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991.
A non-integrable system has an irregular spectrum for stationary bound energy levels. It is shown that the irregular sequence of level spacings gives an unambiguous representation of chaos in quantum systems. 相似文献
992.
Tsunetoshi Kobayashi 《Physics letters. A》1984,103(9):424-426
He(I) photoelectron angular distributions of typical intramolecular hydrogen bond systems, 2-chloroethanol and 2-bromoethanol, were measured. The intramolecular hydrogen bonds were found not to influence the photoelectron angular distributions for the halogen atom lone pair bands of these compounds. This result is useful for spectral band assignments. 相似文献
993.
Electronic absorption and magnetic circular dichroism (MCD) spectra in UV-vis region of Waugh-structure [XMo9O32]6?(X = Ni(IV), Mn(IV)) ion in aqueous solution and solid IR spectra have been measured. The Ni(IV) ion in the polyanion has a low-spin d6 electronic configuration and the Mn(IV) ion has a d3 configuration. Visible absorption spectrum of the nickelate(IV) polyanion is interpreted to be mainly governed by charge-transfer transitions of the “ligand”, Mo9O32, to Ni(IV) ion, rather than d-d transitions, while visible absorption of the manganate(IV) polyanion is governed, to a great extent, by d-d transitions. It is indicated by the MCD spectrum that the splitting of the first d-d absorption in the manganate(IV) polyanion is due to a contribution of the spin-forbiden transition, rather than from a trigonal splitting of the spin-allowed transition. Absorption and MCD spectra in UV region are due to charge-transfer transition within a common “ligand”, which are less influenced by the kind of heteroatom, Ni(IV) or Mn(IV). The MCD pattern by the intra-ligand charge-transfer is especially characteristic of the Waugh-structure polyanions. 相似文献
994.
995.
Enthalpies of fusion have been measured by differential scanning calorimetry for a Na2O-SiO2 system at 50, 66.6, and 74.4 mol% SiO2. Enthalpies of mixing of liquids obtained from different calorimetry techniques are critically evaluated. The data on calorimetric enthalpy, activity of Na2O, cristobalite liquidus, and immiscibility gap are used to determine the enthalpy and entropy of mixing of sodium-silicate liquids are determined as a function of composition by the least squares method. The derived mixing properties are based only on the experimental data and are independent of any assumption about the structure and chemical species in liquids. The enthalpy of mixing has a minimum value of −120 kJ/mol at 35-40 mol% SiO2 and is convex upward around 80-90 mol% SiO2. The entropy of mixing have a maximum value of + 6 J/K-mol at 75 mol% SiO2, and it decreases with the SiO2 content to −5 J/K-mol at 40 mol% SiO2. This decrease in entropy can be accounted for by ideal mixing of Q4, Q3, and Q0 + 1 + 2 (= Q0 + Q1 + Q2) species in the liquids and is responsible for the negative temperature dependence of the partial molar Gibbs energy of mixing of Na2O, observed in activity measurements. Comparison of the present results with previous values suggests that a quasi-chemical model and the Adam-Gibbs model overestimate the configurational entropy of mixing of liquids. 相似文献
996.
Yasuhiro Maeda Masaki Yumoto Norihito Saito Takayo Ogawa Kazuo Kurokawa Akihiko Nakano Masafumi Yamashita Satoshi Wada 《Optical Review》2010,17(3):305-308
We have achieved a rapid and random wavelength tuned picosecond pulsed laser and a widely tunable UV-blue picosecond pulsed
laser by using the intracavity second harmonic generation of the laser. The tuning range was from 384 to 434 nm with picosecond
pulse oscillation. In addition, we demonstrated biological imaging using a fluorescent protein excited by the widely tunable
UV-blue picosecond pulsed laser. We found that the laser is suitable for biological imaging using the fluorescent protein
as an excitation light source without damages. 相似文献
997.
Feng Dang Kazumi Kato Hiroaki Imai Satoshi Wada Hajime Haneda Makoto Kuwabara 《Ultrasonics sonochemistry》2010,17(2):310-314
A new effect of ultrasonic irradiation on the formation of BaTiO3 particles was identified. Ultrasonication caused the aggregation of the original 5–10 nm BaTiO3 particles in the same crystal axis and accelerated the formation of BaTiO3 particles significantly. Furthermore, narrow size distribution was obtained for the aggregated particles under ultrasonic irradiation. 相似文献
998.
