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91.
Katsunori Wakabayashi Mitsutaka Fujita Koichi Kusakabe Kyoka Nakada 《Czechoslovak Journal of Physics》1996,46(4):1865-1866
Anoble mechanism of spin polarization is proposed for finite graphite sheet with edge. For graphite ribbon with zigzag edge, there appear peculiar ‘edge states’. These localized states comprise nearly flat band at the Fermi level, which easily causes magnetic instability. Magnetic structure is suggested from Hartree-Fock analysis of the Hubbard model, where huge magnetic moments are induced at around both of edges by weak HubbardU and are coupled antiferromagnetically with each other. 相似文献
92.
In the presence of palladium complexes as catalysts, fluorinated disilanes add to 1,3-dienes, metehyl vinyl ketone and p-benzoquinone to give mainly 1,4-addition products. 相似文献
93.
Fujita M Nakao Y Matsunaga S Seiki M Itoh Y Yamashita J Van Soest RW Fusetani N 《Journal of the American Chemical Society》2003,125(51):15700-15701
A novel MMP inhibitor, ageladine A (1) with antiangiogenic activity was isolated from a marine sponge Agelas nakamurai. Structure 1 was determined by a combination of spectroscopic and chemical methods to be an unprecedented structure of 4-(4,5-dibromo-1H-pyrrol-2-yl)]-1H-imidazo[4,5-c]pyridin-2-amine. 相似文献
94.
The cyclopropane ring can be used effectively in restricting the conformation of biologically active compounds to improve activity and also to investigate bioactive conformations. We designed (1S,2R)- and (1R,2R)-2-aminomethyl-1-(1H-imidazol-4-yl)cyclopropanes (1 and 2, respectively) and their enantiomers (ent-1 and ent-2) as conformationally restricted analogues of histamine. The four types of chiral cyclopropanes bearing two differentially functionalized carbon substituents in a cis or trans relationship on a cyclopropane ring, (1S,2R)-2-(tert-butyldiphenylsilyloxy)methyl-1-formylcyclopropane (7) and (1R,2R)-2-(tert-butyldiphenylsilyloxy)methyl-1-formylcyclopropane (8) and their enantiomers (ent-7 and ent-8), were developed as the key intermediates for synthesizing 1, 2, ent-1, and ent-2. The reaction between (R)-epichlorohydrin [(R)-12] and phenylsulfonylacetonitrile (13a) in the presence of NaOEt in EtOH followed by treatment with acid gave the chiral cyclopropane lactone 11a with 98% ee in 82% yield. Compound 11a was converted into both the cis- and trans-chiral cyclopropane units 7 and 8, respectively, via reductive desulfonylation with Mg/MeOH as the key step. The corresponding enantiomers, the cis-substituted ent-7 and the trans-substituted ent-8, were also prepared starting from (S)-epichlorohydrin [(S)-12]. The four conformationally restricted target histamine analogues 1, 2, ent-1, and ent-2 were successfully synthesized from 7, 8, ent-7, and ent-8, respectively. The chiral cyclopropane units 7, 8, ent-7, and ent-8 should be useful as versatile intermediates for synthesizing various compounds having an asymmetric cyclopropane structure. 相似文献
95.
Buck SB Hardouin C Ichikawa S Soenen DR Gauss CM Hwang I Swingle MR Bonness KM Honkanen RE Boger DL 《Journal of the American Chemical Society》2003,125(51):15694-15695
Key derivatives and analogues of fostriecin were prepared and examined that revealed a fundamental role for the unsaturated lactone and confirmed the essential nature of the phosphate monoester. Thus, an identical 200-fold reduction in protein phosphatase 2A (PP2A) inhibition is observed with either the saturated lactone (7) or with an analogue that lacks the entire lactone (15). This 200-fold increase in PP2A inhibition attributable to the unsaturated lactone potentially may be due to reversible C269 alkylation within the PP beta12-beta13 active site loop accounting for PP2A/4 potency and selectivity. 相似文献
96.
Shinsaku Fujita 《Theoretical chemistry accounts》2007,117(3):353-370
Planted three-dimensional (3D) trees, which are defined as a 3D version of planted trees, are enumerated by means of Fujita’s
proligand method formulated in Parts 1–3 of this series [Fujita in Theor Chem Acc 113:73–79, 80–86, 2005; Fujita in Theor
Chem Acc 115:37–53, 2006]. By starting from the concepts of proligand and promolecule introduced previously [Fujita in Tetrahedron
47:31–46, 1991], a planted promolecule is defined as a 3D object in which the substitution positions of a given 3D skeleton are occupied by a root and proligands.
Then, such planted promolecules are introduced as models of planted 3D-trees. Because each of the proligands in a given planted
promolecule is regarded as another intermediate planted promolecule in a nested fashion, the given planted promolecule is
recursively constructed by a set of such intermediates planted promolecules. The recursive nature of such intermediate planted
promolecules is used to derive generating functions for enumerating planted promolecules or planted 3D-trees. The generating
functions are based on cycle indices with chirality fittingness (CI-CFs), which are composed of three kinds of sphericity
indices (SIs), i.e., a
d
for homospheric cycles, c
d
for enantiospheric cycles, and b
d
for hemispheric cycles. For the purpose of evaluating c
d
recursively, the concept of diploid is proposed, where the nested nature of c
d
is demonstrated clearly. The SIs are applied to derive functional equations for recursive calculations, i.e., a(x), c(x
2), and b(x). Thereby, planted 3D-trees or equivalently monosubstituted alkanes as stereoisomers are enumerated recursively by counting
planted promolecules. The resulting values are collected up to 20 carbon content in a tabular form. Now, the enumeration problem
initiated by mathematician Cayley [Philos Mag 47(4):444–446, 1874] has been solved in such a systematic and integrated manner
as satisfying both mathematical and chemical requirements. 相似文献
97.
98.
99.
100.
Masao Tomoi Noriyuki Yanai Satoshi Shiiki Hiroshi Kakiuchi 《Journal of polymer science. Part A, Polymer chemistry》1984,22(4):911-926
Polymer-supported crown ethers were prepared from chloromethylated or ω-bromoalkylated polystyrene resins and hydroxymethylbenzo-18-crown-6 and 15- or 18-membered monoazacrown ethers. Effects of the cavity size of crown ethers, the degree of crosslinking, the degree of ring substitution, particle size, spacer chains, and solvents on the activity of the polymer-supported crown ethers in the reaction of 1-chloro- or 1-bromo-octane with aqueous NaI or KI were investigated and mechanisms of the reaction were discussed in terms of mass transfer, intraparticle diffusion, and intrinsic reactivity. 相似文献