Potential-dependent structure of the interfacial water on the gold electrode

Doubly tunable sum frequency generation (SFG) spectra demonstrate that the water molecules at gold/electrolyte interface change their orientation with applied potential. At negative potentials, water molecules in the double layer align with their oxygen atom pointing to the solution. As potential became positive to be close to the potential of zero charge (PZC), the SFG signal decreased, suggesting the OH groups of the water molecule are either in random orientation or parallel to the electrode. As potential became more positive than the PZC, the SFG signal increased again with the oxygen-up orientation as same as in the negative potential region, indicating that water molecules interact with the adsorbed sulfate anions. The peak position of the SFG spectra indicates a relatively disordered state of water molecules at the gold electrode surface, in contrast to the previously observed ice-like structure of water at electrolyte/oxide interfaces.     

A Color Appearance Model Applicable in Mesopic Vision

We propose a color vision model that can be used to predict color appearance in mesopic vision as well as photopic and scotopic vision. It is based on a two-stage model which consists of the cone and opponent stages and it assumes rod intrusion at the opponent stage. The model has the following features to describe the color appearance in mesopic vision. First, it includes a gradual and nonlinear shift in spectral luminous efficiency from V (LD) to V (LD) to cope with the spectral sensitivity difference between photopic and scotopic vision and the nonlinearity of rod influence on the luminance channel. Second, the model assumes decrease of the chromatic component with decreasing illuminance to explain the reduction of saturation at low illuminance levels. Third, it assumes that red/green and yellow/blue components change with illuminance levels independently, thus explaining hue shifts with decreasing illuminance. We applied the model for color appearance simulation of natural scenes in a mesopic visual environment.     

Investigation of the influence of cell density of human fibroblasts cryopreserved inside collagen sponges at various cooling rates

The influence of cell density of cells cryopreserved inside a collagen matrix at various cooling rates was investigated. Human fibroblasts were three-dimensionally cultured for 2 days in a collagen sponge (20 mm in diameter and 1 mm in thickness) as an extracellular matrix to imitate biological tissue (artificial tissue). Different cell densities for the artificial tissue were used, from 10(5) to 10(7) cells/cm(3). Four artificial tissues were first stacked in a test chamber, frozen at a cooling rate of 0.3 to 50 degrees C/min in a solution of Dulbecco's Modified Eagle Medium, 20% fetal bovine serum and 10% dimethylsulfoxide, kept frozen below -185 degrees C for 2 hours, and then finally thawed. Membrane integrity of fibroblasts using a trypan blue exclusion assay was evaluated as an index for post-thaw cellular viability. Results show that with increasing cell density, the post-thaw membrane integrity decreased. Therefore, in the cryopreservation of biological tissue, it seems high cell density is one factor which causes a decline in viability.     

A possible interpretation of CDF dijet mass anomaly and its realization in supersymmetry

Recently, the CDF Collaboration reports an anomaly in dijet mass distribution in association with a lepton and missing energy. We discuss a possibility that the origin of the lepton and missing energy comes not from a W boson but a new boson particle, which is also responsible for the dijet mass peak. We show that such a situation can be realized in the framework of the minimal supersymmetric standard model and the dijet anomaly can be explained.     

Tip‐heating‐assisted Raman spectroscopy at elevated temperatures

We demonstrate tip‐heating‐assisted enhanced Raman spectroscopy to investigate the temperature dependence of the carbon nanotube G‐band with nanoscale resolution. The controllable and nanoscale heat generated at the tip apex was used to thermally perturb and characterize a small volume in a carbon nanotube sample that is precisely positioned underneath the tip. The dependence of tip enhancement with temperature was also experimentally examined, which is in good agreement with the enhancement calculated from the electromagnetic model of isolated spheroids. The technique presented may open up opportunities in the study of controlled heat‐assisted biochemical reactions and physical transformations of nanostructures. It can also be used for thermal characterization of various materials requiring site‐selective and controllable nanoscale heat source and could enable the realization of new photothermal devices. Copyright © 2010 John Wiley & Sons, Ltd.     

Nano-crater formation on a Si(1 1 1)-(7 × 7) surface by slow highly charged ion-impact

Using scanning tunneling microscopy (STM) and time of flight secondary ion mass spectrometry (TOF/SIMS), we observed radiation effects on a Si(1 1 1)-(7 × 7) surface in the collision of a single highly charged ion (HCI) with a charge state q up to q = 50. The STM observation with atomic resolution revealed that a nanometer sized crater-like structure was created by a single HCI impact, where the size increased rapidly with q. The secondary ion yields also increased with q in which multiply charged Si ions (Siⁿ⁺) were clearly observed in higher q HCI-collisions. The sputtering mechanism is briefly discussed, based on the so-called Coulomb explosion model.     

Intersecting brane models and F-theory in six dimensions

We analyze six-dimensional supergravity theories coming from intersecting brane models on the toroidal orbifold T⁴/_Z2$T^4/{\mathbb{Z}}_2$. We use recently developed tools for mapping general 6D supergravity theories to F-theory to identify F-theory constructions dual to the intersecting brane models. The F-theory picture illuminates several aspects of these models. In particular, we have some new insight into the matter spectrum on intersecting branes, and analyze gauge group enhancement as branes approach orbifold points. These novel features of intersecting brane models are also relevant in four dimensions, and are confirmed in 6D using more standard Chan–Paton methods.     

Coherence effect on decryption characteristics in message modulation type chaos secure communication systems using fiber-optic ring resonators

We numerically investigated the dependence of the decryption characteristics in a message modulation type chaos secure communication system using optical fiber ring resonators (OFRRs) on the coherence condition of carrier light. Since the output dynamics of OFRRs were formed on the basis of interference phenomenon among the circulated components in OFRRs, the coherence condition of input light affected inherently the OFRR output dynamics, resulting in the decryption characteristics. It was found that the decryption characteristics degraded as coherence length increased, i.e., as the spectral width of the input light decreased. The decryption characteristics also grew worse as the parameter differences between the transmitter and the receiver became larger.     

In vivo estimation of optical properties of rat liver using single-reflectance fiber probe during ischemia and reperfusion

Optical Review - To quantify the changes in optical properties of in vivo rat liver tissue, we applied diffuse reflectance spectroscopy (DRS) system using single-reflectance fiber probe during...