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41.
Mitsunori Oda Yosuke Fukuchi Satoshi Ito Nguyen Chung Thanh Shigeyasu Kuroda 《Tetrahedron letters》2007,48(52):9159-9162
Reactions of pyrrolidine with 2 equiv of aldehydes without any catalyst in a pressurized vessel at 140–200 °C yielded 1,3-disubstituted pyrroles. -Branched aldehydes gave fairly good yields of the corresponding products by this method, which provides a facile non-oxidative procedure for synthesizing 1,3-dialkylpyrroles from inexpensive pyrrolidine and aldehydes. 相似文献
42.
Takanari Yasui Takeshi Ohtsuka Tetsu Suzuki Shigeki Okajima Kazuya Nakayama Mitsuru Tomioka Katsuhiro Kamimura Takeo Namekata Hiroaki Minamide Hiromasa Ito 《International Journal of Infrared and Millimeter Waves》2006,27(2):199-210
A new, wide-band, high-speed and high-sensitivity THz detector has been developed. The prototype detector consists of a parabolic
cylindrical mirror, a long wire antenna and a Schottky barrier diode. Direct detection measurements have shown a stable sensitivity
of 150 ± 50 V/W for 1–2 THz without any adjustments. The long wire antenna was fixed at the focus of parabolic cylindrical
mirror then it has been realized less operation steps, easy coupling to the external THz signals and a dramatic enhancement
in the practicality of this system. The optically polished mirror and frosted surface one showed comparable sensitivities,
thus easy polishing and less cost mirror fabrication can be applied for this system. The radiation pattern showed a maximum
radiation angle of approximately 23° with its dominant main lobe, which was attributed to the wire antenna character and confirmed
good agreements with classical antenna theory. 相似文献
43.
1,3-Di-tert-butylazulene reacted with highly electrophilic trifluoromethanesulfonate of N-containing heterocycles to give 5-(dihydroheteroaryl)azulene derivatives in good yield and treatment of the 5-(dihydroheteroaryl)azulene derivatives with KOH afforded 5-(heteroaryl)azulenes in excellent yield. 相似文献
44.
Kazuro Shiomi Satoshi mura 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2004,80(6):245
Microorganisms produce many useful antiparasitic agents. Antiparasitic activities and biochemical targets of antiprotozoal and anthelmintic antibiotics are reviewed. Antimalarial apicidin, thiolactomycin, fosmidomycin, and borrelidin, antitrypanosomal ascofuranone, and nematocidal emodepside, 2-deoxoparaherquamide A, and nafuredin are recently discovered antibiotics, and they have potential as useful drugs. 相似文献
45.
Doubly tunable sum frequency generation (SFG) spectra demonstrate that the water molecules at gold/electrolyte interface change their orientation with applied potential. At negative potentials, water molecules in the double layer align with their oxygen atom pointing to the solution. As potential became positive to be close to the potential of zero charge (PZC), the SFG signal decreased, suggesting the OH groups of the water molecule are either in random orientation or parallel to the electrode. As potential became more positive than the PZC, the SFG signal increased again with the oxygen-up orientation as same as in the negative potential region, indicating that water molecules interact with the adsorbed sulfate anions. The peak position of the SFG spectra indicates a relatively disordered state of water molecules at the gold electrode surface, in contrast to the previously observed ice-like structure of water at electrolyte/oxide interfaces. 相似文献
46.
Kazuhiro Yamamoto Haruhiko Ito Kouki Totsuka Tomohiro Sato 《Optics Communications》2006,265(2):692-695
We consider a new scheme of optically ionizing atoms with 10-nm-order spatial resolution. In this method, two-color near-field lights are generated on a narrow slit illuminated by two-color evanescent lights via total-internal reflection of two-wavelength light beams. In order to illustrate the feasibility, we first obtain the ionization cross section from two-step photionization of cold Rb atoms by two-color evanescent lights on a plane surface of a prism. Then, we numerically estimate the ionization efficiency as a function of the slit width using Bethe formula. The scheme is useful for detecting ground-state atoms under less perturbation by scattered light. 相似文献
47.
Mana Ito Takashi Ishizone 《Journal of polymer science. Part A, Polymer chemistry》2006,44(16):4832-4845
Anionic polymerization of N‐methoxymethyl‐N‐isopropylacrylamide ( 1 ) was carried out with 1,1‐diphenyl‐3‐methylpentyllithium and diphenylmethyllithium, ‐potassium, and ‐cesium in THF at ?78 °C for 2 h in the presence of Et2Zn. The poly( 1 )s were quantitatively obtained and possessed the predicted molecular weights based on the feed molar ratios between monomer to initiators and narrow molecular weight distributions (Mw/Mn = 1.1). The living character of propagating carbanion of poly( 1 ) either at 0 or ?78 °C was confirmed by the quantitative efficiency of the sequential block copolymerization using N,N‐diethylacrylamide as a second monomer. The methoxymethyl group of the resulting poly( 1 ) was completely removed to give a well‐defined poly(N‐isopropylacrylamide), poly(NIPAM), via the acidic hydrolysis. The racemo diad contents in the poly(NIPAM)s could be widely changed from 15 to 83% by choosing the initiator systems for 1 . The poly(NIPAM)s obtained with Li+/Et2Zn initiator system possessed syndiotactic‐rich configurations (r = 75–83%), while either atactic (r = 50%) or isotactic poly(NIPAM) (r = 15–22%) was generated with K+/Et2Zn or Li+/LiCl initiator system, respectively. Atactic and syndiotactic poly(NIPAM)s (42 < r < 83%) were water‐soluble, whereas isotactic‐rich one (r < 31%) was insoluble in water. The cloud points of the aqueous solution of poly(NIPAM)s increased from 32 to 37 °C with the r‐contents. These indicated the significant effect of stereoregularity of the poly(NIPAM) on the water‐solubility and the cloud point in water © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4832–4845, 2006 相似文献
48.
In this study, we attempted to control the timing of light-emission from bioluminescent bacteria, by changed cell numbers inoculated into medium. Luminous bacteria express bioluminescence when the number of cells reached a threshold. Inoculated cell density had an effect on the time of bioluminescence starting. Samples were prepared by varying cell density of inoculation. In the results, all the vials showed different luminescence profiles in the order of inoculated cell population. 相似文献
49.
Atiya MS Chiang I Frank JS Haggerty JS Ito MM Kycia TF Li KK Littenberg LS Stevens A Strand RC Louis WC Akerib DS Marlow DR Meyers PD Selen MA Shoemaker FC Smith AJ Azuelos G Blackmore EW Bryman DA Felawka L Kitching P Kuno Y Macdonald JA Numao T Padley P Poutissou J Poutissou R Roy J 《Physical review letters》1990,65(1):21-24
50.
LeA be an automaton whose set of inputs equalsX (|X|≧2) and whose cardinality of the set of states equalsn (n≧2), and letQ be the set of all primitive words overX. ByT(A) we denote the language accepted byA. In this paper, we give the following results:
Moreover, we deal with the case |T(A)⋔Q|<∞ and obtain upper bounds on the cardinalities ofT(A)⋔Q and of some language related toT(A). 相似文献
(1) | T(A)⋔Q≠ ⊘ if and only ifA accepts a primitive wordy withlg(y)≦3n−3, wherelg(y) means the length ofy. |
(2) | |T(A)⋔Q|=∞ if and only ifA accepts a primitive wordy withn≦lg(y)≦3n−3, where |T(A)⋔Q| means the cardinality ofT(A)⋔Q. |