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951.
Fabian Gyger André Sackmann Michael Hübner Pascal Bockstaller Dagmar Gerthsen Henning Lichtenberg Jan‐Dierk Grunwaldt Nicolae Barsan Udo Weimar Claus Feldmann 《Particle & Particle Systems Characterization》2014,31(5):591-596
Pd@SnO2 and SnO2@Pd core@shell nanocomposites are prepared via a microemulsion approach. Both nanocomposites exhibit high‐surface, porous matrices of SnO2 shells (>150 m2 g?1) with very small SnO2 crystallites (<10 nm) and palladium (Pd) nanoparticles (<10 nm) that are uniformly distributed in the porous SnO2 matrix. Although similar by first sight, Pd@SnO2 and SnO2@Pd are significantly different in view of their structure with Pd inside or outside the SnO2 shell and in view of their sensor performance. As SMOX‐based sensors (SMOX: semiconducting metal oxide), both nanocomposites show a very good sensor performance for the detection of CO and H2. Especially, the Pd@SnO2 core@shell nanocomposite is unique and shows a fast response time (τ90 < 30 s) and a very good response at low temperature (<250 °C), especially under humid‐air conditions. Extraordinarily high sensor signals are observed when exposing the Pd@SnO2 nanocomposite to CO in humid air. Under these conditions, even commercial sensors (Figaro TGS 2442, Applied Sensor MLC, E2V MICS 5521) are outperformed. 相似文献
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Linear continuous logic is the fragment of continuous logic obtained by restricting connectives to addition and scalar multiplications. Most results in the full continuous logic have a counterpart in this fragment. In particular a linear form of the compactness theorem holds. We prove this variant and use it to deduce some basic preservation theorems. 相似文献
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Chang‐Ching Chan Mark S. Bolgar Dilusha Dalpathado David K. Lloyd 《Rapid communications in mass spectrometry : RCM》2012,26(12):1507-1514
A method has been developed to reduce the mass spectrometric ion signal suppression associated with the use of TFA as an additive in LC mobile phases. Through post‐column infusion of diluted NH4OH solution to LC eluents, the ammonium ion introduced causes the neutral analyte‐TFA ion pair to dissociate which consequently releases the protonated analyte as free ions into the gas phase (through regular electrospray ionization mechanisms). An ion signal improvement from 1.2 to 20 times for a variety of compounds had been achieved through the application of this method. The molar ratios of NH4OH:TFA which result in a reduction of signal suppression were determined to be between 0.5:1 and 50:1. In addition, it was shown that this NH4OH infusion method could reduce the level of doubly‐charged species and the product ions formed via in‐source collision. The use of diluted NH4OH solution is favorable since it is compatible with mass spectrometry analysis, and it is applicable in both positive and negative‐ion generation mode. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献