O‐LDH)‐based nanocomposites. The effect of size of the organic modifier was obviously visible on the interlayer distance of O‐LDH and also on the morphological reorganization of the dispersed O‐LDH particles during vulcanization process. The strain‐induced crystallization of the XNBR was found to be strongly dependent on the morphological change that occurs during vulcanization process. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2010 相似文献
24.
Bianchi type V perfect fluid cosmological models are investigated with cosmological term varying with time. Using a generation technique (Camci et al., 2001), it is shown that Einsteins field equations are solvable for any arbitrary cosmic scale function. Solutions for particular forms of cosmic scale functions are also obtained. The cosmological constant is found to be a decreasing function of time, which is supported by results from recent type Ia supernovae observations. Some physical aspects of the models are also discussed. 相似文献
25.
Giulio?CodognatoEmail author Sayantan?GhosalEmail author 《International Journal of Game Theory》2003,31(4):493-498
In this paper, we generalize the exitence result for pure strategy Nash equilibria in anonymous nonatomic games. By working directly on integrals of pure strategies, we also generalize, for the same class of games, the existence result for undominated pure strategy Nash equilibria even though, in general, the set of pure strategy Nash equilibria may fail to be weakly compact.
Received August 2001 相似文献
26.
A novel ferrocene-based anion receptor bearing amide and triazolium donor groups and its anion complexation have been reported. We found that it shows marked electrochemical selectivity to F(-), followed by AcO(-) > Cl(-) > Br(-) > I(-), which is in accordance with (1)H NMR titration results. 相似文献
27.
Pradhan Susanta Kumar Ambade Balram 《Journal of Radioanalytical and Nuclear Chemistry》2019,320(2):459-466
A modified LED fluorimetry determination of uranium in Nb/Ta minerals has been developed. The mineral is brought into solution by fusion with mixed phosphate flux (NaH2PO4, H2O and Na2HPO4). Iron quenches uranium fluorescence when it is present above the ratio of (iron to uranium) 100. Uranium is separated in ethyl acetate by solvent extraction and then stripped back into pyrophosphate buffer (pH ~ 7) prior to its LED fluorimetry determination. This modified method has been applied for the determination of uranium in synthetic mixtures and Nb/Ta minerals including Certified Reference Materials (X1807) with high degree of accuracy and precision.
相似文献28.
A method to study domain structure in ferroelectrics, using pyroelectric effect is described. Variation of pyroelectric signal
from the surface of a triglycine sulphate crystal plate has been studied by scanning the surface of the crystal with a low
wattage He-Ne laser beam. The integrated pyroelectric signal is due to two components, namely, (1) the primary component arising
out of the change in spontaneous polarization with temperature and (2) the delayed component arising out of the possible polarization
reversal. The component of an electric field along the ferroelectric axis due to thermal hemisphere within the crystal plate
formed by the laser beam has been calculated and shown to exceed coercive field, making polarization reversal possible. The
delayed pyroelectric signal is a measure of polarization reversal within the patch illuminated and its observed variation
over the surface yields information of the domain structure. 相似文献
29.
Gyanaranjan Prusty Amit K. Guria Indranil Mondal Anirban Dutta Dr. Ujjwal Pal Dr. Narayan Pradhan 《Angewandte Chemie (International ed. in English)》2016,55(8):2705-2708
A generic modular synthetic strategy for the fabrication of a series of binary‐ternary group II‐VI and group I‐III‐VI coupled semiconductor nano‐heterostructures is reported. Using Ag2Se nanocrystals first as a catalyst and then as sacrificial seeds, four dual semiconductor heterostructures were designed with similar shapes: CdSe‐AgInSe2, CdSe‐AgGaSe2, ZnSe‐AgInSe2, and ZnSe‐AgGaSe2. Among these, dispersive type‐II heterostructures are further explored for photocatalytic hydrogen evolution from water and these are observed to be superior catalysts than the binary or ternary semi‐conductors. Details of the chemistry of this modular synthesis have been studied and the photophysical processes involved in catalysis are investigated. 相似文献
30.
The oxidation of alcohols to aldehydes using stoichiometric 4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate (1) in CH(2)Cl(2) at room temperature is a highly selective process favoring reaction at the carbinol center best able to accommodate a positive charge. The oxidation of aldehydes to carboxylic acids by 1 in wet acetonitrile is also selective; the rate of the process correlates with the concentration of aldehyde hydrate. A convenient and high yield method for oxidation of alcohols directly to carboxylic acids has been developed. 相似文献