Study of Amorphous Ferrimagnet Fe0.66Er0.19B0.15 by Means of Monochromatic Circularly Polarised Source

Properties of amorphous alloy Fe_0.66Er_0.19B_0.15 are reported. A reorientation of the Fe and Er magnetic moments during sample cooling through the compensation point in a large magnetic field is found by means of monochromatic circularly polarised radiation. This revised version was published online in August 2006 with corrections to the Cover Date.     

Influence of high-frequency magnetic fields on Mössbauer resonance

The influence of high-frequency magnetic modulation on Mössbauer resonance is investigated using the⁶⁷Zn resonance. A phase-modulation theory theory explaining the experimental results is presented. Implications to magnetic modulation experiments with the⁵⁷Fe resonance are also discussed.     

Phase modulation of recoilless gamma radiation by nuclear zeeman effect

The use of an alternating magnetic field for phase modulation of recoilless gamma radiation is studied. The measurements were performed with the Mössbauer resonances of Fe-57 and Zn-67. Novel time-domain data are presented from experiments on the nuclear Zeeman effect at high modulation frequencies.     

Thermosensitivity of Bile Acid‐Based Oligo(ethylene glycol) Stars in Aqueous Solutions

Amphiphilic star‐shaped oligo(ethylene glycol)s with a hydrophobic bile acid core and varying number of hydrophilic arms have been made. Their thermal behavior in aqueous solutions depends on the number rather than the length of the arms. The two‐armed lithocholate derivative showed the strongest tendency for association and exhibited the lowest cloud point (79 °C) of the oligomers made, as well as another phase separation at a lower temperature (31 °C). The “double thermosensitivity” arising both from the salt‐dependent LCST of the oligo(ethylene glycol) segments and the temperature‐responsive self‐assembly of amphiphilic bile acid derivative provides an interesting path in the design of bile acid‐based smart materials.

     

Coherence of radiation as studied by multiple coincidences of photons and particles

Coincidences of photons and particles are measured by counting the number of events occurring simultaneously in two or more detectors. Coherent and incoherent radiation may have different behavior when the number of coincidence counts is studied with different arrangements of the coincidence detectors: the coincidence rate for the coherent radiation field, such as that obtained from a single-mode laser, is independent on the transverse separation between the detectors as long as the intensity of the radiation stays constant. On the other hand, with incoherent thermal radiation, using suitable monochromatization, the coincidence rate can show a significant bunching effect at detector separations smaller than the transverse coherence length. As a third alternative, photon antibunching may be observed if the radiation field is prepared in a number state, such as that available from resonance fluorescence of atoms, ions or molecules. If the time resolution of the detectors is not sufficient to resolve separate counts, corresponding effects can be observed in experiments, where the analog outputs of the detectors are multiplied to produce an intensity correlation signal. Intensity correlation and coincidence studies of photons and particles are reviewed in this report starting from the early experiments in the 1950’s and including recent work on X-ray coincidences and three-pion correlations. New results are presented for three- and four-photon coincidences at the X-ray wavelengths.     

Shell structure fingerprints of tensor interaction

We address the consequences of strong tensor terms in the local energy density functional, resulting from fits to the f _5/2 -f _7/2 splittings in ⁴⁰Ca , ⁴⁸Ca , and ⁵⁶Ni . In this study, we focus on the tensor contribution to the nuclear binding energy. In particular, we show that it exhibits an interesting topological feature closely resembling that of the shell correction. We demonstrate that in the extreme single-particle scenario at spherical shape, the tensor contribution shows tensorial magic numbers equal to N(Z) = 14 , 32, 56, and 90, and that this structure is smeared out due to configuration mixing caused by pairing correlations and migration of proton/neutron sub-shells with neutron/proton shell filling. Based on a specific Skyrme-type functional SLy4_T, we show that the proton tensorial magic numbers shift with increasing neutron excess to Z = 14 , 28, and 50.     

Encapsulation and release by star‐shaped block copolymers as unimolecular nanocontainers

A five‐arm star‐shaped poly(ethylene oxide) (PEO) with terminal bromide groups was used as a macroinitiator for the atom transfer radical polymerization of tert‐butyl acrylate (tBA), resulting in five‐arm star‐shaped poly(ethylene oxide)‐block‐poly(tert‐butyl acrylate) block copolymers. The polymerization proceeded in a controlled way using a copper(I)bromide/pentamethyl diethylenetriamine catalytic system in acetonitrile as solvent. The hydrolysis of the tBA blocks of the amphiphilic star‐shaped PEO‐b‐PtBA block copolymer resulted in dihydrophilic star structures. The encapsulation of the star‐block copolymers and their release properties in acid environment have been followed by UV‐spectroscopy and color changes, using the dye methyl orange as a hydrophilic guest molecule. Characterization of the structures has been done by ¹H NMR, size exclusion chromatography, MALDI‐TOF, and differential scanning calorimetry. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 650–660, 2008     

Preparation of chiral indenes containing β-pinenyl derived ligand substituents

A simple procedure for the preparation of new 1-, 2- and 1,3-chirally substituted indenes is described in which indenyllithium or 2-indenylmagnesium bromide is reacted with a β-pinenyl derived chlorosilane. Synthesis of the ethylene bridged bis(indene) analogues of two of the new compounds is also described.