Kang-Sin Choi Tatsuo Kobayashi Ryosuke Maruyama Masaki Murata Yuichiro Nakai Hiroshi Ohki Manabu Sakai 《The European Physical Journal C - Particles and Fields》2010,67(1-2):273-282
We study 10D super Yang–Mills theory with the gauge groups E 6, E 7 and E 8. We consider the torus/orbifold compactification with magnetic fluxes and Wilson lines. They lead to 4D interesting models with three families of quarks and leptons, whose profiles in extra dimensions are quasi-localized because of magnetic fluxes. 相似文献
999.
Kishi N Kikuchi S Ramesh P Sugai T Watanabe Y Shinohara H 《The journal of physical chemistry. B》2006,110(49):24816-24821
Photoluminescence (PL) from purified (>90%) double-wall carbon nanotubes (DWNTs), which have been synthesized by zeolite catalyst-supported chemical vapor deposition (zeolite-CCVD), of very small diameters (0.8-nm average inner tube) is reported. The PL contour mappings for various ratios (1-90%) of double- versus single-wall carbon nanotubes by thermal oxidation have enabled us to unambiguously identify the chirality of inner tubes for the DWNTs synthesized. After the extensive high-temperature oxidation at 700 degrees C, high-purity (>90%) DWNTs of approximately 0.8 nm inner diameter are obtained, and most of these correspond to the DWNTs having inner tubes with chiralities of (7,5), (7,6), and (9,4). 相似文献
1000.
Reddy BM Lakshmanan P Loridant S Yamada Y Kobayashi T López-Cartes C Rojas TC Fernandez A 《The journal of physical chemistry. B》2006,110(18):9140-9147
The thermal stability of a nanosized Ce(x)Zr(1-x)O2 solid solution on a silica surface and the dispersion behavior of V2O5 over Ce(x)Zr(1-x)O2/SiO2 have been investigated using XRD, Raman spectroscopy, XPS, HREM, and BET surface area techniques. Oxidative dehydrogenation of ethylbenzene to styrene was performed as a test reaction to assess the usefulness of the VOx/Ce(x)Zr(1-x)O2/SiO2 catalyst. Ce(x)Zr(1-x)O2/SiO2 (1:1:2 mol ratio based on oxides) was synthesized through a soft-chemical route from ultrahigh dilute solutions by adopting a deposition coprecipitation technique. A theoretical monolayer equivalent to 10 wt % V2O5 was impregnated over the calcined Ce(x)Zr(1-x)O2/SiO2 sample (773 K) by an aqueous wet impregnation technique. The prepared V2O5/Ce(x)Zr(1-x)O2/SiO2 sample was subjected to thermal treatments from 773 to 1073 K. The XRD measurements indicate the presence of cubic Ce0.75Zr0.25O2 in the case of Ce(x)Zr(1-x)O2/SiO2, while cubic Ce0.5Zr0.5O2 and tetragonal Ce0.16Zr0.84O2 in the case of V2O5/Ce(x)Zr(1-x)O2/SiO2 when calcined at various temperatures. Dispersed vanadium oxide induces more incorporation of zirconium into the ceria lattice, thereby decreasing its lattice size and also accelerating the crystallization of Ce-Zr-O solid solutions at higher calcination temperatures. Further, it interacts selectively with the ceria portion of the composite oxide to form CeVO4. The RS measurements provide good evidence about the dispersed form of vanadium oxide and the CeVO4 compound. The HREM studies show the presence of small Ce-Zr-oxide particles of approximately 5 nm size over the surface of amorphous silica and corroborate with the results obtained from other techniques. The catalytic activity studies reveal the ability of vanadium oxide supported on Ce(x)Zr(1-x)O2/SiO2 to efficiently catalyze the ODH of ethylbenzene at normal atmospheric pressure. The remarkable ability of Ce(x)Zr(1-x)O2 to prevent the deactivation of supported vanadium oxide leading to stable activity in the time-on-stream experiments and high selectivity to styrene are other important observations. 相似文献