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排序方式: 共有393条查询结果,搜索用时 483 毫秒
71.
M. Satyanarayana 《Semigroup Forum》1988,37(1):225-231
Communicted by J. S. Ponizovskii 相似文献
72.
73.
M. V. S. Chandrasekhar Rao N. Venkateswara Rao S. Bhuloka Reddy G. Satyanarayana D. L. Sastry M. R. Iyer S. G. Sahasrabhude 《Zeitschrift für Physik A Hadrons and Nuclei》1988,330(2):161-165
The total conversion coefficient of the 127.49 keV E3 isomeric transition in the decay of134mCs was measured using the gamma intensity balance method with the help of a high resolution low energy photon detector. Theα Tvalue was found to be 5.84±0.47 as against the theoretical value of 6.96, thus showing an anomaly of (16.1±6.7)%. TheK-conversion coefficient,α kwas also measured using the X-ray peak to gamma ray intensity method and found to be 2.24±0.04 as against the theoretical value of 2.72, which shows an anomaly of (17.6±1.4)% consistent with the experimental anomaly inα T. TheE3 hindrance factor of the isomeric transition was estimated to be (3.44±0.23) ·104. 相似文献
74.
In this paper, we disclose the synthesis of the dioxabicyclo[3.2.1]octane subunit of the potent antibiotic sorangicin A. The synthesis was achieved in a convergent manner in 8 steps. Regio- and stereoselective intermolecular epoxide opening, ring-closing metathesis and iodo-etherification are key steps. cis-2-Butene diol has been employed as a common staring material. 相似文献
75.
J.S. Yadav M. Satyanarayana E. Balanarsaiah S. Raghavendra 《Tetrahedron letters》2006,47(34):6095-6098
A simple, mild, efficient and environmentally benign method for the synthesis of 2,3-unsaturated allyl C-glycosides and O- and S-glycosides is described using phosphomolybdic acid supported on silica gel as a reusable catalyst with high α-selectivity. 相似文献
76.
An acid catalysed rearrangement was employed for the enantiospecific conversion of isotwistanol to tricyclo[5.2.1.04,8]decanes, which provided support for the proposed biosynthesis of allopupukeananes from pupukeananes. The strategy has been further extended to the enantiospecific synthesis of a homobrexane. 相似文献
77.
Tatakuntla Satyanarayana Nageswara Rao Anipindi Veeraputhiran Subbiah Madhusudan Waman Pandit 《Transition Metal Chemistry》1992,17(4):325-327
The rapid oxidation ofbis(2,4,6-tripyridyl-1,3,5-triazine)-iron(II), [Fe(TPTZ)2]2+, bytrans-1,2-diaminocyclohexanetetraacetatomanganate(III), [MnIII(Y)]−, in acetate buffers was monitored using stopped-flow spectrophotometry. The reaction is first order in the substrate and
evidence was obtained for pre-complexation between the oxidant and the substrate. The reaction rate increases as the pH increases.
Characterisation of the products using the radiotracers54Mn and59Fe indicated that [MnII(Y)]2− and [Fe(TPTZ)2]3+ are the final products. The reaction obeys the rate law:
相似文献
78.
N. Kurmaiah D. Satyanarayana V. Pandu Ranga Rao 《Fresenius' Journal of Analytical Chemistry》1967,230(3):199-204
Summary Salicylaldehyde is proposed as both a chelating and extracting agent. Vanadium(V) can be extracted from aqueous solutions of pH 1.4 using a solvent mixture containing 90% salicylaldehyde and 10% n-butanol. n-Butanol exerts a synergic effect on the extraction of vanadium(V) by salicylaldehyde. Based on this extraction, a spectrophotometric method has been developed for the determination of vanadium, the sensitivity being 0.0168 g of vanadium per cm2. The nature of the extracted species and a possible mechanism for the synergic effect of the alcohol are discussed.
Zusammenfassung Salicalaldehyde wird als chelatbildendes Extraktionsmittel für Vanadium vorgeschlagen. Aus wäßrigen Lösungen vom pH 1,4 kann Vanadium mit einem Lösungsmittelgemisch aus 90% Salicylaldehyd und 10% n-Butanol extrahiert werden, wobei das Butanol eine synergistische Wirkung ausübt. Die anschließende spektrophotometrische Bestimmung kann mit einer Empfindlichkeit von 0,0168 g V/cm2 durchgeführt werden. Die Art des gebildeten Komplexes sowie die Wirkung des Alkohols werden diskutiert.相似文献 79.
Anala S Pavlovskaya GE Pichumani P Dieken TJ Olsen MD Meersmann T 《Journal of the American Chemical Society》2003,125(43):13298-13302
The first successful in situ studies of free combustion processes by one- and two-dimensional NMR spectroscopy are reported, and the feasibility of this concept is demonstrated. In this proof-of-principle work, methane combustion over a nanoporous material is investigated using hyperpolarized (hp)-xenon-129 NMR spectroscopy. Different inhomogeneous regions within the combustion cell are identified by the xenon chemical shift, and the gas exchange between these regions during combustion is revealed by two-dimensional exchange spectra (EXSY). The development of NMR spectroscopy as an analytical tool for combustion processes is of potential importance for catalyzed reactions within opaque media that are difficult to investigate by other techniques. 相似文献
80.
R. Srinivasulu P. V. V. Satyanarayana K. Ravi Kumar 《Russian Journal of General Chemistry》2013,83(12):2419-2422
Treatment of tetrahydropyranyl (THP) ethers with zinc triflate in methanol provides a simple and efficient process for deprotection of these ethers and the parent alcohols are obtained in excellent yields. 相似文献
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